Site M0077: Post-Impact Sedimentary Rocks

S. Gulick, J. Morgan, C.L. Mellett, S.L. Green, T. Bralower, E. Chenot, G. Christeson, P. Claeys, C. Cockell, M. Coolen, L. Ferrière, C. Gebhardt, K. Goto, H. Jones, D. Kring, J. Lofi, C. Lowery, R. Ocampo-Torres, L. Perez-Cruz, A.E. Pickersgill, M. Poelchau, A. Rae, C. Rasmussen, M. Rebolledo-Vieyra, U. Riller, H. Sato, J. Smit, S. Tikoo, N. Tomioka, J. Urrutia-Fucugauchi, M. Whalen, A. Wittmann, K. Yamaguchi, L. Xiao, and W. Zylberman2


Introduction
In the uppermost part of the cored interval in Hole M0077A, a succession of post-impact sedimentary rocks was recovered between 505.7 and 617.33 meters below seafloor (mbsf) (Core 1R to Section 40R-1, 109.4 cm). The following sections detail the data and measurements from this package.

Operations
At 1315 h on 19 April 2016, the coring assembly was prepared and running in of pipe recommenced to allow for the start of coring in Hole M0077A. At 2020 h, the bottom-hole assembly (BHA) was recovered for inspection due to the lack of advance and was then delatched and sent back to the bottom of the hole. No progress was made, so the string was again tripped out at 2043 h. A fabricated "stinger" was added to the BHA to guide it past the misaligned casing. This assembly was run in at 0345 h on 20 April. By 0655 h, the BHA had passed the misaligned casing and progressed to the base of the hole, where coring commenced. At 1055 h, the first core barrel was recovered to the deck. It contained debris material associated with the drilling process (metal and rubber). A second core barrel was deployed and rotated for approximately 30 min with no advance. On recovery to deck, this barrel was found to be empty. Following discussion, it was decided to fish for any additional pieces of metal (thought to be crowns from a damaged bit) that could be at the bottom of the hole. Attempts to remove debris and advance coring were made throughout the day.
On 21 April, attempts to remove debris continued until 1415 h, when essential maintenance to the rig was carried out. Rig maintenance continued until 0710 h on 22 April. For the remainder of the day, attempts to clear the borehole of debris continued. At 2330 h, after no advance, the pipe was tripped to change the bit.
Tripping of pipe continued until 1155 h, when the BHA was recovered on deck. A tricone bit was added to the BHA to drill open hole past the obstruction. Shortly afterward, the supply boat Linda F arrived to transfer personnel to the platform. Running in pipe continued, and at 1630 h, open-hole drilling commenced. By 2120 h, the hole advanced beyond the debris/obstruction to 505.70 m drilling depth below seafloor (DSF).
Tripping pipe commenced and continued until 0215 h on 24 April, when the BHA was recovered to deck and the bit was changed to allow coring. The pipe was run in and reached the base of the hole at 0730 h, when coring commenced. The first core, Core 1R, was recovered to deck at 0800 h. Coring then continued on 24 April with a total of nine runs, reaching 521.67 m DSF.
During the early hours of 25 April, it was necessary to carry out maintenance on the top drive motors, resulting in a break in coring until 0505 h. Cores 10R and 11R were recovered at 0650 h and 0900 h, respectively, before further rig maintenance was required. Following this, coring progressed smoothly on 25 April, reaching 546.09 m DSF by 2400 h. The supply boat Linda F arrived at 1600 h on 26 April to deliver groceries and other supplies. Smooth coring operations continued on 26 and 27 April. Core 40R was recovered at 1715 h on 27 April. Within this core, the base of the Post-Impact Sedimentary Rocks interval was identified.

Lithology
This section outlines the general lithologies that characterize the Post-Impact Sedimentary Rocks interval in Hole M0077A. It describes seven preliminary lithostratigraphic subunits (1A-1G) (Table T1), which were designated based on changes in the distribution of lithologies throughout the core. Additionally, this section describes computed tomography (CT) facies and how they can be used to evaluate lithologic and diagenetic variations in the core. The cores in this interval were remarkably undisturbed, with the exception of some fractures.

