Abstract
Highly crystalline nanoclusters of MoS2 were synthesized and their optical absorption and photoluminescence spectra were investigated. Key results include: (1) strong quantum confinement effects with decreasing size; (2) preservation of the quasiparticle (or excitonic) Nature of the optical response for clusters down to ~2.5 nm in size which are only two unit cells thick; (3) demonstration that 3-D confinement produces energy shifts which are over an order of magnitude larger than those due to 1-D confinement; (4) observation of large increases in the spin-orbit splittings at the top of the valence band at the K and M points of the Brillouin zone with decreasing cluster size; and (5) observation of photoluminescence due to both direct and surface recombination.
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References
See A.D. Yoffe, Adv. in Phys. 42, 173 (1993) and references therein for a recent review.
H. Tributsch, Z. Naturforsch 32a, 972 (1977).
R. Coehoorn, C. Haas, J. Dijkstra, C.J.F. Flipse, R.A. de Groot and A. Wold, Phys. Rev. B., 35, 6195 (1987), 35, 6203 (1987).
J.P. Wilcoxon, P.P. Newcomer, and G.A. Samara, J. Appl. Phys. (submitted).
J.P. Wilcoxon, DOE patent #5,147,841, issued Sep. 15, 1992.
J.P. Wilcoxon and G.A. Samara, Phys Rev. B 51, 7299, (1995).
B.L. Evans and P.A. Young, Proc. Roy. Soc. A., 284, 402 (1965).
A.M. Goldberg, A.R. Beal, F.A. Levy and E.A. Davis, Phil. Mag. 32, 367 (1975).
R.F. Frindt and A.D. Yoffe, Proc. Roy. Soc. A., 273, 69 (1963).
F. Parsapour, D.F. Kelley, S. Craft and J.P. Wilcoxon, J. Chem. Phys. 104, 1 (1996).
F. Consadori and R.F. Frindt, Phys. Rev. B 2, 4893 (1970).
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Wilcoxon, J.P., Newcomer, P.P. & Samara, G.A. Synthesis and Optical Properties of MoS2 Nanoclusters. MRS Online Proceedings Library 452, 371–376 (1996). https://doi.org/10.1557/PROC-452-371
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DOI: https://doi.org/10.1557/PROC-452-371