Abstract
A discrete heterotrinuclear complex [{Ni2LDy(OAc)3(CH3OH)}2] · 2CH3OH · 3CH2Cl2, with a naphthalenediol-based acyclic bis(salamo) ligand H4L, has been synthesized and structurally characterized using elemental analyses, IR, UV/Vis and fluorescence spectra and single crystal X-ray diffraction. The crystal structure shows two crystallographically independent but chemically identical molecules (molecules I and II). All the Ni(II) atoms are hexa-coordinated with slightly distorted octahedral geometries. The central Dy atoms are nona-coordinated with slightly distorted tricapped trigonal prism geometries. An infinite 3D supramolecular structure is formed via intermolecular hydrogen bonding and C–H…π interactions.
Acknowledgments
This work was supported by the National Natural Science Foundation of China (21361015 and 21761018) and the Program for Excellent Team of Scientific Research in Lanzhou Jiaotong University (201706), which are gratefully acknowledged.
References
[1] S. S. Sun, C. L. Stern, S. T. Nguyen, J. T. Hupp, J. T. Hupp, J. Am. Chem. Soc. 2004, 126, 6314.10.1021/ja037378sSearch in Google Scholar PubMed
[2] L. Zhao, X. T. Dang, Q. Chen, J. X. Zhao, L. Wang, Synth. React. Inorg. Met-Org. Nano-Met. Chem.2013, 43, 1.10.1080/15533174.2011.652275Search in Google Scholar
[3] L. Zhao, L. Wang, Y. X. Sun, W. K. Dong, X. L. Tang, X. H. Gao, Synth. React. Inorg. Met-Org. Nano-Met. Chem.2012, 42, 1303.10.1080/15533174.2012.684235Search in Google Scholar
[4] P. Wang, L. Zhao, Spectrochim. Acta Part A2015, 135, 342.10.1016/j.saa.2014.06.129Search in Google Scholar PubMed
[5] Y. X. Sun, S. T. Zhang, Z. L. Ren, X. Y. Dong, L. Wang, Synth. React. Inorg. Met.-Org. Nano-Met. Chem.2013, 43, 995.10.1080/15533174.2012.753614Search in Google Scholar
[6] X. Y. Dong, Y. X. Sun, L. Wang, L. Li, J. Chem. Res.2012, 36, 387.10.3184/174751912X13366711594575Search in Google Scholar
[7] Y. X. Sun and X. H. Gao, Synth. React. Inorg. Met.-Org. Nano-Met. Chem.2011, 41, 973.10.1080/15533174.2011.591329Search in Google Scholar
[8] Y. X. Sun, L. Xu, T. H. Zhao, S. H. Liu, G. H. Liu, X. T. Dong, Synth. React. Inorg. Met.-Org. Nano-Met. Chem.2013, 43, 509.10.1080/15533174.2012.740756Search in Google Scholar
[9] T. K. Chin, S. Endud, S. Jamil, S. Budagumpi, H. O. Lintang, Catal. Lett.2013, 143, 282.10.1007/s10562-012-0959-1Search in Google Scholar
[10] X. Y. Li, L. Chen, L. Gao, Y. Zhang, S. F. Akogun, W. K. Dong, RSC Adv.2017, 7, 35905.10.1039/C7RA06796HSearch in Google Scholar
[11] W. K. Dong, J. C. Ma, L. C. Zhu, Y. Zhang, X. L. Li, Inorg. Chim. Acta2016, 445, 140.10.1016/j.ica.2016.02.043Search in Google Scholar
[12] S. Ömer, Ö. Ö. Ümmühan, S. Nurgul, A. Burcu, S. Musa, T. Tuncay, S. Zeynel, Tetrahedron2016, 72, 5843.10.1016/j.tet.2016.08.004Search in Google Scholar
[13] W. K. Dong, P. F. Lan, W. M. Zhou, Y. Zhang, J. Coord. Chem.2016, 65, 1272.10.1080/00958972.2016.1168520Search in Google Scholar
[14] L. Q. Chai, G. Wang, Y. X. Sun, W. K. Dong, L. Zhao, X. H. Gao, J. Coord. Chem.2012, 65, 1621.10.1080/00958972.2012.677836Search in Google Scholar
[15] L. Q. Chai, J. J. Huang, H. S. Zhang, Y. L. Zhang, J. Y. Zhang, Y. X. Li, Spectrochim. Acta Part A2014, 131, 526.10.1016/j.saa.2014.04.127Search in Google Scholar PubMed
[16] L. Q. Chai, G. Liu, J. Y. Zhang, J. J. Huang, J. F. Tong, J. Coord. Chem.2013, 66, 3926.10.1080/00958972.2013.857016Search in Google Scholar
