Skip to main content
SpringerLink
Log in

New Strategies for the Fabrication of Enzyme Electrodes

  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

The electrochemical properties of o-dianisidine have been studied in both aqueous and organic solvents. This aryl diamine has been electrochemically polymerized on ITO coated glass electrodes and it was determined that the optical properties of these films are influenced by the polymerization conditions. The use of this polymer film as substrate for chemical coupling of biomaterials has been demonstrated with the light harvesting protein, phycoerythrin. Fabrication and bioanalytical application of enzyme electrodes by electrochemical copolymerization of o-dianisidine with the enzymes glucose oxidase and horseradish peroxidase, modified with o-dianisidine is described.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. S. Mekler and S. M. Bystryak. Anal. Chim. Acta. 264, 359 (1992).

    Article  CAS  Google Scholar 

  2. C. -H. Yang and T. -C. Wen. J. Appl. Electrochem. 24, 166 (1994).

    Article  CAS  Google Scholar 

  3. D. N. Upadhyay, S. Bharathi and G. P. Rao. Solar Energy Materials & Solar Cells 37, 307 (1995).

    Article  CAS  Google Scholar 

  4. S. S. Pandey, S. Annapoorni and B. D. Malhotra. Macromolecules. 26, 3190 (1993).

    Article  CAS  Google Scholar 

  5. S. F. Patil, A. G. Bedekar and C. M. Agashe. J. Mater. Sci. Lets. 12, 1354 (1993).

    CAS  Google Scholar 

  6. E. E. Karyakina, L. V. Neftyakova and A. A. Karyakin. Analytical Letters. 27, 2871 (1994).

    Article  CAS  Google Scholar 

  7. L. A. Samuelson, D. L. Kaplan, J. O. Lim, M. Kamath, K. A. Marx and S. K. Tripathy. Thin Solid Films. 242, 50 (1994).

    Article  CAS  Google Scholar 

  8. S. Alva, S. Sengupta, R. Phadke and G. Govil. Biosensors & Bioelectronics 6, 663 (1991).

    Article  CAS  Google Scholar 

  9. Q. Deng and S. Dong. J. Electroanal. Chem. 377, 191 (1994).

    Article  CAS  Google Scholar 

  10. A. Ohki, K. Naka and O. Ito. Chemistry Letters. 1065 (1994).

    Google Scholar 

  11. T. Tatsuma, T. Watanabe, S. Tatsuma and T. Watanabe. Anal. Chem. 66, 290 (1994).

    Article  CAS  Google Scholar 

  12. A. Mulchandani, C. -L. Wang and H. H. Weetall. Anal. Chem. 67, 94 (1995).

    Article  CAS  Google Scholar 

  13. S. Alva, R. S. Phadke and G. Govil. J. Ind. Chem. Soc. 70, 403 (1993).

    CAS  Google Scholar 

Download references

Acknowledgments

Support from ARO URI Grant DAAL03-91-G-0064, ARO Cooperative Grant DAAH04-94-2-003 and US Army/USDA Contracts DAAK60-93-K-0012 and DAAK60-93-K-0004 are gratefully acknowledged.

Author information

Authors and Affiliations

  1. Departments of Physics and Centers for Advanced Materials and Intelligent Biomaterials, University of Massachusetts Lowell, Lowell, MA, 01854, USA

    K. Shridhara Alva, Jayant Kumar & Sukant K. Tripathy

  2. Departments of Chemistry, Centers for Advanced Materials and Intelligent Biomaterials, University of Massachusetts Lowell, Lowell, MA, 01854, USA

    Lynne A. Samuelson & Kenneth A. Marx

  3. Biotechnology Division, US Army Natick RD & E Center, Natick, MA, 01760, USA

    David L. Kaplan

Authors
  1. K. Shridhara Alva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Lynne A. Samuelson
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jayant Kumar
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Kenneth A. Marx
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. David L. Kaplan
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Sukant K. Tripathy
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Alva, K.S., Samuelson, L.A., Kumar, J. et al. New Strategies for the Fabrication of Enzyme Electrodes. MRS Online Proceedings Library 414, 119–124 (1995). https://doi.org/10.1557/PROC-414-119

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/PROC-414-119

Search

Navigation