Lithologic descriptions
Lithologic descriptions were compiled from information summarized in the Expedition Drilling Information System (Expedi-tionDIS) and from the visual core descriptions (VCDs). Descriptions systematically refer to color, bedding thickness and character, grain size, ichnofabric index (1-5), fossils, alteration features, interbedded and vertically adjacent facies, and the occurrence of a specific lithology in the core.

Claystone
Claystones are light to dark gray and bluish gray (gray colors vary between 2.5Y 3/1, 4/1, 5/2, and 6/1-2; bluish gray colors vary mainly between Gley 2 4/1, 5/1, 6/1, and 7/1) ( Figure F1). Claystone occurs in relatively thin layers (between 0.5 and 15 cm thick) throughout the different lithostratigraphic subunits (except for Subunit 1G) and are interpreted to be volcanic ash beds. Upper and lower claystone contacts are commonly sharp but locally disrupted by burrowing. The grain size is dominantly clay, although local coarse grains (shell fragments or subangular clasts) are present within the claystone beds. Lamination and structures occur rarely, with disturbed lamination the most commonly observed structure. The ichnofabric index for most claystone units was described as 1, although burrowing is present locally at the top and bottom of individual claystone beds, indicating an ichnofabric index of 2-3. In addition, several units contain pyrite or chert nodules, whereas others appear to have a slurry-like texture.

A B
C D E F G H packages at the base and in the lower portion and as thin interbeds throughout the subunit.

Dark marlstone/claystone
Dark marlstone/claystone is olive-brown (2.5Y 4/3), very dark grayish brown (2.5Y 3/2), or very dark gray (2.5Y 3/1) with local light olive-brown interbeds (2.5Y 5/4) ( Figure F1). Marlstone and claystone are lumped together in this facies because they are commonly interlaminated at the millimeter scale. Bedding ranges from millimeter to decimeter thick with millimeter-to centimeter-scale bedding most common. Beds are planar to wavy, and grain size is dominantly clay to silt sized with local sand-sized grains. The ichnofabric index ranges from 1 to 4 with local well-preserved individual burrows. Locally thin millimeter-scale light-colored packstones or grainstones are interbedded. Alteration features include soft-sediment deformation, pyrite, and carbonate nodules. Dark marlstone/claystone occurs in Subunits 1A-1E, locally overlies black shale, marlstone, wackestone, or packstone, and commonly grades upward into marlstone and/or wackestone or packstone.

Lithostratigraphic units
Lithostratigraphic units were defined based on significant changes in the distribution of the different lithologies described above. Contacts between units are usually sharp and either depositional or erosional but are locally gradational due to bioturbation (Table T1; Figures F2, F4, F5, F6, F7, F8, F11, F12, F13). The biostratigraphy of the cored interval provides age control (see Biostratigraphy) ( Figure F12).

Subunit 1C
Subunit 1C extends from 537.80 to 559.75 mbsf and consists of intercalated dark marlstone/claystone, marlstone, wackestone, packstone, and local claystone (Figures F6, F13A). Dark marlstone/claystones are laminated at the millimeter scale or centimeter-scale bedded. Claystones are centimeter-scale bedded, and other lithologies are centimeter-to decimeter-scale bedded. The subunit displays a centimeter-scale soft-sediment fold within a packstone in Section 14R-1, 100-107.5 cm. Soft-sediment deforma- Figure F11. Upper and lower contacts of lithostratigraphic Subunit 1G, Hole M0077A. Upper contact is illustrated and described in Figure F13. Upper portion of subunit displays Cr enrichment based on μXRF mapping, and base displays enrichment of Ni and Cr based on X-ray intensity mapping (see Geochemistry  Figure F12. Lithostratigraphic summary, Hole M0077A. For more on the biostratigraphic scheme, see Biostratigraphy.  tion recurs in the lower part of Section 20R-2 and the upper part of Section 21R-1 with decimeter-scale soft-sediment folds in dark marlstone/claystone. The base of the subunit is a gradational contact designated as the last millimeter-scale dark marlstone/limestone overlying marlstone with thin light brown wackestone interbeds in Section 21R-1, 146.20 cm (559.75 mbsf ) ( Table T1).