[17] L. Q. Chai, H. S. Zhang, J. J. Huang and Y. L. Zhang, Spectrochim. Acta Part A2015, 137, 661.10.1016/j.saa.2014.08.084Search in Google Scholar PubMed
[18] L. Q. Chai, L. J. Tang, L. C. Chen, J. J. Huang, Polyhedron2017, 122, 228.10.1016/j.poly.2016.11.032Search in Google Scholar
[19] L. Q. Chai, K. Y. Zhang, L. J. Tang, J. Y. Zhang, H. S. Zhang, Polyhedron2017, 130, 100.10.1016/j.poly.2017.04.010Search in Google Scholar
[20] L. Chen, W. K. Dong, H. Zhang, Y. Zhang, Y. X. Sun, Cryst. Growth Des.2017, 17, 3636.10.1021/acs.cgd.6b01860Search in Google Scholar
[21] X. Y. Dong, X. Y. Li, L. Z. Liu, H. Zhang, Y. J. Ding, W. K. Dong. RSC Adv.2017, 7, 48394.10.1039/C7RA07826ASearch in Google Scholar
[22] X. Q. Song, Y. J. Peng, G. Q. Chen, X. R. Wang, P. P. Liu, W. Y. Xu, Inorg. Chim. Acta2015, 427, 13.10.1016/j.ica.2014.12.008Search in Google Scholar
[23] H. L. Wu, Y. C. Bai, Y. H. Zhang, Z. Li, M. C. Wu, C. Y. Chen, J. W. Zhang, J. Coord. Chem.2014, 67, 3054.10.1080/00958972.2014.959507Search in Google Scholar
[24] C. Y. Chen, J. W. Zhang, Y. H. Zhang, Z. H. Yang, H. L. Wu, G. L. Pan, Y. C. Bai, J. Coord. Chem.2015, 68, 1054.10.1080/00958972.2015.1007965Search in Google Scholar
[25] H. L. Wu, Y. H. Bai, Y. H. Zhang, G. L. Pan, J. Kong, F. R. Shi, X. L. Wang, Z. Anorg. Allg. Chem.2014, 640, 2062.10.1002/zaac.201400109Search in Google Scholar
[26] H. L. Wu, G. L. Pan, Y. C. Bai, Y. H. Zhang, H. Wang, F. R. Shi, X. L. Wang, J. Kong, J. Photochem. Photobiol. B2014, 135, 33.10.1016/j.jphotobiol.2014.04.005Search in Google Scholar PubMed
[27] H. L. Wu, G. L. Pan, Y. C. Bai, H. Wang, J. Kong, F. R. Shi, Y. H. Zhang, X. L. Wang, J. Chem. Res.2014, 38, 211.10.3184/174751914X13933417974082Search in Google Scholar
[28] H. L. Wu, H. Wang, X. L. Wang, G. L. Pan, F. R. Shi, Y. H. Zhang, Y. C. Bai, J. Kong, New J. Chem.2014, 38, 1052.10.1039/c3nj01145cSearch in Google Scholar
[29] H. L. Wu, G. L. Pan, Y. C. Bai, H. Wang, J. Kong, F. R. Shi, Y. H. Zhang, X. L. Wang, J. Coord. Chem.2013, 66, 2634.10.1080/00958972.2013.812725Search in Google Scholar
[30] H. L. Wu, G. L. Pan, Y. C. Bai, H. Wang, J. Kong, F. R. Shi, Y. H. Zhang, X. L. Wang, Res. Chem. Intermed.2015, 41, 3375.10.1007/s11164-013-1440-5Search in Google Scholar
[31] F. Wang, Y. L. Xu, S. O. Aderinto, H. P. Peng, H. Zhang, H. L. Wu, J. Photochem. Photobiol. A2017, 332, 273.10.1016/j.jphotochem.2016.09.004Search in Google Scholar
[32] H. L. Wu, Y. Bai, J. K. Yuan, H. Wang, G. L. Pan, X. Y. Fan, J. Kong, J. Coord. Chem.2012, 65, 2839.10.1080/00958972.2012.707314Search in Google Scholar
[33] P. P. Liu, C. Y. Wang, M. Zhang, X. Q. Song, Polyhedron2017, 129, 133.10.1016/j.poly.2017.03.019Search in Google Scholar
[34] X. Y. Dong, S. F. Akogun, W. M. Zhou, W. K. Dong, J. Chin. Chem. Soc.2017, 64, 412.10.1002/jccs.201600844Search in Google Scholar
[35] C. H. Tao, J. C. Ma, L. C. Zhu, Y. Zhang, W. K. Dong, Polyhedron2017, 128, 38.10.1016/j.poly.2017.02.040Search in Google Scholar
[36] Y. J. Dong, X. Y. Dong, W. K. Dong, Y. Zhang, L. S. Zhang, Polyhedron2017, 123, 305.10.1016/j.poly.2016.12.010Search in Google Scholar
[37] L. Wang, Q. Zhao, X. Y. Li, G. X. An, W. K. Dong, Z. Naturforsch.2017, 72b, 947.10.1515/znb-2017-0107Search in Google Scholar
[38] H. L. Wu, C. P. Wang, F. Wang, H. P. Peng, H. Zhang, Y. C. Bai, J. Chin. Chem. Soc.2015, 62, 1028.10.1002/jccs.201500121Search in Google Scholar
