Abstract
High-quality electron sources can be made from individual multi-walled carbon nanotubes. A process was developed allowing the control over 1) the length of the fraction of the nanotube protruding from the support tip, 2) the contact length of the nanotube with the support tip, 3) the diameter of the nanotube. In addition, the cap of the nanotube was closed and the nanotube was cleaned thoroughly. The field emission model successfully describes the electron emission process of these electron sources and the work function is 5.1 eV. The emitters show a highly stable emission, as expected on account of the extremely stable structure of the carbon nanotube.
Similar content being viewed by others
References
N. de Jonge, J. M. Bonard, Phil.Trans.R.Soc.Lond.A 362, 2239–2266 (2004).
W. B. Choi, D. S. Chung, J. H. Kang, H. Y. Kim, Y. W. Jin, I. T. Tan, Y. H. Lee, J. E. Jung, N. S. Lee, G. S. Park and J. M. Kim, Appl.Phys.Lett. 75, 3129–3131 (1999).
Y. Saito, S. Uemura, Carbon 38, 169–182 (2000).
H. Sugie, M. Tanemure, V. Filip, K. Iwata, K. Takahashi and F. Okuyama, Appl.Phys.Lett. 78, 2578–2580 (2001).
G. Z. Yue, Q. Qiu, B. Gao, Y. Cheng, J. Zhang, H. Shimoda, S. Chang, J. P. Lu and O. Zhou, Appl.Phys.Lett 81, 355–357 (2002).
N. de Jonge, Y. Lamy, K. Schoots and T. H. Oosterkamp, Nature 420, 393–395 (2002).
A. G. Rinzler, J. H. Hafner, P. Nikolaev, L. Lou, S. G. Kim, D. Tomanek, P. Nordlander, D. T. Colbert and R. E. Smalley, Science 269, 1550–1553 (1995).
N. de Jonge, Y. Lamy and M. Kaiser, Nano Letters 3, 1621–1624 (2003).
R. G. Lacerda, A. S. Teh, M. H. Yang, K. B. K. Teo, N. L. Rupesinghe, S. H. Dalal, K. K. K. Koziol, D. Roy, G. A. J. Amaratunga, W. I. Milne, M. Chowalla, D. G. Hasko, F. Wyczisk and P. Legagneux, Appl.Phys.Lett. 84, 269–271 (2004).
D. T. Colbert, J. Zhang, S. M. McClure, P. Nikolaev, Z. Chen, J. H. Hafner, D. W. Owens, P. G. Kotula, C. B. Carter, J. H. Weaver, A. G. Rinzler and R. Smalley, Science 266,1218–1222 (1994).
N. de Jonge, M. Doytcheva, M. Allioux, M. Kaiser, S. A. M. Mentink, K. B. K. Teo, R. G. Lacerda and W. Milne, I, Adv.Mater. 17, 451–455 (2005).
N. de Jonge, J.Appl.Phys. 95, 673–681 (2004).
K. Hata, A. Takakura and Y. Saito, Surf.Sci. 490, 296–300 (2001).
R. H. Fowler, L. Nordheim, Proc.Roy.Soc.London A 119, 173–181 (1928).
R. H. Good, E. W. Mueller, Field Emission, ed. S. Fluegge (Springer verlag, 1956) pp. 176–231.
P. W. Hawkes, E. Kasper, Principles of electron optics II: Applied geometrical optics (Academic Press, 1996).
O. Groening, O. M. Kuettel, C. Emmenegger, P. Groening and L. Schlapbach, J.Vac.Sci.Technol.B 18, 665–678 (2000).
N. de Jonge, M. Allioux, M. Doytcheva, M. Kaiser, K. B. K. Teo, R. G. Lacerda and W. Milne, I, Appl.Phys.Lett. 85, 1607–1609 (2004).
R. Gao, Z. Pan and Z. L. Wang, Appl.Phys.Lett. 78, 1757–1759 (2001).
M. Doytcheva, M. Kaiser, M. A. Verheijen, M. Reyes-Reyes, M. Terrones and N. de Jonge, Chem.Phys.Lett. 396, 126–130 (2004).
P. Kruit, G. H. Jansen, Space charge and statistical Coulomb effects, ed. J. Orloff (CRC press, 1997) pp. 275–318.
S. T. Purcell, P. Vincent, C. Journet and V. T. Binh, Phys.Rev.Lett. 88, 105502–1–105502–4 (2002).
J. F. Hainfeld, scanning electron microscopy 1, 591–604 (1977).
V. H. Crespi, N. G. Chopra, M. L. Cohen, A. Zettl and Louie S.G., Phys.Rev.B 54, 5927–5931 (1996).
R. Saito, G. Dresselhaus and M. S. Dresselhaus, Physical properties of carbon nanotubes (Imperial college press, 1998).
T. Paulmier, M. Balat-Pichelin, D. Le Queau, R. Berjoan and J. F. Robert, Appl.Surf.Sci. 180, 227–245 (2001).
Acknowledgments
The authors thank P.A. Barendse, M. Meuwese and M. van Wely-Dieleman for experimental help, T. H. Oosterkamp, S.A.M. Mentink, G. Schwind, G. van Veen and M. v/d Zande for discussions, and A.G. Rinzler for providing the are discharge nanotube sample.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
de Jonge, N., Oostveen, J.T., van Rooij, T. et al. Carbon Nanotube Electron Sources for Electron Microscopes. MRS Online Proceedings Library 858, 295–305 (2004). https://doi.org/10.1557/PROC-858-HH9.1
Published:
Issue Date:
DOI: https://doi.org/10.1557/PROC-858-HH9.1