Subunit 1D
Subunit 1D stretches from 559.75 to 580.89 mbsf and contains interbedded dark marlstone/claystone, claystone, marlstone, wackestone, and packstone intercalated at the centimeter to decimeter scale (Figures F5, F13B). Dark marlstone/claystone was observed mostly laminated at the millimeter scale, whereas marlstones are generally centimeter-scale bedded or bioturbated and decimeter-scale bedded. Claystones are mainly centimeter-scale bedded except for decimeter-thick claystones. One such claystone bed extends from the base of Section 22R-2 to the top of Section 22R-3, and another exists in Section 24R-2. Both are bioturbated with an ichnofabric index of 2-3. Wackestones and packstones are largely bioturbated and centimeter-scale bedded in the upper part of the subunit but become thicker downhole (>20 cm). Marlstones are brownish gray or grayish brown, and limestones are light brownish gray to light yellowish brown. The subunit appears largely cyclic, with lithologies that coarsen upward from dark marlstone/claystone to marlstone to wackestone and/or packstone. The base of the subunit is slightly gradational at the bottom of a dark marlstone/claystone with minor burrowing in Section 28R-1, 125.20 cm (580.89 mbsf ) ( Table T1). The contact was designated based on the change to bluish marlstones that occur in the core below. Figure F13. Basal contacts of Subunits 1A-1F, Hole M0077A. A. Sharp erosional contact at base of Subunit 1A truncates underlying thin grainstone at 11R-2, 116.8 cm (530.18 mbsf ). B. Base of Subunit 1B is packstone that erosionally truncates the underlying dark marlstone/claystone at the top of Subunit 1C at 14R-1, 86.40 cm (537.89 mbsf ). Base of Subunit 1C is a gradational contact designated as the last dark millimeter-scale marlstone/limestone overlying marlstone with thin light brown wackestone interbeds at 21R-1, 146.20 cm (559.75 mbsf ). D. Base of Subunit 1D is slightly gradational at the bottom of a dark marlstone/claystone with minor burrowing at 28R-1, 125.20 cm (580.89 mbsf ). E. Base of Subunit 1E is the top of a prominent carbonate-cemented surface with about 1.5 cm of relief at 37R-1, 25.5 cm (607.27 mbsf ). F. Base of Subunit 1F is a sharp contact below the base of the greenish claystone at 40R-1, 34.20 cm (616.58

Subunit 1E
Subunit 1E occurs from 580.89 to 607.27 mbsf and contains interbedded dark marlstone/claystone, lighter brown marlstone (ichnofabric index = 2-3), light brown to bluish wackestone and packstone (ichnofabric index = 2-4), and black shale (ichnofabric index = 1) (Figures F2, F13B). Facies other than black shale contain wispy stylolites. Units that contain black shale display elevated gamma ray signatures and the highest total organic carbon (TOC) contents in the core ( Figure F8). The upper portion of the subunit is highly cyclic, with decimeter-thick dark marlstone/claystone or marlstone-based cycles that grade upward into wackestone or packstone. Contacts between lithologies are usually gradational due to burrowing. From the top of the subunit to the middle of Section 29R-1, marlstones are dominantly light brownish gray or grayish brown and limestones are light brownish gray to light yellowish brown, with all displaying some bluish intervals. Deeper marlstones are dominantly light bluish gray, and limestones are light gray to light bluish gray. In Section 33R-2, 25.5 cm (596.65 mbsf ), cyclic bedding is replaced by a package of dark marlstone/claystone that is burrowed at the top (ichnofabric index = 3), parallel laminated below, and intercalated with thin planar-laminated black shale and dark brown wackestone. This package extends to Section 34R-1, 26.5 cm (598.21 mbsf ). Downhole, the core once again records decimeter-scale cyclic alternations of dark gray to light bluish gray marlstones that grade upward into light gray to light bluish gray wackestone or packstone with foraminifers ( Figure F3) and local black chert. In Section 36R-1, 58 cm, burrows take on a brownish hue and lithologies alternate between light brown and bluish colors. Contacts between lithologies are usually gradational due to burrowing. In Section 36R-2, 78 cm, is a 1.5 cm thick granule-pebble carbonate rudstone. Below the rudstone to Section 36R-4, 16 cm, is a package of light yellowish brown wackestone and packstone with centimeter-thick dark gray marl interbeds and black chert horizons. The lowermost package in the subunit is a burrowed packstone that grades downward into black shale at Section 37R-1, 0-25.5 cm. A gradational contact between the packstone and black shale occurs at Section 37R-1, 4.5 cm. The base of the subunit is the top of a prominent carbonate-cemented surface with about 1.5 cm of relief in Section 37R-1, 25.5 cm (607.27 mbsf ) ( Table T1).

