Abstract
This paper analyzes the applications of various ionic liquids (ILs) as metal ion carriers and extractants utilized for the separation of metal cations from aqueous solutions. Subsequently, an up-to-date review of the use of ILs in polymer inclusion membranes is presented. ILs represent a promising group of extractants and ion carriers of metal ions in extraction and membrane separation processes. The removal of heavy metals ions from aqueous solutions using ILs indicates an extensive and promising research area. It is expected that the role of ILs will gradually increase as the worldwide implementation of separation methods in recovery of metal ions from various aqueous solutions is growing quickly.
About the authors
Beata Pospiech studied at the Pedagogical University in Czestochowa, Poland, where she obtained her Master’s degree in Chemistry in 2000. She received her PhD degree in 2005 at Czestochowa University of Technology, Poland. At present, she works in the Department of Chemistry. Her research is focused on the hydrometallurgical recovery of nonferrous metals, especially on the separation of metal ions from aqueous solutions by SX and transport across PIMs containing various compounds as ion carriers.
Wojciech Kujawski graduated from Nicolaus Copernicus University in Torun, Poland, where studied for his PhD thesis. Subsequently, he prepared his habilitation thesis both in Poland (DSc, Technical University in Szczecin, 2008) and in France (HDR de Université Montpellier 2, 2011). He is a faculty member (associated professor since 2012) at the Faculty of Chemistry NCU, Torun. He has (co-)authored ca. 100 papers related to membranes and membrane separation techniques. His research interest is focused mainly on physical chemistry of membrane processes, ion-exchange membranes, task-specific membranes, ILs, modification of polymeric and ceramic membranes, biofuels, and bio-energy.
References
Alguacil FJ, Alonso M, Lopez FA, Lopez-Delgado A. Application of pseudo-emulsion based hollow fiber strip dispersion (PEHFSD) for recovery of Cr(III) from alkaline solutions. Sep Purif Technol 2009; 66: 586–590.10.1016/j.seppur.2009.01.012Search in Google Scholar
Alguacil FJ, Alonso M, Lopez FA, Lopez-Delgado A. Pseudo-emulsion membrane strip dispersion (PEMSD) pertraction on chromium(VI) using Cyphos IL 101 ionic liquid as carrier. Environ Sci Technol 2010a; 44: 7504–7508.10.1021/es101302bSearch in Google Scholar
Alguacil FJ, Alonso M, Lopez FA, Lopez-Delgado A, Padilla I, Tayibi H. Pseudo-emulsion based hollow fiber with strip dispersion pertraction of iron(III) using (PJMTH+)2(SO42-) ionic liquid as carrier. Chem Eng J 2010b; 157: 272–276.10.1016/j.cej.2009.11.016Search in Google Scholar
Alonso FT, Rubio AM, Alvarez R, Ortuno JA. Dynamic potential response and SEM-EDX studies of polymeric inclusion membranes based on ionic liquids. Int J Electrochem Sci 2013; 8: 4955–4969.Search in Google Scholar
Baczynska M, Regel-Rosocka M, Wisniewski M. Removal of Zn(II) from aqueous chloride solutions with polymer inclusion membranes. In: Konieczny K, Korus I, editors. Membranes and membrane processes in environmental protection. Polish Academy of Sciences: Warsaw, Gliwice, 2014, 118: 139–148.Search in Google Scholar
Bari MF, Hossain MS, Mujtaba IM, Jamaluddin SB, Hussin K. Simultaneous extraction and separation of Cu(II), Zn(II), Fe(II) and Ni(II) by polystyrene microcapsules coated with Cyanex 272. Hydrometallurgy 2009; 95: 308–315.10.1016/j.hydromet.2008.07.003Search in Google Scholar
