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Inhomogeneity in the Network Order of Device Quality a-Si:H

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Abstract

In this paper we show that the degree of order of the Si network in a-Si:H is increasing with two length scales from the surface into the bulk. The major manifestation of the disorder is the variation in the Si-Si bond-stretching rather than the variation in the width of the dihedral angle distribution. The results are interpreted in terms of the decrease of the hydrogen concentration from the free surface into the bulk.

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References

  1. M.H. Brodsky in Light Scattering in Solids, Vol. 1, edited by M. Cardona (Springer Verlag, Berlin, 1975), p.205.

    Article  Google Scholar 

  2. D. Beeman and R. Alben, Adv. in Physics, 26 339 (1977).

    Article  CAS  Google Scholar 

  3. D. Bermejo, M. Cardona and M.H. Brodsky, Proc. of the VII Intl. Conf on Amorphous and Liquid Semiconductors, edited by W. Spear (University of Edinburgh, Edinburgh, 1977), p. 343, D. Bermejo and M. Cardona, J. Non Cryst. Solids 32 405 (1979).

    Article  CAS  Google Scholar 

  4. D. Beeman, R. Tsu and M.F. Thorpe, Phys. Rev. B32 874 (1985).

    Article  Google Scholar 

  5. R. Tsu, J.G. Hernandez and F.H. Pollak, J. Non. Cryst. Solids 66 109 (1984).

    Article  CAS  Google Scholar 

  6. N. Maley and J.S. Lannin, Phys. Rev. B, 36 1146 (1987).

    Article  CAS  Google Scholar 

  7. J. S. Lannin, J. Non Cryst. Solids 97&98, 39, 203 (1987).

    Article  Google Scholar 

  8. N. Maley, D. Beeman and J.S. Lannin, Phys. Rev. B38 10611 (1988).

    Article  Google Scholar 

  9. F. Cerdeira, C.J. Buchenauer, F.H. Pollak and M. Cardona, Phys. Rev. B 5 580 (1972).

    Article  Google Scholar 

  10. B. Ranchoux, D. Jousse, J.C. Bruyere and A. Deneuville, J. Non Cryst. Solids, 53 & 60, 185 (1983).

    Article  Google Scholar 

  11. J. Hanna, H. Azuma, H. Shirai, M. Azumaard, and I. Shimizu, J. Non. Cryst. Solids 114 804 (1989).

    Article  CAS  Google Scholar 

  12. A. H. Mahan, J. Carapella, B. F. Nelson, R. S. Crandall and I. Balberg, J. Appl. Phys. 69 (1991).

  13. S. T. Kshirsagar, N. J. Khaladkar, J. B. Mamdapurkar and A.P.B. Sinha, Japanese J. Appl. Phys. 25 1788 (1986).

    Article  CAS  Google Scholar 

  14. Y. Hishikawa, S. Tsuda, N. Nakamura, S. Nakano and Y. Kuwanto, Appl. Phys. Lett. 57 771 (1990).

    Article  CAS  Google Scholar 

  15. Y. Hishikawa, K. Wantabe, S. Tsuda, M. Ohnishi and Y. Kuwanto, Japanese J. Appl. Phys. 24 385 (1985).

    Article  CAS  Google Scholar 

  16. Y. Hishikawa, K. Wantabe, S. Tsuda, S. Nakano, M. Ohnishi and Y. Kuwanto, J. Non Cryst. Solids 97&98 399 (1987).

    Article  Google Scholar 

  17. Y. M. Li, B. F. Fieselmann and A. Catalano, Proc. of the XXII IEEE PVSC (IEEE, New York, 1991), p. 1231.

    Google Scholar 

  18. L. Yang, I. Balberg, A. Catalano and M. Bennett, Mat. Res. Soc. Symp. Proc. 192 243 (1990).

    Article  CAS  Google Scholar 

  19. F. Adar in Materials Characterization for Systems Performance and Reliability, edited by J.W. McCauley V. Weiss (Plenum Publishing Corp., 1986) p. 339.

  20. M. Favre, H. Curtins and A.V. Shah, J. Non Cryst. Solids 97&98 731 (1987).

    Article  Google Scholar 

  21. S. Hasegawa, S. Shimizu and Y. Kurata, Phil. Mag. B49 511, 521 (1984).

    Article  Google Scholar 

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Acknowledgments

The authors are indebted to A. Catalano and B.P. Nelson for the samples used in this study. This work was supported in part by EPSCoR-NSF grant EHR-9108775, in part by U.S. Army Research Office grant No. DAALO3-89-G-0114, and in part by the U.S.-Israel Binational Science Foundation.

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Morell, G., Katiyar, R., Weisz, S. et al. Inhomogeneity in the Network Order of Device Quality a-Si:H. MRS Online Proceedings Library 297, 321–326 (1993). https://doi.org/10.1557/PROC-297-321

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  • DOI: https://doi.org/10.1557/PROC-297-321

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