[39] L. Wang, J. C. Ma, W. K. Dong, L. C. Zhu, Y. Zhang, Z. Anorg. Allg. Chem.2016, 642, 834.10.1002/zaac.201600125Search in Google Scholar
[40] S. Akine, T. Matsumoto, T. Taniguchi, T. Nabeshima, Inorg. Chem.2005, 44, 9.Search in Google Scholar
[41] P. P. Liu, L. Sheng, X. Q. Song, W. Y. Xu, Y. A. Liu, Inorg. Chim. Acta2015, 434, 252.10.1016/j.ica.2015.05.026Search in Google Scholar
[42] X. Q. Song, P. P. Liu, Z. R. Xiao, X. Li, Y. A. Liu, Inorg. Chim. Acta2015, 438, 232.10.1016/j.ica.2015.09.022Search in Google Scholar
[43] Y. A. Liu, C. Y. Wang, M. Zhang, X. Q. Song, Polyhedron2017, 127, 278.10.1016/j.poly.2017.02.007Search in Google Scholar
[44] W. K. Dong, J. C. Ma, L. C. Zhu, Y. Zhang, Cryst. Growth Des.2016, 16, 6903.10.1021/acs.cgd.6b01067Search in Google Scholar
[45] W. K. Dong, J. C. Ma, L. C. Zhu, Y. Zhang, New J. Chem.2016, 40, 6998.10.1039/C6NJ00855KSearch in Google Scholar
[46] H. Zhang, W. K. Dong, Y. Zhang, S. F. Akogun, Polyhedron2017, 133, 279.10.1016/j.poly.2017.05.051Search in Google Scholar
[47] X. Q. Song, P. P. Liu, C. Y. Wang, Y. A. Liu, W. S. Liu, M. Zhang, RSC Adv.2017, 7, 22692.10.1039/C7RA01469DSearch in Google Scholar
[48] J. C. Ma, X. Y. Dong, W. K. Dong, Y. Zhang, L. C. Zhu, J. T. Zhang, J. Coord. Chem.2016, 69, 149.10.1080/00958972.2015.1108410Search in Google Scholar
[49] L. Wang, X. Y. Li, Q. Zhao, L. H. Li, W. K. Dong, RSC Adv.2017, 7, 48730.10.1039/C7RA08789FSearch in Google Scholar
[50] Y. J. Dong, X. L. Li, Y. Zhang, W. K. Dong, Supramol. Chem.2017, 29, 518.10.1080/10610278.2017.1285031Search in Google Scholar
[51] W. K. Dong, J. Zhang, Y. Zhang, N. Li, Inorg. Chim. Acta2016, 444, 95.10.1016/j.ica.2016.01.034Search in Google Scholar
[52] X. Y. Dong, L. Gao, F. Wang, Y. Zhang, W. K. Dong, Crystals2017, 7, 267.10.3390/cryst7090267Search in Google Scholar
[53] W. K. Dong, G. Li, Z. K. Wang, D. X. Yong, Spectrochim. Acta Part A2014, 133, 340.10.1016/j.saa.2014.04.190Search in Google Scholar PubMed
[54] G. M. Sheldrick, Acta Crystallogr.2015, C71, 3.Search in Google Scholar
[55] P. Wang, L. Zhao, Synth. React. Inorg. Met.-Org. Nano-Met. Chem.2016, 46, 1095.10.1080/15533174.2015.1004416Search in Google Scholar
[56] W. K. Dong, Z. K. Wang, G. Li, M. M. Zhao, X. Y. Dong, S. H. Liu, Z. Anorg. Allg. Chem.2013, 639, 2263.10.1002/zaac.201300254Search in Google Scholar
[57] Y. J. Dong, J. C. Ma, L. C. Zhu, W. K. Dong and Y. Zhang, J. Coord. Chem.2017, 70, 103.10.1080/00958972.2016.1262537Search in Google Scholar
[58] W. Wang, Y. Yang, F. X. Wang, W. K. Dong, X. Z. Zhou, Z. Q. Lei, RSC Adv.2015, 5, 17216.10.1039/C4RA14790ASearch in Google Scholar
[59] S. S. Zheng, W. K. Dong, Y. Zhang, L. Chen, Y. J. Ding, New J. Chem.2017, 41, 4966.10.1039/C6NJ04090JSearch in Google Scholar
[60] J. Hao, L. L. Li, J. T. Zhang, F. A. Sunday, L. Wang, W. K. Dong, Polyhedron2017, 134, 1.10.1016/j.poly.2017.05.060Search in Google Scholar
[61] L. Xu, L. C. Zhu, J. C. Ma, Y. Zhang, J. Zhang, W. K. Dong, Z. Anorg. Allg. Chem.2015, 641, 2520.10.1002/zaac.201500619Search in Google Scholar
[62] W. K. Dong, J. T. Zhang, Y. J. Dong, Y. Zhang, Z. K. Wang, Z. Anorg. Allg. Chem.2016, 642, 189.10.1002/zaac.201500751Search in Google Scholar
[63] J. J. Zhou, X. Q. Song, Y. A. Liu, X. L. Wang, RSC Adv.2017, 7, 25549.10.1039/C7RA02386CSearch in Google Scholar
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