Beltrami D, Cote G, Mokhtari H, Courtaud B, Chagnes A. Modeling of the extraction of uranium (VI) from concentrated phosphoric acid by synergistic mixtures of bis-(2-ethylhexyl)-phosphoric acid and tri-n-octylphosphine oxide. Hydrometallurgy 2012; 129–130: 118–125.10.1016/j.hydromet.2012.09.005Search in Google Scholar
Benosmane N, Hamdi S, Hamdi M, Boutemeur B. Selective transport of metal ions across polymer inclusion membranes (PIMs) containing calix[4]resorcinarenes. Sep Pur Technol 2009; 65: 211–219.10.1016/j.seppur.2008.10.039Search in Google Scholar
Blith-Raith AH, Paimin R, Cattrall RW, Kolev SD. Separation of cobalt(II) and nickel(II) by solid phase extraction into Aliquat 336 chloride immobilized in poly(vinyl chloride). Talanta 2007; 71: 419–423.10.1016/j.talanta.2006.04.017Search in Google Scholar
Cholico-Gonzales D, Avila-Rodriguez M, Reyes-Aguilera JA, Cote G, Chagnes A. Rheological behaviour of binary mixtures containing. hexyl(tetradecyl)phosphonium chloride (Cyphos IL 101) and bis(2,4,4-trimethylpentyl)phosphinic acid (Cyanex 272) between 288.15 K and 343.15 K. J Mol Liq 2012; 169: 27–32.Search in Google Scholar
Cieszynska A, Wisniewski M. Selective extraction of palladium(II) from hydrochloric acid solutions with phosphonium extractants. Sep Purif Technol 2011; 80: 385–389.10.1016/j.seppur.2011.05.025Search in Google Scholar
Coll MT, Fortuny A, Kedari CS, Sastre AM. Studies on the extraction of Co(II) and Ni(II) from aqueous chloride solutions using Primene JMT-Cyanex 272 ionic liquid extractant. Hydrometallurgy 2012; 125–126: 24–28.10.1016/j.hydromet.2012.05.003Search in Google Scholar
Cussler EL, Aris R, Bhown A. On the limits of diffusion. J Membr Sci 1989; 43: 149–164.10.1016/S0376-7388(00)85094-2Search in Google Scholar
Danesi PR. Separation of metal species by supported liquid membranes. Sep Sci Technol 1984; 19: 857–894.10.1080/01496398408068598Search in Google Scholar
De Agreda I, Garcia-Diaz F, López, Alguacil FJ. Supported liquid membranes technologies in metals removal from liquid effluents. Rev Metall 2011; 47: 146–168.10.3989/revmetalmadrid.1062Search in Google Scholar
De Los Rios AP, Hernandez-Fernandez J, Alguacil FJ, Lozano LJ, Ginesta A, Garcia-Diaz I, Sanchez-Segado S, Lopez FA, Godinez C. On the use of imidazolium and ammonium-based ionic liquids as green solvents for the selective recovery of Zn(II), Cd(II), Cu(II) and Fe(III) from hydrochloride aqueous solutions. Sep Purif Technol 2012; 97: 150–157.10.1016/j.seppur.2012.02.040Search in Google Scholar
De San Miguel ER, Monroy-Baretto M, Aguilar JC, Ocampo AL, de Gyves J. Structural effects on metal ion migration across polymer inclusion membranes: dependence of membrane properties and transport profiles on the weight and volume fractions of the components. J Membr Sci 2011; 379: 416–425.10.1016/j.memsci.2011.06.013Search in Google Scholar
Dietz ML, Stepinski DC. Anion concentration-dependent partitioning mechanism in the extraction of uranium into room-temperature ionic liquids. Talanta 2008; 75: 598–603.10.1016/j.talanta.2007.11.051Search in Google Scholar PubMed
Domanska U, Rekawek A. Extraction of metal ions from aqueous solutions using imidazolium based ionic liquids. J Solution Chem 2009; 38: 739–751.10.1007/s10953-009-9402-7Search in Google Scholar
Ferreira AR, Neves LA, Riberio JC, Lopes FM, Coutinho JAP, Coelhoso IM, Crespo JG. Removal of thiols from model jet-fuel streams assisted by ionic liquid membrane extraction. Chem Eng J 2014; 256: 144–154.10.1016/j.cej.2014.06.107Search in Google Scholar
