Abstract
A new class of (meth)acrylate substituted alkoxysilanes has been developed. These are synthesized by addition of the H-S- or H-Si-unit of thiosilanes (e.g. HS- (CH2)3-SiCH3(OCH32)or hydrosila-nes to one (meth) acrylate C=C bond of commercially available di-, tri-, tetra- or penta-(meth)acrylate compounds. The alkoxysilyl groups allow the formation of an inorganic Si-O-Si-network by a hydrolysis and polycondensation reaction (sol-gel process), and the (meth)acrylate groups are available for thermally or photochemical ly induced organic polymerisation. The elegant procedure for the synthesis of a wide variety of multifunctional alkoxysilanes and the preparation of optical lenses will be discussed.
Similar content being viewed by others
References
E. P. Plueddemann, Silane Coupling Agents, Plenum Press, New York (1991)
H. Schmid, B. Seiferiing, G. Philipp, K. Deichmann in: Proc. Int. Congres on Ultrastructure Processing of Ceramics, Glasses and Composites, San Diego, J. D. Mackenzie, D. R. Ulrich (Eds), Mat. Res. Soc. Symp. Proc. (1987) 651
S. Amberg-Schwab, E. Arpac, W. Glaubitt, K. Rose, G. Schottner and U. Schubert in: High Performance Films and Coatings, Ed. P. Vincenzini, Eiservier Science Publ. (1991)
K. Greiwe, Farbe und Lacke 97 (1991) 968
H. Wolter and H. Schmidt, DVS-Berichte 129 (1990) 80; H. Schmidt and H. Wolter, J. Non-Cryst. Solids 121 (1990) 428; M. Popall, J. Kappel, M. Pilz and J. Schulz, VDI-Berichte 933 (1991) 139
H. Wolter, W. Glaubitt and K Rose, Mat. Res. Soc Symp. Proc. (1992), in print
H. Wolter, W. Glaubitt; Berlin. 4. Polymertage (1991) Berliner Verband für Polymerforschung
E. Scholz, Karl Fischer Titration, Springer Verlag, New York (1984) 92
Petrach Systems Si lanes & Silicons, USA
Sartomer Company, Oakland, USA
Acknowledgement
We gratefully thank Ms. H. Bauerlein for her technical assistance.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Wolter, H., Glaubitt, W. & Rose, K. Multifunctional (Meth)Acrylate Alkoxysilanes a New Type of Reactive Compounds. MRS Online Proceedings Library 271, 719–724 (1992). https://doi.org/10.1557/PROC-271-719
Published:
Issue Date:
DOI: https://doi.org/10.1557/PROC-271-719