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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Darstellung und Kristallstruktur vom Arsen(III)arsen(V)oxidhydroxid As3O5(0H) / Preparation and Crystal Structure of the Arsenic(III) Arsenic(V) Oxide Hydroxide As3O5(OH)

  • Doris Bodenstein , Axel Brehm , Peter G. Jones , Einhard Schwarzmann and George M. Sheldrick
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1982-0204
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Abstract

The title compound was prepared by heating the hydrolysis products of AS2O4 in a sealed tube. The crystal structure was determined and refined to R = 0.058 [P21/c, a = 1250.4(6), b = 459.3(2), c = 1097.6(6) pm, β = 118.08(5)°, Z = 4]. The structure consists of infinite layers, containing pyramidal As(III)O3 and tetrahedral As(V)O4 groups, and stabilised by hydrogen bonding

Keywords: Sealed-Tube Synthesis; Crystal Structure; Arsenic; Oxide
Received: 1981-10-7
Published Online: 2014-6-2
Published in Print: 1982-2-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 37 Issue 2

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