Fisher L, Falta T, Koellensperger G, Stojanivic A, Kogelnig D, Galanski M, Krachler R, Keppler BK, Hann S. Ionic liquids for extraction of metals and metal containing compounds from communal and industrial waste water. Water Res 2011; 45: 4601–4614.10.1016/j.watres.2011.06.011Search in Google Scholar PubMed
Fontas C, Tayeb R, Dhahbi M, Gaudichet E, Thominette F, Roy P, Stenkeste K, Fontaine-Aupart MP, Tingry S, Tronel-Peyroz E, Seta P. Polymer inclusion membranes: the concept of fixed sites membrane revised. J Membr Sci 2007; 290: 62–72.10.1016/j.memsci.2006.12.019Search in Google Scholar
Fortunato R, Afonso CAM, Reis MA, Crespo JG. Supported liquid membranes using ionic liquids: study of stability and transport mechanisms. J Membr Sci 2004; 242: 197–209.10.1016/j.memsci.2003.07.028Search in Google Scholar
Fortunato R, Gonzales-Munoz MJ, Kubasiewicz M, Luque S, Alvarez JR, Afonso CA, Coelhoso IM, Crespo JG. Liquid membranes using ionic liquids: the influences of water on solute transport. J Membr Sci 2005; 249: 153–162.10.1016/j.memsci.2004.10.007Search in Google Scholar
Fortuny A, Coll MT, Sastre AM. Use of methyltrioctyl/decylammonium bis 2,4,4-(trimethylpentyl)phosphinate ionic liquid (ALiCY IL) on the boron extraction in chloride media. Sep Purif Technol 2012; 97: 137–141.10.1016/j.seppur.2012.02.037Search in Google Scholar
Fuerhacker M, Haile TM, Kogelnig D, Stojanovic A, Keppler B. Application of ionic liquids for the removal of heavy metals from wastewater and activated sludge. Water Sci Technol 2012; 65: 1765–1773.10.2166/wst.2012.907Search in Google Scholar PubMed
Gajda B, Bogacki M. The application of polymer inclusive membranes for removal of heavy metal ions from waste solutions. J Achievements Mater Manufacturing Eng 2012; 55: 673–678.Search in Google Scholar
Gega J, Otrembska P. Separation of Ni(II) and Cd(II) ions with supported liquid membranes (SLM) using D2EHPA as a carrier. Sep Sci Technol 2014; 49: 1756–1760.10.1080/01496395.2014.906463Search in Google Scholar
Genand-Pinaz S, Papaiconomou N, Leveque JM. Removal of platinum from water by precipitation or liquid-liquid extraction and separation from gold using ionic liquids. Green Chem 2013; 15: 2493–2501.10.1039/c3gc40557eSearch in Google Scholar
Gherasim CV, Cristea M, Grigoras CV, Bourceanu G. New polymer inclusion membrane. Preparation and characterization. Dig J Nanomater Bios 2011; 6: 1499–1508.Search in Google Scholar
Gherrou A, Kerdjoudj H, Molinari R, Seta P. Preparation and characterization of polymeric plasticized membranes (PPM) embedding a crown ether carrier application to copper ions transport. Mater Sci Eng C 2005; 25: 436–443.10.1016/j.msec.2004.11.002Search in Google Scholar
Gizli N, Cinarli S, Demircioglu M. Characterization of poly(vinylchloride) (PVC) based cation exchange membranes prepared with ionic liquids. Sep Purif Technol 2012; 97: 96–107.10.1016/j.seppur.2012.02.028Search in Google Scholar
Guo L, Liu Y, Zhang C, Chen J. Preparation of PVDF-based polymer inclusion membrane using ionic liquid plasticizer and Cyphos IL 104 carrier for Cr(VI) transport. J Membr Sci 2011; 372: 314–321.10.1016/j.memsci.2011.02.014Search in Google Scholar
Hawkins CA, Garvey SL, Dietz ML. Structural variations in room-temperature ionic liquids: influence on metal ion partitioning modes and extraction selectivity. Sep Purif Technol 2012; 89: 31–38.10.1016/j.seppur.2011.12.004Search in Google Scholar
