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Licensed Unlicensed Requires Authentication Published by De Gruyter October 21, 2020

MXene/wood-based composite materials with electromagnetic shielding properties

  • Zhenxing Wang , Xiaoshuai Han , Sijie Wang ORCID logo , Xuewen Han and Junwen Pu EMAIL logo
From the journal Holzforschung

Abstract

With the growing popularity in digital systems and electronic communication equipment, there is an urgent need to develop lightweight, green, and efficient electromagnetic interference (EMI) shielding materials to handle the increasingly serious problem of radiation pollution. Herein, Ti3C2Tx (MXene)/natural wood (NW) composites were prepared using a vacuum-pulse impregnation method and characterized by Fourier transform infrared (FTIR), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) patterns, X-ray photoelectron spectroscopy (XPS) analysis, and EMI shielding performance. As demonstrated, Ti3C2Tx nanosheets were successfully inserted into wood matrices, and hydrogen bonding between Ti3C2Tx nanosheets and cellulose nanofibers induced the fabrication of Ti3C2Tx/NW composites. Ti3C2Tx/NW composites exhibited excellent EMI shielding effectiveness (SE) values of 28.2 dB at the X-band frequency.


Corresponding author: Junwen Pu, College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, China, E-mail:

Award Identifier / Grant number: 501100012138

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by Special Fund for Beijing Common Construction Project and Beijing Forestry University, grant no. 2016HXKFCLXY001.

  3. Conflict of interest statement: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

References

Balci, O., Polat, E.O., Kakenov, N., and Kocabas, C. (2015). Graphene-enabled electrically switchable radar-absorbing surfaces. Nat. Commun. 6: 668, https://doi.org/10.1038/ncomms7628.Search in Google Scholar PubMed

Bera, R., Maitra, A., Paria, S., Karan, S.K., Das, A.K., Bera, A., Si, S.K., Halder, L., De, A., and Khatua, B.B. (2018). An approach to widen the electromagnetic shielding efficiency in PDMS/ferrous ferric oxide decorated RGO-SWCNH composite through pressure induced tunability. Chem. Eng. J. 335: 501–509, https://doi.org/10.1016/j.cej.2017.10.178.Search in Google Scholar

Cao, W.T., Feng, W., Jiang, Y.Y., Ma, C., Zhou, Z.F., Ma, M.G., Chen, Y., and Chen, F. (2019). MXene-reinforced cellulose nanofibril inks for 3D-printed smart fibres and textiles. Adv. Funct. Mater. 29: 1905898, https://doi.org/10.1002/adfm.201905898.Search in Google Scholar

Cao, M.S., Song, W.L., Hou, Z.L., Wen, B., and Yuan, J. (2010). The effects of temperature and frequency on the dielectric properties, electromagnetic interference shielding and microwave-absorption of short carbon fiber/silica composites. Carbon 48: 788–796, https://doi.org/10.1016/j.carbon.2009.10.028.Search in Google Scholar

Cao, M.S., Wang, X.X., Cao, W.Q., Fang, X.Y., Wen, B., and Yuan, J. (2018a). Thermally driven transport and relaxation switching self-powered electromagnetic energy conversion. Small 14: 1800987, https://doi.org/10.1002/smll.201800987.Search in Google Scholar PubMed

Cao, W.T., Chen, F.F., Zhu, Y.J., Zhang, Y.G., Jiang, Y.Y., Ma, M.G., and Chen, F. (2018b). Binary strengthening and toughening of MXene/cellulose nanofiber composite paper with nacre-inspired structure and superior electromagnetic interference shielding properties. ACS Nano 12: 4583–4593, https://doi.org/10.1021/acsnano.8b00997.Search in Google Scholar PubMed

Chaudhary, A., Kumar, R., Teotia, S., Dhawan, S.K., Dhakate, S.R., and Kumari, S. (2017). Integration of MCMBs/MWCNTs with Fe3O4 in a flexible and light weight composite paper for promising EMI shielding applications. J. Mater. Chem. C 5: 322–332, https://doi.org/10.1039/c6tc03241a.Search in Google Scholar

