Abstract
The ligand 3-(4-(1,3,5-trimethyl-1H-pyrazol-4-yl)phenyl)acetylacetone (1) combines a Pearson hard O,O′ chelating acetylacetone donor with a softer pyrazole N donor bridged by a phenylene spacer. Deprotonation and coordination to CuII leads to a square planar bis-acetylacetonato complex; interpreting the close proximity of an adjacent complex’s pyrazole moiety as an
About the author
Steven van Terwingen fell in love with chemistry in school back in 2010, when exploring dyes and their pH-dependent coloration. After receiving his qualification for higher education at the Nelly-Sachs-Gymnasium in Neuss in July 2013, he started studying chemistry at RWTH Aachen University in October of the same year. In late 2016, he first came into touch with single crystal X-ray diffraction (SCXRD) during a research project in Ulli Englert’s group. He immediately was mesmerized by the absolute nature of this method and proceeded his scientific career with his master thesis under the supervision of Ulli Englert in November 2018. He is currently working on his Ph.D. thesis in the same group, investigating novel heteroditopic ligands for the rational design of bimetallic coordination polymers. He examines these coordination polymers to serve as precursors for heterogeneous catalysts, which can catalyze important decomposition reactions of greenhouse gases to counteract climate change. In the future he hopes to combine his interests in organic chemistry and SCXRD to develop and characterize new pharmaceuticals.
Acknowledgement
S.v.T. gratefully acknowledges an RWTH fellowship for doctoral students.
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: None declared.
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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Supplementary Material
The online version of this article offers supplementary material (https://doi.org/10.1515/zkri-2021-2059).
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