Hosseini T, Mostoufi N, Daneshpayeh M, Rashchi F. Modeling and optimization of synergistic effect of Cyanex 302 and D2EHPA on separation of zinc and manganese. Hydrometallurgy 2011; 105: 277–283.10.1016/j.hydromet.2010.10.015Search in Google Scholar
Ines M, Almeida GS, Cattrall RW, Kolev SD. Recent trends in extraction and transport of metal ions using polymer inclusion membranes (PIMs). J Membr Sci 2012; 415–416: 9–23.10.1016/j.memsci.2012.06.006Search in Google Scholar
Janssen CHC, Sanchez A, Witkamp GJ, Kobrak MN. A novel mechanism for the extraction of metals from water to ionic liquids. ChemPhysChem 2013; 14: 3806–3813.10.1002/cphc.201300686Search in Google Scholar
Kagaya S, Cattrall RW, Kolev SD. Solid-phase extraction of cobalt(II) from lithium chloride solutions using a poly(vinyl chloride)-based polymer inclusion membrane with Aliquat 336 as the carrier. Anal Sci 2011; 27: 653–657.10.2116/analsci.27.653Search in Google Scholar
Kang J, Senanayake G, Sohn J, Shin SM. Recovery of cobalt sulfate from spent lithium ion batteries by reductive leaching and solvent extraction with Cyanex 272. Hydrometallurgy 2001; 100: 168–171.10.1016/j.hydromet.2009.10.010Search in Google Scholar
Kebiche-Senhadji O, Tingry S, Seta P, Benamor M. Selective extraction of Cr(VI) over metallic species by polymer inclusion membrane (PIM) using anion (Aliquat 336) as carrier. Desalination 2010; 258: 59–65.10.1016/j.desal.2010.03.047Search in Google Scholar
Kislik V, editor. Liquid membranes: principles and application in chemical separations and wastewater treatment, Elsevier Science Publisher: Oxford, 2009.Search in Google Scholar
Kogelnig D., Stojanovic A., Galanski M, Grossl M, Jirsa F, Krachler R, Keppler BK. Greener synthesis of new ammonium ionic liquids and their potential as extraction agents. Tetrahedron Lett 2008; 49: 2782–2785.10.1016/j.tetlet.2008.02.138Search in Google Scholar
Kogelnig D, Stojanovic A, Jirsa F, Korner W, Krachler R, Keppler BK. Transport and separation of iron(III) from nickel(II) with the ionic liquid trihexyl(tetradecyl)phosphonium chloride. Sep Purif Technol 2010; 72: 56–60.10.1016/j.seppur.2009.12.028Search in Google Scholar
Kogelnig D, Regelsberger A, Stojanovic A, Jirsa F, Krachler R, Keppler BK. A polymer inclusion membrane based on the ionic liquid trihexyl(tetradecyl)phosphonium chloride and PVC for solid-liquid extraction of Zn(II) from hydrochloric acid solution. Monatsh Chem 2011; 142: 769–772.10.1007/s00706-011-0530-6Search in Google Scholar
Kolev SD, Sakai Y, Cattrall RW, Paimin R, Potter ID. Theoretical and experimental study of palladium(II) extraction from hydrochloric acid solutions into Aliquat 336/PVC membranes. Anal Chim Acta 2000; 413: 241–246.10.1016/S0003-2670(00)00811-4Search in Google Scholar
Lamb JD, Nazarenko AY, Uenishi J, Tsukube H. Silver(I) ion-selective transport across polymer inclusion membranes containing new pyridino- and bipyridino-podands. Anal Chim Acta 1998; 373: 167–173.10.1016/S0003-2670(98)00360-2Search in Google Scholar
Lee JM. Extraction of noble metal ions from aqueous solution by ionic liquids. Fluid Phase Equilib 2012; 319: 30–36.10.1016/j.fluid.2012.01.033Search in Google Scholar
Lee JY, Kumar RJ, Kim JS, Kim DJ, Yoon HS. Extraction and separation of Pt(IV)/Rh(III) from acidic chloride solutions using Aliquat 336. J Ind Eng Chem 2009; 15: 359–364.10.1016/j.jiec.2008.12.006Search in Google Scholar
Lozano LJ, Godinez C, Rios AP, Hernandez-Fernandez FJ. Review: recent advances in supported liquid membrane technology. J Membr Sci 2011; 376: 1–14.10.1016/j.memsci.2011.03.036Search in Google Scholar
