Darstellung und Charakterisierung von Berlinerblau-Analoga des Typs Ti[MB(CN)6] / Preparation and Characterization of Prussian Blue Analogs of the Type Ti[MB(CN)6]

Hidenari Inoue; Ekkehard Fluck

doi:10.1515/znb-1984-0211

Open Access Published by De Gruyter June 2, 2014

Darstellung und Charakterisierung von Berlinerblau-Analoga des Typs Ti[M^B(CN)₆] / Preparation and Characterization of Prussian Blue Analogs of the Type Ti[M^B(CN)₆]

Hidenari Inoue and Ekkehard Fluck

From the journal Zeitschrift für Naturforschung B

https://doi.org/10.1515/znb-1984-0211

Three compounds of the type Ti[M^B(CN)₆] (M^B = Co, Rh, and Ir) have been synthesized and characterized by means of their X-ray diffraction powder patterns, magnetic measurements, infrared, electronic, and X-ray photoelectron spectra. All compounds crystallize in the facecentered cubic system and form a three-dimensional framework of two octahedral coordination units M^BC₆ and TiN₆. Upon the formation of Ti[M^B(CN)₆] from the corresponding potassium salt, the π back-donation in the [M^B(CN)₆]^3- moiety is enhanced by the bridge formation through the cyanide ligand

: Preparation; Characterization; Prussian Blue Analogs

Received: 1983-10-12

Published Online: 2014-6-2

Published in Print: 1984-2-1

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Darstellung und Charakterisierung von Berlinerblau-Analoga des Typs Ti[M^B(CN)₆] / Preparation and Characterization of Prussian Blue Analogs of the Type Ti[M^B(CN)₆]

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