Abstract
In this investigation YBa2Cu3O7-δ (YBCO) films were fabricated via a metal acetate, trifluoroacetic acid based sol-gel route and spin-coat deposited on (100) LaAlO3 with a focus on maximizing Jc, while minimizing processing time. We demonstrate that the use of a low-pO2 atmosphere during the pyrolysis stage can lead to at least a tenfold reduction in pyrolysis time, compared to a 1 atm O2 ambient. High-quality YBCO films on LaAlO3, with Jc values up to 3 MA/cm2 at 77 K, can be routinely crystallized from these rapidly pyrolyzed films.
Similar content being viewed by others
References
P.M. Mankiewich, J.H. Scofield, W.J. Skocpol, R.E. Howard, A.H. Dayem, and E. Good, Appl. Phys. Lett. 51, 1753 (1987).
M.P. Siegal, J.M. Phillips, R.B. van Dover, T.H. Tiefel, and J.H. Marshall, J. Appl. Phys. 68, 6353 (1990).
M.P. Siegal, S.Y. Hou, J.M. Phillips, T.H. Tiefel, and J.H. Marshall, J. Mater. Res. 7, 2658 (1992).
F.H. Garzon, J.G. Beery, D.R. Brown, R.J. Sherman, and I.D. Raistrick, Appl. Phys. Lett. 54, 1365 (1989).
S-W. Chan, B.G. Bagley, L.H. Greene, M. Giroud, W.L. Feldmann, K.R. Jenkin II, and B.J. Wilkins, Appl. Phys. Lett. 53, 1443 (1988).
S.Y. Hou, J.M. Phillips, D.J. Werder, T.H. Tiefel, J.H. Marshall, and M.P. Siegal, J. Mater. Res. 9, 1936 (1994).
A. Malecki, J. Oblakowski, and S. Labus, Mater. Res. Bull. 30, 731 (1995).
A. Gupta, R. Jagannathan, E.I. Cooper, E.A. Giess, J.I. Landman, and B.W. Hussey, Appl. Phys. Lett. 52, 2077 (1988).
P.C. McIntyre, M.J. Cima, J.A. Smith Jr ., R.B. Hallock, M.P. Siegal, and J.M. Phillips, J. Appl. Phys. 71, 1868 (1992).
P.C. McIntyre and M.J. Cima, J. Mater. Res. 9, 2219 (1994).
J.A. Smith, M.J. Cima, and N. Sonnenberg, IEEE Trans. Appl. Supercond. 9, 1531 (1999).
P.C. McIntyre, M.J. Cima, and M.F. Ng, J. Appl. Phys. 68, 4183 (1990).
E.M. Gyorgy, R.B. van Dover, K.A. Jackson, L.F. Schneemeyer, and J.V. Waszczak, Appl. Phys. Lett. 55, 283 (1989).
S.A. Krupoder, V.S. Danilovich, A.O. Miller, and G.G. Furin, J. Fluorine Chem. 73, 13 (1995).
D.J. Carlson, M.P. Siegal, J.M. Phillips, T.H. Tiefel, and J.H. Marshall, J. Mater. Res. 5, 2797 (1990).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Dawley, J.T., Clem, P.G., Siegal, M.P. et al. High Jc YBa2Cu3O7-δ films via rapid, low pO2 pyrolysis. Journal of Materials Research 16, 13–16 (2001). https://doi.org/10.1557/JMR.2001.0004
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.2001.0004