Luo H, Dai S, Bonnesen PV. Solvent extraction of Sr2+ and Cs+ based on room temperature ionic liquids monoaza-substituted crown ethers. Anal Chem 2004; 76: 2773–2779.10.1021/ac035473dSearch in Google Scholar PubMed
Malik MA, Hashim M, Nabi F. Ionic liquids in supported liquid membrane technology. Chem Eng J 2011; 171: 242–254.10.1016/j.cej.2011.03.041Search in Google Scholar
Matsumoto H, Sakaebe H, Tatsumi K. Preparation of room temperature ionic liquids based on aliphatic cations and asymmetric amide anions and their electrochemical properties as a lithium battery electrolyte. J Power Sources 2005; 146: 45–50.10.1016/j.jpowsour.2005.03.103Search in Google Scholar
Meindersma GW, Galan Sanchez LM, Hansmeier AR, Haan AB. Application of task-specific ionic liquids for intensified separations. Monatsh Chem 2007; 138: 1125–1136.10.1007/s00706-007-0757-4Search in Google Scholar
Mishra S, Devi N. Extraction of copper(II) from hydrochloric acid solution by Cyanex 921. Hydrometallurgy 2011; 107: 29–33.10.1016/j.hydromet.2010.12.016Search in Google Scholar
Mishra RK, Rout PC, Sarangi K, Nathsarma KC. Solvent extraction of Fe(III) from the chloride leach liquor of low grade iron ore tailing using Aliquat 336. Hydrometallurgy 2011; 108: 93–99.10.1016/j.hydromet.2011.03.003Search in Google Scholar
Nakashima K, Kubota F, Maruyama T, Goto M. Feasibility of ionic liquids as alternative separation media for industrial solvent extraction processes. Ind Eng Chem Res 2005; 44: 4368–4372.10.1021/ie049050tSearch in Google Scholar
Nathsarma KC, Devi N. Separation of Zn(II) and Mn(II) from sulphate solutions using sodium salts of D2EHPA, PC 88A and Cyanex 272. Hydrometallurgy 2006; 84: 149–154.10.1016/j.hydromet.2006.05.004Search in Google Scholar
Nayl AA. Extraction and separation of Co(II) and Ni(II) from acidic sulfate solutions using Aliquat 336. J Hazard Mater 2010; 173: 223–230.10.1016/j.jhazmat.2009.08.072Search in Google Scholar
Nghiem LD, Mornane P, Potter JD, Perera JM, Cattrall RW, Kolev SD. Extraction and transport of metal ions and small organic compounds using polymer inclusion membranes (PIMs). J Membr Sci 2006; 281: 7–41.10.1016/j.memsci.2006.03.035Search in Google Scholar
Nowak L, Regel-Rosocka M, Marszałkowska B, Wisniewski M. Removal of Zn(II) from chloride acidic solutions with hydrophobic quaternary salts. Pol J Chem Technol 2010; 12: 24–28.10.2478/v10026-010-0028-8Search in Google Scholar
O’Rourke M, Duffy N, De Marco R, Potter I. Electrochemical impedance spectroscopy – a simple method for the characterization of polymer inclusion membranes containing Aliquat 336. Membranes 2011; 1: 132–148.10.3390/membranes1020132Search in Google Scholar
Papaiconomou N, Lee JM, Salminem J, Stosch M, Prausnitz JM. Selective extraction of copper, mercury, silver, and palladium ions from water using hydrophobic ionic liquids. Ind Eng Chem Res 2007; 47: 5080–5086.10.1021/ie0706562Search in Google Scholar
Pereira N, John A, Cattrall RW. Influence of the composition of polymer inclusion membranes on their homogeneity and flexibility. Desalination 2009; 236: 327–333.10.1016/j.desal.2007.10.083Search in Google Scholar
Perez MA, Marin LP, Quintana JC, Yazdani-Pedram M. Influence of different plasticizers on the response of chemical sensors based on polymeric membranes for nitrate ion determination. Sens Actuators B 2003; 89: 262–268.10.1016/S0925-4005(02)00475-6Search in Google Scholar
