Abstract
Increased interest in ion conducting thin films and thin-film devices is evidenced by the number of papers on this topic presented at the recent Garmisch conference [1[. Magnetically enhanced (magnetron) sputtering [2,3] is an important technique for depositing these as well as other kinds of ceramic thin films. Two advantages of magnetron over conventional diode sputtering are the increased sputtering rate, which is important in the deposition of ceramic materials, and the reduction in electron bombardment of the substrate and growing film. In this paper, we describe our high-vacuum film growth chamber and present the results of tests of this system in fabricating films of lithium ion conducting glass electrolytes, TiS2, and vanadium oxide by reactive dc and rf magnetron sputtering. The results of combining these films into a thin film lithium battery also are discussed.
Similar content being viewed by others
References
Proceedings of the Sixth International Conference on Solid State Ionics, ed. by H. Schultz and W. Weppner (Garmisch-Partenkirchen, FRG, 1987).
R. K. Waits in Thin Film Processes, ed. by J. L. Vossen and W. Kern (Academic Press, New York, 1978).
B. Chapman, Glow Discharge Processes (Wiley, New York, 1980).
K. Kanehori, K. Matsumoto, K. Miyauchi, and T. Kudo, Solid State Ionics9&10, 1455 (1983).
K. Miyauchi, K. Matsumoto, K. Kanehori, and T. Kudo, Denki Kagaku51, 211 (1983).
K. Miyauchi, T. Oi, and T. Suganuma, U.S. Patent No. 4,390,460 (June 28, 1983).
Y-W. Hu, I. D. Raistrick, and R. A. Huggins, J. Electrochem. Soc. 124, 1240 (1977).
J. I. Goldstein, D. E. Newbury, P. Echlin, D. C. Joy, C. Fiori, and E. Lifshin, Scanning Electron Microscopy and X-ray Microanalysis (Plenum Press, New York, 1981)
K. Sreenivas and M. Sayer, J. Appl. Phys. 64, 1484 (1988).
K. Miyauchi, K. Matsumoto, K. Kandhori, and T. Kudo, Solid State Ionics9/10, 1469 (1983).
K. Kanehori, Y. Ito, F. Kirino, K. Miyauchi, and T. Kudo, Solid State Ionics18/19, 818 (1986).
D. Zehnder, C. Deshpandey, B. Dunn, and R. F. Bunshah, ibid. 18/19, 813 (1986).
C. Aita, Y-L. Liu, M. Kao, and S. D. Hansen, J. Appl. Phys. 60, 749 (1986).
E. Kusano, J. A. Theil, and J. A. Thornton, J. Vac. Sci. Technol. A 6, 1663 (1988).
T. N. Kennedy, R. Hakim, and J. D. Mackenzie, Mat. Res. Sci. Bull. 2, 193 (1967).
J. P. Audiere, A. Madi, and J. C. Grenet, J. Mater. Sci. 17, 2973 (1982).
J. B. MacChesney, J. F. Potter, and H. J. Guggenheim, J. Electrochem. Soc. 115, 52 (1968).
G. A. Rozgonyi and W. J. Polito, J. Electrochem. Soc. 115, 56 (1968).
T. Szorenyi, K. Bali, M. I. Torok, and I. Hevesi, Thin Solid Films121, 29 (1984).
C. Sanchez, J. Kivage, and G. Lucazeau, J. Raman Spectrosc. 12, 68 (1982).
L. Jourdaine, J. L. Souquet, V. Delord, and M. Ribes, “Lithium Solid State Glass Based Microgenerators,” Solid State Ionics, in press (1988).
L. Jourdaine, M. Bonnat, and J. L. Souquet, Solid State Ionics18/19, 461 (1986).
Author information
Authors and Affiliations
Additional information
Research sponsored by the Division of Materials Sciences, U.S. Department of Energy under contract No. ACO5-84OR21400 with Martin Marietta Energy Systems, Inc.
Rights and permissions
About this article
Cite this article
Bates, J.B., Dudney, N.J., Chu, Y.T. et al. Properties of Electrolyte and Electrode Films Prepared by RF and DC Magnetron Sputtering. MRS Online Proceedings Library 135, 143–148 (1988). https://doi.org/10.1557/PROC-135-143
Published:
Issue Date:
DOI: https://doi.org/10.1557/PROC-135-143