Abstract
In order to realize a thin film of organic single crystals, we have been investigating fabrication process using vapour deposition technique. Up to now, highly oriented thin films of 2-methyl-4-nitroaniline(MNA) and 4-(N,N-dimethylamino)-3-acetamidonitrobenzene(DAN), both of which are promising organic materials for nonlinear optical devices, could be fabricated on a buffed polyimide and on a thermally oxidized silicon wafer, respectively. In the case of MNA films, a series of results by X-ray diffraction and by SEM observation showed weak two-dimensional characteristics suggesting the existence of topographic effects and/or of interaction between MNA molecules and molecular moieties of polyimide substrate. Small optical transmittance of both MNA and DAN thin films are explained in terms of light scattering by grain boundaries and surface roughness.
Similar content being viewed by others
References
G. F. Lipscomb, A. F. Garito and S. Narang: J. Chem.Phys., 75, 1509, (1981)
B. F. Levine, C. G. Bethea, C. D. Thurmond, R. T. Lynch and J. L. Bernstein: J.Appl.Phys., 50(4), 2523, (1979)
R. J. Twieg and K. Jain, in Nolinear Optical Properties of Organic and Polymeric Materials, edited by D.J. Williams, (American Chemical Society, Washington D.C., 1983), p.57.
J. C. Baumert, R. J. Twieg, G. C. Bjorklund, J. A. Logan and C. W Dirk, Appl.Phys.Lett. 51, 1484, (1987).
A. Inoue, M Ishino, Y Akagi and Y Nakajima, Proceedings of the 33rd Japan Congress on Materials Research (The Society of Materials Science, Kyoto, JAPAN, 1990) p.177.
Acknowledgement
The authors wish to thank members of Materials Research and Analysis Center of SHARP Corporation for valuable suggestion and discussion.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Inoue, A., Ishino, M., Akagi, Y. et al. Approach Towards Heteroepitaxial Growth of Functional Molecular Crystals by Vapour Deposition. MRS Online Proceedings Library 202, 469–474 (1990). https://doi.org/10.1557/PROC-202-469
Published:
Issue Date:
DOI: https://doi.org/10.1557/PROC-202-469