Pernak J. Ionic liquids. Compounds for 21st century. Przem Chem 2003; 82: 521–524.Search in Google Scholar
Pernak J. Ionic liquids as a multifunctional compounds. Przem Chem 2010; 11: 1499–1503.Search in Google Scholar
Pitsch F, Krull FF, Agel F, Schulz P, Wasserscheid P, Melin T, Wessling M. An adaptive self-healing ionic liquid nanocomposite membrane for olefin-paraffin separations. Adv Mater 2012; 24: 4306–4310.10.1002/adma.201201832Search in Google Scholar PubMed
Pospiech B. Separation of silver(I) and copper(II) from aqueous solutions by transport through polymer inclusion membranes with Cyanex 471X. Sep Sci Technol 2012; 47: 1413–1419.10.1080/01496395.2012.672521Search in Google Scholar
Pospiech B. Hydrometallurgical recovery of cobalt(II) from acidic chloride solutions by transport through polymer inclusion membranes. Physicochem Probl Miner Process 2013; 49: 641–649.Search in Google Scholar
Pospiech B. Synergistic solvent extraction and transport of Zn(II) and Cu(II) across polymer inclusion membranes with a mixture of TOPO and Aliquat 336. Sep Sci Technol 2014a; 49: 1706–1712.10.1080/01496395.2014.906456Search in Google Scholar
Pospiech B. Selective recovery of cobalt(II) towards lithium(I) from chloride media by transport across polymer inclusion membrane with triisooctylamine. Pol J Chem Technol 2014b; 16: 15–20.10.2478/pjct-2014-0003Search in Google Scholar
Pospiech B. Highly efficient facilitated membrane transport of palladium(II) ions from hydrochloric acid solutions through plasticizer membranes with Cyanex 471X. Physicochem Probl Miner Process 2015; 51: 281–291.Search in Google Scholar
Pospiech B, Walkowiak W. Separation of copper(II), cobalt(II) and nickel(II) from chloride solutions by polymer inclusion membranes. Sep Purif Technol 2007; 57: 461–468.10.1016/j.seppur.2006.07.005Search in Google Scholar
Pospiech B, Walkowiak W. Application of trioctylphosphine oxide for separation of metal ions from aqueous solutions. Przem Chem 2009; 2: 168–171.Search in Google Scholar
Pospiech B, Walkowiak W. Studies on iron(III) removal from chloride aqueous solutions by solvent extraction and transport through polymer inclusion membranes with D2EHPA. Physicochem Probl Miner Process 2010; 44: 195–204.Search in Google Scholar
Pospiech B, Walkowiak W, Wozniak MJ. Application of TBP in selective removal of iron(III) in solvent extraction and transport through polymer inclusion membranes. Physicochem Probl Miner Process 2005; 39: 89–98.Search in Google Scholar
Radzyminska-Lenarcik E, Ulewicz M. The use of 1-alkylimidzoles for selective separation of zinc ions in the transport process across a polymeric inclusion membrane. Physicochem Probl Miner Process 2014; 51: 131–142.Search in Google Scholar
Rahman M, Brazel Ch. Ionic liquids: new generation stable plasticizers for poly(vinyl chloride). Polym Degrad Stabil 2006; 91: 3371–3382.10.1016/j.polymdegradstab.2006.05.012Search in Google Scholar
Reddy BR, Priya DN, Kumar JR. Solvent extraction of cadmium(II) from sulphate solutions using TOPS 99, PC 88A, Cyanex 272 and their mixtures. Hydrometallurgy 2004; 74: 277–283.10.1016/j.hydromet.2004.06.001Search in Google Scholar
Regel-Rosocka M, Nowak L, Wisniewski M. Removal of Zn(II) and iron ions from chloride solutions with phosphonium ionic liquids. Sep Purif Technol 2012; 97: 158–163.10.1016/j.seppur.2012.01.035Search in Google Scholar
Regel-Rosocka M, Wisniewski M. Selective removal of zinc(II) from spent pickling solutions in the presence of iron ions with phosphonium ionic liquid Cyphos IL 101. Hydrometallurgy 2011; 110: 85–90.10.1016/j.hydromet.2011.08.012Search in Google Scholar
