Skip to main content
Log in

Carbon Nanofibers as a Novel Catalyst Support

  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

Catalytically grown carbon nanofibers have been prepared by the thermal decomposition of carbon containing gases over copper-nickel and iron surfaces. This material is found to be highly graphitic in nature when prepared from certain catalysts and gaseous reactants. In the as-grown state, carbon nanofibers have surface areas in the range 200 to 300 m2/g, and by following careful activation procedures this value can readily be increased to ˜700 m2/g. Electrical measurements indicate that the material has a conductivity approaching that of single crystal graphite. This material combines the attributes of active carbon and graphite and in addition, the physical form of carbon nanofibers offers some interesting opportunities for the design of unique catalyst systems.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Smiseck and S. Cerny, ”Active Carbon”, Elsevier, N. Y., 1970.

    Google Scholar 

  2. C. L. Thomas, ”Catalytic Processes and Proven Catalysts”, Academic Press, N. Y., 1970.

    Google Scholar 

  3. H.-J. Jung, P. L. Walker Jr., and M. A. Vannice, J. catal. 75, 416 (1982).

    Article  CAS  Google Scholar 

  4. A. A. Chen, M. A. Vannice and J. Phillips, J. Phys. Chem. 91, 67 (1985).

    Google Scholar 

  5. J. J. Venter, A. A. Chen, J. Phillips and M. A. Vannice, J. Catal. 119, 451 (1989).

    Article  CAS  Google Scholar 

  6. P. Ehrburger, O. P. Mahajan and P. L. Walker Jr., J. Catal. 43, 61 (1976).

    Article  CAS  Google Scholar 

  7. F. Rodriguez-Reinoso, J. D. Lopez-Gonzalez, C. Moreno-Castilla, A. Guerrero-Ruiz and I Rodriguez-Ramos, Fuel 63, 1089 (1984)

    Article  CAS  Google Scholar 

  8. J. Phillips and J. A. Dumesic, Appl. Catal. 9, 1 (1984).

    Article  CAS  Google Scholar 

  9. I. C. Brownlie, G. R. Fryer, and G. Webb, J. Catal. 14, 263 (1969).

    Article  CAS  Google Scholar 

  10. P. Gallezot, D. Richard and G. Bergeret, in ”Novel Materials in Heterogeneous Catalysis” edited by R. T. K. Baker and L. L. Murrell, ACS Symposium Series 437, p. 150, 1990

    Article  CAS  Google Scholar 

  11. R. T. K. Baker., Carbon 27. 315 (1989).

    Article  CAS  Google Scholar 

  12. N. M. Rodriguez., J. Mater. Res. 8, 3233 (1993).

    Article  CAS  Google Scholar 

  13. R. J. Koestner, J. C. Frost, P. C. Stair, M. A. Van Hove, and G. A. Somorjai, Surf. Sci. 116, 85 (1982).

    Article  CAS  Google Scholar 

  14. X. Y. Zhu, and J. M. White., Surf. Sci. 214, 240 (1989).

    Article  CAS  Google Scholar 

  15. R. T. Yang and J. P. Chen, J. Catal. 115, 240 (1989).

    Article  Google Scholar 

  16. M. S. Kim, N. M. Rodriguez, and R. T. K. Baker, J. Catal. 134, 253 (1992).

    Article  CAS  Google Scholar 

  17. N. M. Rodriguez, M. S. Kim, and R. T. K. Baker, J. Phys. Chem. in press.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kim, MS., Rodriguez, N.M. & Baker, R.T.K. Carbon Nanofibers as a Novel Catalyst Support. MRS Online Proceedings Library 368, 99–104 (1994). https://doi.org/10.1557/PROC-368-99

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/PROC-368-99

Navigation