Abstract
A solidification model for Pr1+xBa2−xCu3O7−δ ternary oxides by the top seeded crystal pulling (SRL–CP: Solute Rich Liquid–Crystal Pulling) method is presented in which the composition of the grown single crystals is estimated from the starting composition in the crucible. This model involves the diffusion flux balance of each element at the growth interface in the liquid considering equilibrium tie-lines in the PrOy–BaO–CuO ternary phase diagram which have been obtained experimentally. The self-diffusion coefficient for Pr and the interdiffusivities for Ba and Cu in the liquid are used in this model because this liquid is a dilute solution for Pr. The calculated results are in good agreement with the experimental ones.
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L. Soderholm, K. Zhang, D. G. Hinks, M. A. Beno, J.D. Jorgensen, C. U. Segre, and Ivan K. Schuller, Nature 328, 604–605 (1987).
A. P. Goncalves, I.C. Santos, E. B. Lopes, R. T. Henriques, M. Almeida, and M.O. Figueiredo, Phys. Rev. B 37, 7476–7481 (1988).
K. Kinoshita, A. Matsuda, H. Shibata, T. Ishii, T. Watanabe, and T. Yamada, Jpn. J. Appl. Phys. 27, L1642–L1645 (1988).
A. Matsuda, K. Kinoshita, T. Ishii, H. Shibata, T. Watanabe, and T. Yamada, Phys. Rev. B 38, 2910–2913 (1988).
U. Neukirch, C. T. Simmons, P. Sladeczek, C. Laubschat, O. Strebel, G. Kaindel, and D. D. Sarma, Europhys. Lett. 5, 567–571 (1988).
Z. Zou, K. Oka, T. Ito, and Y. Nishihara, Proc. of the 9th Int. Symp. on Supercond. (ISS’96), in press.
H. A. Blacksteed, D. B. Chrisey, John D. Dow, J.S. Horwitz, A. E. Klunzinger, and D. B. Pulling, Physica C235–240, 1539–1540 (1994).
M. Tagami and Y. Shiohara, J. Cryst. Growth 171, 409–414 (1997).
M. Tagami, M. Kambara, T. Umeda, and Y. Shiohara, J. Mater. Res. (in press).
Y. Yamada and Y. Shihara, Physica C217, 182–188 (1993).
W. G. Cochran, Proc. Cambridge Philos. Soc. 30, 365 (1934).
V. G. Levich, Physicochemical Hydrodynamics (Prentice-Hall, Englewood Cliffs, NJ 1962), p. 60.
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Tagami, M., Umeda, T. & Shiohara, Y. Diffusion model for the crystal growth of Pr1+xBa2−xCu3O7–δ by the top seeded crystal pulling method. Journal of Materials Research 12, 2880–2888 (1997). https://doi.org/10.1557/JMR.1997.0382
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DOI: https://doi.org/10.1557/JMR.1997.0382