Abstract
Liquid crystal elastomers (LCE) exhibit a combination of elasticity and mesogenic ordering, yielding large thermally stimulated changes in shape. These LCE systems although well characterised, still yield open questions in the nature of how the crosslinking affects the LCE phase transition. Therefore calorimetry and deuteron-nuclear magnetic resonance were used to study the isotropic-nematic phase transition of uniformly ordered LCE. We observed that the density of crosslinkers strongly affects the nematic-isotropic phase transition. The observed spread critical transitions are explained with a dispersion of local mechanical fields that yields a weakly disordered orientational state composed of regions that exhibit temperature profiles of the nematic order parameter ranging from first order to supercritical. On increasing crosslinking density, the predominantly first order thermodynamic response transforms into a predominantly supercritical one.
Additionally, to illustrate the response of these actuating systems, it was demonstrated that a LCE can be electrically heated. The insulating LCE network was reprocessed using conducting nanoparticles dispersed in a solvent with high LCE swelling capability. This results in a low electrical resistivity surface layer of LCE network with a high concentration of conducting nanoparticles. The reprocessing allows the effective resistivity of a LCE film to be reduced from highly insulating values to values useable for electrical actuation. This layer in addition withstands large changes in geometrical shape both in contraction and expansion. Utilizing a resistive “Joule” heating effect, the reprocessed system exhibits an indirect electromechanical effect characterised by a 150length change that can be cycled for more than 10, 000 times.
Similar content being viewed by others
References
M. Warner, E. M. Terentjev, Liquid Crystal Elastomers, Clarendon, Oxford, 2003.
M. Hebert, R. Kant, and P.-G. de Gennes J. Phys. I (France) 7 909 (1997).
W. Kaufhold, H. Finkelmann, and H. R. Brand, Makromol. Chem. 192 2555 (1991).
S. Disch, C. Schmidt, and H. Finkelmann, Makromol. Rapid. Commun. 15 303 (1994).
S. M. Clarke, A. Hotta, A. R. Tajbakhsh, and E. M. Terentjev, Phys. Rev. E 64 061702 (2001).
J. V. Selinger, H. G. Jeon, and B. R. Ratna, Phys. Rev. Lett. 89 225701 (2002).
H. R. Brand and K. Kawasaki, Macromol. Rapid Commun. 15 251 (1994).
G. G. Pereira and M. Warner, Eur. Phys. J. E 5 295 (2001).
P. G. de Gennes and K. Okumura, Europhys. Lett. 63 76 (2003).
A. Lebar, Z. Kutnjak, S. Zumer, H. Finkelmann, A. Sánchez-Ferrer, B. Zalar, Phys. Rev. Lett. 94 197801 (2005).
G. Cordoyiannis, A. Lebar, B Zalar, S. Zumer, H. Finkelmann, and Z. Kutnjak, to be published
I. Petridis and E. M. Terentjev, J. Phys. A: Math. Gen. 39 9693 (2006).
H. Finkelmann, E. Nishikawa, G. G. Pereira, and M. Warner, Phys. Rev. Lett. 87 015501 (2001).
P. M. Hogan, A. R. Tajbakhsh, and E. M. Terentjev, Phys. Rev. E 65 041720 (2002).
Y. Yusuf, J. H. Huh, P. E. Cladis, H. R. Brand, H. Finkelmann and S. Kai, Phys. Rev. E 71 061702 (2005).
S. Courty, J. Mine, A. R. Tajbakhsh and E. M. Terentjev, Europhys. Lett. 64 654 (2003).
S. V. Ahir and E. M. Terentjev, Nat. Mater. 4 491 (2005).
S. V. Ahir, A. M. Squires, A. R. Tajbakhsh, and E. M. Terentjev, Phys. Rev. B 73 011803 (2006).
S. V. Ahir and E. M. Terentjev, Phys. Rev. Lett. 64 133902 (2006).
M. Shahinpoor, Proc. Soc. Photo-Opt. Instrum. Eng. 3987 187 (2000).
M. Camacho-Lopez, H. Finkelmann, P. Palffy-Muhoray and M. Shelley, Nat. Mater. 3 307 (2004).
D. K. Shenoy, D. Thomsen III, A. Srinivasan, P. Keller and B. Ratna, Sens. Actuators A 96 184 (2002)
M. Chambers, B. Zalar, M. Remskar, H Finkelmann and S. Zumer, Appl. Phys. Lett. 89 243116 (2006); Vir. J. Nan. Sci. & Tech. 14, 120 (2006).
M. Chambers, B. Zalar, M. Remskar, H Finkelmann and S. Zumer, submitted for publication.
M. Chambers, B. Zalar, M. Remskar, H Finkelmann and S. Zumer, in preparation.
Kupfer and H. Finkelmann, Makromol. Chem. Rapid Commun. 12 717 (1991).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zumer, S., Chambers, M., Cordoyiannis, G. et al. Some Advances in Liquid Crystal Elastomers: From Crosslinks Affected Ordering to Carbon Nanoparticles Enabled Actuation. MRS Online Proceedings Library 1005, 406 (2007). https://doi.org/10.1557/PROC-1005-Q04-06
Published:
DOI: https://doi.org/10.1557/PROC-1005-Q04-06