Rout A, Venkatesan KA, Srinivasan TG, Vasudeva PR. Ionic liquid extractants in molecular diluents: Extraction behavior of europium(III) in quarternary ammonium-based ionic liquids. Sep Purif Technol 2012; 95: 26–31.10.1016/j.seppur.2012.04.020Search in Google Scholar
Rout A, Kotlarska J, Dehaen W, Binnemans K. Liquid-liquid extraction of neodymium(III) by dialkylphosphate ionic liquids from acidic medium: the importance of the ionic liquid cation. Phys Chem Chem Phys 2013; 15: 16533–16541.10.1039/c3cp52218kSearch in Google Scholar PubMed
Rybka P, Regel-Rosocka M. Nickel(II) and cobalt(II) extraction from chloride solutions with quaternary phosphonium salts. Sep Sci Technol 2012; 47: 1296–1302.10.1080/01496395.2012.672532Search in Google Scholar
Salazar-Alvarez G, Bautista-Flores AN, De San Miguel R. Transport characterisation of a PIM system used for the extraction of Pb(II) using D2EHPA as carrier. J Membr Sci 2005; 240: 247–257.10.1016/j.memsci.2004.09.048Search in Google Scholar
Sastre AM, Kumar A, Shukla JP, Singh RK. Improved techniques in liquid membrane separations: an overview. Sep Purif Methods 1998; 27: 213–298.10.1080/03602549809351641Search in Google Scholar
Savant AD, Raut DG, Darvatkar NB, Salunkhe MM. Recent developments of task-specific ionic liquids in organic synthesis. Green Chem Lett Rev 2011; 4: 41–54.10.1080/17518253.2010.500622Search in Google Scholar
Shimojo K, Goto M. Solvent extraction and stripping of silver ions in room temperature ionic liquids containing calixarenes. Anal Chem 2004; 76: 5039–5044.10.1021/ac049549xSearch in Google Scholar
Show A, Peterson RT, Lamb JD. Polymer inclusion membranes containing macrocyclic carriers for use in cation separations. J Membr Sci 1996; 111: 291–298.10.1016/0376-7388(95)00295-2Search in Google Scholar
Skouta R. Selective chemical reactions in supercritical carbon dioxide, water, and ionic liquids. Green Chem Lett Rev 2009; 4: 121–156.10.1080/17518250903230001Search in Google Scholar
Stojanovic A, Morgenbesser C, Kogelnig D, Krachler R, Keppler BK, Kokorin A. Quaternary ammonium and phosphonium ionic liquids in chemical and environmental engineering. In: Kokorin A, editor. Ionic liquids: theory, properties, new approaches. Shanghai: In Tech, 2011: 657–680.Search in Google Scholar
Sugiura M, Kikkawa M, Urita S. Effect of plasticizer on carrier-mediated transport of zinc ion through cellulose triacetate membranes. Sep Sci Technol 1987; 22: 2263–2268.10.1080/01496398708068612Search in Google Scholar
Sun X, Pen B, Chen J, Li DeQ, Luo F. An effective method for enhancing metal-ions selectivity of ionic liquid-based extraction system: adding water-soluble complexing agent. Talanta 2008; 74: 1071–1074.10.1016/j.talanta.2007.07.031Search in Google Scholar PubMed
Sun X, Ji Y, Zhang L, Chen J, Li D. Separation of cobalt and nickel using inner synergistic extraction from bifunctional ionic liquid extractant (Bif-ILE). J Hazard Mater 2010a; 182: 447–452.10.1016/j.jhazmat.2010.06.052Search in Google Scholar PubMed
Sun X, Ji Y, Hu F, He B, Chen J, Li D. The inner synergistic effect of bifunctional ionic liquid extractant for solvent extraction. Talanta 2010b; 81: 1877–1883.10.1016/j.talanta.2010.03.041Search in Google Scholar PubMed
Suresh JS. Recent advances in ionic liquids: green unconventional solvents of this century: part I. Green Chem Lett Rev 2011; 4: 289–310.10.1080/17518253.2011.572294Search in Google Scholar
