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Licensed Unlicensed Requires Authentication Published by De Gruyter August 26, 2015

The effect of large area graphene oxide (LAGO) nanosheets on the mechanical properties of polyvinyl alcohol

  • Khalid Nawaz , Muhammad Ayub , Noaman Ul-Haq EMAIL logo , M.B. Khan , Muhammad Bilal Khan Niazi and Arshad Hussain

Abstract

Large area graphene oxide sheets were synthesized, dispersed in water and used as nanofiller for mechanical improvement in terms of Young’s modulus and ultimate tensile strength (UTS) of polyvinyl alcohol (PVA) at low loading. The molecular level dispersion and interfacial interactions between the graphene oxides and polymeric matrix PVA were the real challenges. An excellent improvement in mechanical properties at 0.35 wt% loading was observed. Modulus improved from 1.58 GPa to 2.72 GPa (~71% improvement), UTS improved from 120 MPa to 197 MPa (~65% improvement), and in spite of these improvements, interestingly, there was no fall in elongation at break at this loading.


Corresponding author: Noaman Ul-Haq, School of Chemical and Materials Engineering, National University of Sciences and Technology, H-12 Islamabad, Pakistan, e-mail:

Acknowledgments

We appreciate the financial assistance from the Higher Education Commission of Pakistan (Grant/Award Number: “pin-IRSIP13-Engg.01”) through the International Research Support Initiative Programme to conduct this work, with the group of Professor Jonathan N. Coleman, School of Physics, Trinity College Dublin, Republic of Ireland.

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Received: 2015-6-12
Accepted: 2015-7-17
Published Online: 2015-8-26
Published in Print: 2016-5-1

©2016 by De Gruyter

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