Chen, Z.H., Zhuo, H., Hu, Y.J., Lai, H.H., Liu, L.X, Zhong, L.X., and Peng, X.W. (2020). Wood-derived lightweight and elastic carbon aerogel for pressure sensing and energy storage. Adv. Funct. Mater. 30, https://doi.org/10.1002/adfm.201910292.Search in Google Scholar

Hakansson, K.M.O., Fall, A.B., Lundell, F., Yu, S., Krywka, C., Roth, S.V., Santoro, G., Kvick, M., Wittberg, L.P., and Wagberg, L., et al. (2014). Hydrodynamic alignment and assembly of nanofibrils resulting in strong cellulose filaments. Nat. Commun. 5: 4018, https://doi.org/10.1038/ncomms5018.Search in Google Scholar PubMed PubMed Central

Han, X.S., Yin, Y.H., Zhang, Q.Q., Li, R., and Pu, J.W. (2018). Improved wood properties via two-step grafting with itaconic acid (IA) and nano-SiO2. Holzforschung 72: 499–506, https://doi.org/10.1515/hf-2017-0117.Search in Google Scholar

Han, X.S., Ye, Y.H., Lam, F., Pu, J.W., and Jiang, F. (2019). Hydrogen-bonding-induced assembly of aligned cellulose nanofibers into ultrastrong and tough bulk materials. J. Mater. Chem. 7: 27023–27031, https://doi.org/10.1039/c9ta11118b.Search in Google Scholar

He, N., He, Z.D., Liu, L., Lu, Y., Wang, F.Q., Wu, W.H., and Tong, G.X. (2020a). Ni2+ guided phase/structure evolution and ultra-wide bandwidth microwave absorption of CoxNi1-x alloy hollow microspheres. Chem. Eng. J. 381: 122743, https://doi.org/10.1016/j.cej.2019.122743.Search in Google Scholar

He, P., Cao, M.S., Cai, Y.Z., Shu, J.C., Cao, W.Q., and Yuan, J. (2020b). Self-assembling flexible 2D carbide MXene film with tunable integrated electron migration and group relaxation toward energy storage and green EMI shielding. Carbon 157: 80–89, https://doi.org/10.1016/j.carbon.2019.10.009.Search in Google Scholar

He, P., Wang, X.X., Cai, Y.Z., Shu, J.C., Zhao, Q.L., Yuan, J., and Cao, M.S. (2019). Tailoring Ti3C2Tx nanosheets to tune local conductive network as an environmentally friendly material for highly efficient electromagnetic interference shielding. Nanoscale 11: 6080–6088, https://doi.org/10.1039/c8nr10489a.Search in Google Scholar PubMed

Li, Y., Yang, H.J., Hao, X.H., Sun, N.N., Du, J.H., and Cao, M.S. (2019). Enhanced electromagnetic interference shielding with low reflection induced by heterogeneous double-layer structure in BiFeO3/BaFe7(MnTi)(2.5)O-19 composite. J. Alloys Compd. 772: 99–104, https://doi.org/10.1016/j.jallcom.2018.09.047.Search in Google Scholar

Liu, J., Zhang, H.B., Sun, R.H., Liu, Y.F., Liu, Z.S., Zhou, A.G., and Yu, Z.Z. (2017). Hydrophobic, flexible, and lightweight MXene foams for high-performance electromagnetic-interference shielding. Adv. Mater. 29: 1702367, https://doi.org/10.1002/adma.201702367.Search in Google Scholar PubMed

Mittal, N., Janson, R., Widhe, M., Benselfelt, T., Hakansson, K.M.O., Lundell, F., Hedhammar, M., and Soderberg, L.D. (2017). Ultrastrong and bioactive nanostructured bio-based composites. ACS Nano 11: 5148–5159, https://doi.org/10.1021/acsnano.7b02305.Search in Google Scholar PubMed

