Abstract
This work aims to provide a systematic approach for deriving desorption mechanisms on semiconductor surfaces from a coupling of temperature programmed desorption (TPD) experiments and Monte Carlo (MC) simulations. MC simulations are used to evaluate different desorption schemes to identify mechanisms consistent with experimental results. Effects of nearest neighbor interactions, island formation, and surface reconstructions are quantified through the simulations. Methyl desorption from Ga-rich GaAs is used as a case study to illustrate the MC procedure for interpretation of TPD spectra.
Similar content being viewed by others
References
G.S. Bales and D.C. Chrzan, Phys. Rev. B 50, 6057(1994).
P.A. Redhead, Vacuum, 12, 203 (1962).
A.M. de Jongard and J.W. Niemantsverdriet, Surf. Sci., 233, 355 (1990).
K.A. Fichthorn and W.H. Weinberg, J. Chem. Phys., 95, 1090 (1991).
B. Meng and W.H. Weinberg, J. Chem. Phys., 100, 5280 (1994).
H.C. Kang and W.H. Weinberg, Surf. Sci., 299/300, 755 (1994).
H.C. Kang and W.H. Weinberg, Acc. Chem. Res., 25, 253 (1992).
Monte Carlo Method in Statistical Physics, K. Binder, ed., Vol 7 of Topics in Current Physics, Springer, Berlin, 1986.
J.R. Creighton, Surf. Sci., 234, 287 (1990).
D.K. Biegelsen, R.D. Bringans, J.E. Northrup, and L.E. Swartz, Phys. Rev. B, 41, 5701 (1990).
K. Ohta, T. Kojima, and T. Nakagawa, J. Crystal Growth, 95, 71 (1989).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Venkataramani, R., Jensen, K. Analysis of TPD Spectra on Semiconductor Surfaces by Monte Carlo Simulations. MRS Online Proceedings Library 399, 109 (1995). https://doi.org/10.1557/PROC-399-109
Published:
DOI: https://doi.org/10.1557/PROC-399-109