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A new type of brittle fracture in a fcc metal bicrystal with intergranular segregation

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Abstract

A new type of brittle fracture was discovered in a Cu–Bi alloy bicrystal with a random misorientation interface. Macroscopically, fracture occurred along the interface with a low-energy release rate of order 50 Jm−2. Microscopically, the crack apparently propagated in a zigzag manner such that a cleavagelike fracture was produced, which consists of two sets of smooth {110} facets and one set of {100} facets with serrations corresponding to their intersections with {111} slip planes. Facet sizes are typically of order 1 by 5 μm or smaller. The very smooth facets and low-energy absorption suggest that a decohesion separation process has occurred along {110} planes, and the serrations suggest that substantial dislocation slip accompanied fracture of the {100} facets. The fracture surface morphology may be explained as the result of a similar morphology of Bi-induced microscopic faceting of the bicrystal interface or, instead, may result from fracture propagating in the vicinity of, but not quite along, the interface. Evidence is presented that favors the latter so that this is a rapid, cleavagelike, semiintergranular fracture that has not been observed in fee metals or alloys when an environment effect is not involved. Its faceted features resemble those of transgranular stress corrosion cracks in certain fee metals.

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References

  1. E. Voce and A. P. C. Hallowes, J. Inst. Met. 73, 323 (1947).

    CAS  Google Scholar 

  2. E. D. Hondros and D. McLean, Philos. Mag. 29, 771 (1974).

    Article  CAS  Google Scholar 

  3. A. M. Donald and L. M. Brown, Acta Metall. 27, 59 (1979).

    Article  CAS  Google Scholar 

  4. S. Biggin, in the Proceedings of the 9th International Conference on Electron Microscopy, Toronto, 1978, Vol. 1, p. 600.

  5. A. Fraczkiewicz and M. Biscondi, J. Phys. (Paris) 46, C4-497 (1985).

    Article  Google Scholar 

  6. J. D. Russell and A. T. Winter, Scr. Metall. 19, 575 (1985).

    Article  CAS  Google Scholar 

  7. S. P. Lynch, Scr. Metall. 13, 1051 (1979).

    Article  CAS  Google Scholar 

  8. R. Liu, H. Narita, C. Altstetter, H. Birnbaum, and E. N. Pugh, Metall. Trans. A 11, 1563 (1980).

    Article  Google Scholar 

  9. J. L. Nelson and J. A. Beavers, Metall. Trans. A 10, 658 (1979).

    Article  Google Scholar 

  10. K. Sieradski, R. L. Sabatini, and R. C. Newman, Metall. Trans. A 15, 1941 (1984).

    Article  Google Scholar 

  11. M. J. Kaufman, E. N. Pugh, and A. J. Forty, Presentation at the 2nd International Conference on Fundamentals of Fracture, Gatlinberg, Tennessee, 4–7 November 1985.

  12. E. N. Pugh, Corrosion, NACE 41, 517 (1985).

    Article  CAS  Google Scholar 

  13. K. Sieradski and R. C. Newman, Philos. Mag. A 51, 95 (1985).

    Article  Google Scholar 

  14. B. Yan and C. Laird, Mater. Sci. Eng. 80, 59 (1986).

    Article  CAS  Google Scholar 

  15. L. Buchinger and C. Laird, Mater. Sci. Eng. 76, 71 (1985).

    Article  CAS  Google Scholar 

  16. Binary Alloy Phase Diagrams, edited by T. B. Massalski (American Society of Metals, Metals Park, OH, 1986), Vol. 1.

    Google Scholar 

  17. S. T. Thorpe, V. Erb, W. A. Miller, and K. T. Aust (private communication).

  18. F. Moya, G. E. Moya-Gontier, F. Cabane-Brouty, and J. Oudar, Acta Metall. 19, 1189 (1971).

    Article  CAS  Google Scholar 

  19. B. Aufray and J. Cabane, Scr. Metall. 15, 1339 (1981).

    Article  CAS  Google Scholar 

  20. A. Pineau, B. Aufray, F. Cabana-Brouty, and J. Cabana, Acta Metall. 31, 1047 (1983).

    Article  CAS  Google Scholar 

  21. B. Singh, R. W. Wook, and E.-A. Knabbe, J. Vac. Sci. Technol. 17, 29 (1980).

    Article  CAS  Google Scholar 

  22. S. Chikwembani and J. Weertman, Scr. Metall. 19, 1499 (1985).

    Article  CAS  Google Scholar 

  23. A. Donald, Philos. Mag. 34, 1185 (1976).

    Article  CAS  Google Scholar 

  24. A. M. Donald and A. J. Craven, Philos. Mag. A 39, 1 (1979).

    Article  Google Scholar 

  25. J. R. Michael and D. E. Williams, Metall. Trans. A 15, 99 (1984).

    Article  Google Scholar 

  26. J. R. Rellick, C. J. McMahon, H. L. Marcus, and P. W. Palmberg, Metall. Trans. 2, 1492 (1971).

    Article  CAS  Google Scholar 

  27. C. J. McMahon, E. Furubayashi, H. Ohtani, and H. C. Feng, Acta Metall. 24, 695 (1976).

    Article  Google Scholar 

  28. W. R. Wagner, T. Y. Tan, and R. W. Balluffi, Philos. Mag. 29, 895 (1974).

    Article  CAS  Google Scholar 

  29. G. H. Bishop, W. H. Hortt, and G. Q. Bruggeman, Acta Metall. 19, 37 (1971).

    Article  CAS  Google Scholar 

  30. M. J. Weins and J. J. Weins, Philos. Mag. 26, 885 (1972).

    Article  CAS  Google Scholar 

  31. J. R. Rice, in Chemistry and Physics of Fracture, edited by R. M. Latanision and R. H. Jones (Martinus Nijhoff, Dordrecht, The Netherlands, 1987) (to be published).

    Google Scholar 

  32. J. S. Wang, “Review of Data to Evaluate Segregation Effects on the Ductile–Brittle Transition in Cu–Bi Bicrystals, “ Progress Report, Harvard University, 1985.

  33. P. M. Anderson, Ph.D. dissertation, Harvard University, 1986.

  34. J. S. Wang, P. M. Anderson, and J. R. Rice, in Mechanical Behavior of MaterialsV, edited by M. G. Yan, S. H. Zhang, and Z. M. Zheng (Pergamon, New York, 1987), p. 191.

    Google Scholar 

  35. M. Gittmann, B. Quantin, and Ph. Domonlin, Met. Sci. 17, 123 (1983).

    Article  Google Scholar 

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Wang, JS. A new type of brittle fracture in a fcc metal bicrystal with intergranular segregation. Journal of Materials Research 3, 16–28 (1988). https://doi.org/10.1557/JMR.1988.0016

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  • DOI: https://doi.org/10.1557/JMR.1988.0016

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