Tsaoulidisa D, Dorea F, Angelia P, Plechkovab NV, Seddon KR. Extraction of dioxouranium(VI) in small channels using ionic liquids. Chem Eng Res Des 2013; 91: 681–687.10.1016/j.cherd.2013.01.008Search in Google Scholar
Visser AE, Swatloski RP, Reichert WM, Griffin ST, Rogers RG. Traditional extractants in nontraditional solvents: groups 1 and 2 extraction by crown ethers in room temperature ionic liquids. Ind Eng Chem Res 2000; 39: 3596–3604.10.1021/ie000426mSearch in Google Scholar
Visser AE, Swatloski RP, Reichert MW, Myton R, Sheff S, Wierzbicki A, Davis JH, Rogers RD. Task-specific ionic liquids incorporating novel cations for the coordination and extraction Hg2+ and Cd2+: synthesis, characterization, and extraction studies. Environ Sci Technol 2002; 36: 2523–2529.10.1021/es0158004Search in Google Scholar
Walkowiak W, Kozlowski CA. Macrocycle carriers for separation of metal ions in liquid membrane processes – a review. Desalination 2009; 240: 186–194.10.1016/j.desal.2007.12.041Search in Google Scholar
Wang L, Shen W. Chemical and morphological stability of Aliquat 336/PVC membranes in membrane extraction: a preliminary study. Sep Purif Technol 2005; 46: 51–62.10.1016/j.seppur.2005.04.009Search in Google Scholar
Wang L, Paimin R, Cattrall RW, Shen W, Kolev SD. The extraction of cadmium(II) and copper(II) from hydrochloric acid solutions using an Aliquat 336/PVC membrane. J Membr Sci 2000; 176: 105–111.10.1016/S0376-7388(00)00436-1Search in Google Scholar
Wassink B, Dreisinger D, Howard J. Solvent extraction separation of zinc and cadmium from nickel and cobalt using Aliquat 336, a strong base anion exchanger, in the chloride and thiocyanate forms. Hydrometallurgy 2000; 57: 235–252.10.1016/S0304-386X(00)00116-XSearch in Google Scholar
Wei GT, Yang Z, Chen ChJ. Room temperature ionic liquid as a novel medium for liquid/liquid extraction of metal ions. Anal Chim Acta 2003; 488: 183–192.10.1016/S0003-2670(03)00660-3Search in Google Scholar
Wellens S, Hoogerstraete TV, Moller C, Thijs B, Luyten J, Binnemans K. Dissolution of metal oxides in an acid-saturated ionic liquid solution and investigation of back-extraction behaviour to the aqueous phase. Hydrometallurgy 2014; 144–145: 27–33.10.1016/j.hydromet.2014.01.015Search in Google Scholar
Yang L, Zhang ZX, Zhang HQ. Asymmetric sulfonium-based molten salts with TFSI- or PF6- anion as novel electrolytes. J Power Sources 2006; 162: 614–619.10.1016/j.jpowsour.2006.06.050Search in Google Scholar
Zhang H, Fang SH, Peng ChX, Luo HJ. Ionic liquids based on S-alkylthiolanium cations and TFSI anion as potential electrolytes. Chinese Sci Bull 2009; 54: 1322–1327.10.1007/s11434-009-0038-1Search in Google Scholar
Zhang Y, Kogelnig D, Morgenbesser C, Stojanovic A, Jirsa F, Lichtscheidl-Schultz I, Krachler R, Li Y, Keppler BK. Preparation and characterization of immobilized [A336][MTBA] in PVA-alginate gel beads as novel solid-phase extractants for an efficient recovery of Hg(II) from aqueous solutions. J Hazard Mater 2011; 196: 201–209.10.1016/j.jhazmat.2011.09.018Search in Google Scholar PubMed
Zhang D, Wang W, Deng Y, Zhang J, Zhao H, Chen J. Extraction and recovery of cerium(IV) and fluorine(I) from sulfuric solutions using bifunctional ionic liquids extractants. Chem Eng J 2012; 179: 19–25.10.1016/j.cej.2011.06.021Search in Google Scholar
Zhao H, Xia S, Ma P. Review: use of ionic liquids as ‘green’ solvents for extractions. J Chem Technol Biotechnol 2005; 80: 1089–1096.10.1002/jctb.1333Search in Google Scholar
©2015 by De Gruyter