Sambyal, P., Iqbal, A., Hong, J., Kim, H., Kim, M.K., Hong, S.M., Han, M.K., Gogotsi, Y., and Koo, C.M. (2019). Ultralight and mechanically robust Ti3C2Tx hybrid aerogel reinforced by carbon nanotubes for electromagnetic interference shielding. ACS Appl. Mater. Interfaces 11: 38046–38054, https://doi.org/10.1021/acsami.9b12550.Search in Google Scholar PubMed

Shahzad, F., Alhabeb, M., Hatter, C.B., Anasori, B., Hong, S.M., Koo, C.M., and Gogotsi, Y. (2016). Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science 353: 1137–1140, https://doi.org/10.1126/science.aag2421.Search in Google Scholar PubMed

Tang, H., Butchosa, N., and Zhou, Q. (2015). A transparent, hazy, and strong macroscopic ribbon of oriented cellulose nanofibrils bearing poly (ethylene glycol). Adv. Mater. 27: 2070–2076, https://doi.org/10.1002/adma.201404565.Search in Google Scholar PubMed

Wang, X., Chen, X., Xie, X., Wu, Y., Zhao, L., Li, Y., and Wang, S. (2018). Effects of thermal modification on the physical, chemical and micromechanical properties of Masson pine wood (Pinus massoniana Lamb.). Holzforschung 72: 1063–1070, https://doi.org/10.1515/hf-2017-0205.Search in Google Scholar

Wang, X.X., Shu, J.C., Cao, W.Q., Zhang, M., Yuan, J., and Cao, M.S. (2019). Eco-mimetic nanoarchitecture for green EMI shielding. Chem. Eng. J. 369: 1068–1077, https://doi.org/10.1016/j.cej.2019.03.164.Search in Google Scholar

Wang, X.Z., Pang, Z.Q., Chen, C.J., Xia, Q.Q., Zhou, Y.B., Jing, S.S., Wang, R.L., Ray, U., Gan, W., and Li, C. (2020b). All-natural, degradable, rolled-up straws based on cellulose micro- and nano-hybrid fibers. Adv. Funct. Mater. 30: 1910417, https://doi.org/10.1002/adfm.201910417.Search in Google Scholar

Wang, T., Yu, W.C., Zhou, C.G., Sun, W.J., Zhang, Y.P., Jia, L.C., Gao, J.F., Dai, K., Yan, D.X., and Li, Z.M. (2020a). Self-healing and flexible carbon nanotube/polyurethane composite for efficient electromagnetic interference shielding. Compos. B Eng. 193: 108015, https://doi.org/10.1016/j.compositesb.2020.108015.Search in Google Scholar

Wen, B., Cao, M.S., Lu, M.M., Cao, W.Q., Shi, H.L., Liu, J., Wang, X.X., Jin, H.B., Fang, X.Y., Wang, W.Z., et al. (2014). Reduced graphene oxides: light-weight and high-efficiency electromagnetic interference shielding at elevated temperatures. Adv. Mater. 26: 3484–3489, https://doi.org/10.1002/adma.201400108.Search in Google Scholar PubMed

Yadav, R.S., Kuritka, I., Vilcakova, J., Skoda, D., Urbanek, P., Machovsky, M., Masar, M., Kalina, L., and Havlica, J. (2019). Lightweight NiFe2O4-reduced graphene oxide-elastomer nanocomposite flexible sheet for electromagnetic interference shielding application. Compos. B Eng. 166: 95–111, https://doi.org/10.1016/j.compositesb.2018.11.069.Search in Google Scholar

Zhan, Z.Y., Song, Q.C., Zhou, Z.H., and Lu, C.H. (2019). Ultrastrong and conductive MXene/cellulose nanofiber films enhanced by hierarchical nano-architecture and interfacial interaction for flexible electromagnetic interference shielding. J. Mater. Chem. C 7: 9820–9829, https://doi.org/10.1039/c9tc03309b.Search in Google Scholar

Received: 2020-04-07
Accepted: 2020-08-27
Published Online: 2020-10-21
Published in Print: 2021-05-26

© 2020 Walter de Gruyter GmbH, Berlin/Boston

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