Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter September 24, 2013

High impact toughness of polyamide 6/poly (vinylidene fluoride) blends induced by an ionic liquid

  • Chun Li , Bing Na EMAIL logo , Ruihua Lv , Jie Zhu , Huayan Pan and Zhiwei Yu

Abstract

This study reports the high impact toughness of polyamide 6 (PA6)/poly (vinylidene fluoride) (PVDF) blends achieved via adding an ionic liquid. The presence of the ionic liquid in the blends promotes the transformation of sea-island structure into co-continuous morphology, which to a large extent accounts for the improvement in toughness. In addition, it is believed that the enhanced mobility of the PA6 matrix by the ionic liquid also contributes to the high impact toughness.


Corresponding author: Bing Na, Fundamental Science on Radioactive Geology and Exploration Technology Laboratory, School of Biology, Chemistry and Material Science, East China Institute of Technology, No.418 Guanglan Road, Nanchang, 330013, China, Fax: +86 794 8258320, e-mail: ;

This work is financially supported by the National Natural Science Foundation of China (No. 51163001), the Program for Young Scientists of Jiangxi Province (No. 20112BCB23023) and the Project of Jiangxi Provincial Department of Education (No. GJJ11138).

References

[1] Argon AS, Cohen RE. Polymer 2003, 44, 6013–6032.10.1016/S0032-3861(03)00546-9Search in Google Scholar

[2] Modic MJ, Pottick LA. Polym. Eng. Sci. 1993, 33, 819–826.Search in Google Scholar

[3] Han SY, Ahn TO, Jeong HM. J. Polym. Eng. 2011, 21, 421–444.Search in Google Scholar

[4] Corté L, Rebizant V, Hochstetter G, Tournilhac F, Leibler L. Macromolecules 2006, 39, 9365–9374.10.1021/ma061090gSearch in Google Scholar

[5] Xu W, Lv R, Na B, Tian N, Li Z. J. Appl. Polym. Sci. 2010, 117, 3139–3145.Search in Google Scholar

[6] Lazkano JM, Pena JJ, Munoz ME, Santamaría A. J. Polym. Eng. 2011, 22, 95–114.Search in Google Scholar

[7] González-Montiel A, Keskkula H, Paul DR. J. Polym. Sci. Polym. Phys.1995, 33, 1751–1767.Search in Google Scholar

[8] Huang JJ, Paul DR. Polymer 2006, 47, 3505–3519.10.1016/j.polymer.2006.03.038Search in Google Scholar

[9] Yu ZZ, Lei M, Ou Y, Yang G. J. Appl. Polym. Sci. 2003, 89, 797–805.Search in Google Scholar

[10] Cui L, Yeh JT, Wang K, Fu Q. J. Polym. Sci. Polym. Phys. 2008, 46, 1360–1368.Search in Google Scholar

[11] Liu ZH, Maréchal Ph, Jérôme R. Polymer 1998, 39, 1779–1785.10.1016/S0032-3861(97)00222-XSearch in Google Scholar

[12] Na B, Xu W, Lv R, Li Z, Tian N, Zou S. Macromolecules 2010, 43, 3911–3915.10.1021/ma1002744Search in Google Scholar

[13] Kim KJ, Cho HW, Yoon KJ. Eur. Polym. J. 2003, 39, 1249–1265.Search in Google Scholar

[14] Vo LT, Giannelis EP. Macromolecules 2007, 40, 8271–8276.10.1021/ma071508qSearch in Google Scholar

[15] Lu L, Chen W. Adv. Mater. 2010, 22, 3745–3748.Search in Google Scholar

[16] Kubisa P. Prog. Polym. Sci. 2004, 29, 3–12.Search in Google Scholar

[17] Zhang G, Liu X, Li B, Bai Y. J. Appl. Polym. Sci. 2009, 112, 3337–3340.Search in Google Scholar

[18] Cong H, Yu B, Tang J, Zhao XS. J. Polym. Res. 2012, 19, 9761.Search in Google Scholar

[19] Brazel CS, Rogers RD. Ed., Ionic Liquids in Polymer Systems: Solvents, Additives and Novel Applications, ACS Symp. Ser. 2005, 913.10.1021/bk-2005-0913Search in Google Scholar

[20] Lu J, Yan F, Texter J. Prog. Polym. Sci. 2009, 34, 431–448.Search in Google Scholar

[21] Singh PK, Kim KW, Rhee HW. Polym. Eng. Sci. 2009, 49, 862–865.Search in Google Scholar

[22] Yoon J, Lee HJ, Stafford CM. Macromolecules 2011, 44, 2170–2178.10.1021/ma102682kSearch in Google Scholar

[23] Scott MP, Rahman M, Brazel CS. Eur. Polym. J. 2003, 39, 1947–1953.Search in Google Scholar

[24] Park K, Ha JU, Xanthos M. Polym. Eng. Sci. 2010, 50, 1105–1110.Search in Google Scholar

[25] Zhao L, Li Y, Cao X, You J, Dong W. Nanotechnology 2012, 23, 255702.10.1088/0957-4484/23/25/255702Search in Google Scholar PubMed

[26] Ueki T, Watanabe M. Bull. Chem. Soc. Jpn. 2012, 85, 33–50.Search in Google Scholar

[27] Paul DR, Barlow JW. J. Macromol. Sci. Rev. Macromol. Chem. 1980, C18, 109–168.Search in Google Scholar

[28] Zhang CL, Feng LF, Zhao J, Huang H, Hoppe S, Hu GH. Polymer 2008, 49, 3462–3469.10.1016/j.polymer.2008.06.003Search in Google Scholar

[29] Lee JK, Han CD. Polymer 1999, 40, 6277–6296.10.1016/S0032-3861(99)00022-1Search in Google Scholar

[30] Li Y, Shimizu H. Macromolecules 2008, 41, 5339–5344.10.1021/ma8006834Search in Google Scholar

[31] Shah D, Maiti P, Gunn E, Schmidt DF, Jiang DD, Batt CA, Giannelis EP. Adv. Mater. 2004, 16, 1173–1177.Search in Google Scholar

[32] Yu W, Zhao Z, Zheng W, Song Y, Li B, Long B, Jiang Q. Mater. Lett. 2008, 62, 747–750.Search in Google Scholar

[33] Vijayakumar RP, Khakhar DV, Misra A. J. Polym. Sci. Polym. Phys. 2011, 49, 1339–1344.Search in Google Scholar

[34] Jansen JC, Friess K, Clarizia G, Schauer J, Izák P. Macromolecules 2011, 44, 39–45.10.1021/ma102438kSearch in Google Scholar

[35] Okada T, Saito H, Inoue T. Macromolecules 1990, 23, 3865–3868.10.1021/ma00218a024Search in Google Scholar

[36] Chang JY, Hong JL. Polymer 2000, 41, 4513–4521.10.1016/S0032-3861(99)00616-3Search in Google Scholar

Received: 2013-4-24
Accepted: 2013-8-28
Published Online: 2013-09-24
Published in Print: 2013-11-01

©2013 by Walter de Gruyter Berlin Boston

Downloaded on 19.4.2024 from https://www.degruyter.com/document/doi/10.1515/polyeng-2013-0103/html
Scroll to top button