Subunit 1F
Subunit 1F extends from 607.27 to 616.58 mbsf and consists of interbedded light gray to light bluish gray wackestone and packstone (ichnofabric index = 3-5) and light to dark bluish gray marlstone (ichnofabric index = 2) at the centimeter to decimeter scale ( Figures F8, F13B). All lithologies contain wispy stylolites. The upper portion of the subunit, to Section 37R-1, 65.5 cm, is light yellowish brown packstone that is burrowed (ichnofabric index = 4) and intercalated with gray marlstone. The uppermost 7.5 cm, above the marlstone, is calcite cemented. Clasts are fine to coarse sand sized and include foraminifers. The lowermost part of this package has two black chert patches. From the base of this package to Section 37R-1, 72.5 cm, is bluish gray claystone. Downhole, bedding is cyclic at the centimeter to decimeter scale with light bluish marlstone bases grading upward into light gray or light bluish gray wackestone and packstone. Contacts between lithologies are usually gradational due to burrowing. Rocks take on a light greenish hue near the base of the subunit. Cycles thicken upward between 610.25 and 612.57 mbsf, thin upward between 612.57 and 613.87 mbsf, thicken upward from 613.87 to 615.06 mbsf, and thin upward from 615.06 to the base of subunit at 616.55 mbsf. The base of the subunit is a sharp contact below the base of the greenish claystone in Section 40R-1, 34.20 cm (616.58 mbsf ) ( Table T1).

Subunit 1G
Subunit 1G occurs from 616.58 to 617.33 mbsf and consists mainly of dark brown to dark grayish brown lime mudstone to wackestone (mud/wackestone) ( Figure F11). The subunit is complex, with several different lithologies that generally fine upward. It contains postdepositional pyrite nodules that disrupt bedding. The upper portion of the subunit has two thin intervals that display Cr enrichment based on μXRF mapping (see Geochemistry and mineralogy). The uppermost Subunit 1G is slightly deformed, with one millimeter-scale greenish marlstone interbedded with the lightest gray mud/wackestone in Section 40R-1, 34.2-36.8 cm (616.58-616.60 mbsf ). Bedding is indistinct in the upper mud/wackestone and is obscured by soft-sediment deformation in Section 40R-1, 57.5-67.5 cm (616.73-616.83 mbsf ). In Section 40R-1, 78-100.04 cm (617.24 mbsf ), Subunit 1G contains millimeter-bedded couplets of dark brown and dark grayish brown mud/wackestone that overlie centimeter-bedded mud/wackestone. In Section 40R-1, 100.04-109.4 cm (617.24 to 617.33 mbsf ), are five thin intervals: (1) a 3 cm thick light gray mud/wackestone laminated at the submillimeter scale with local greenish laminae, (2) a 1.8 cm thick mud/wackestone that is slightly darker gray and has some greenish laminae and clasts, (3) a 3.1 cm thick light gray mud/wackestone laminated at the submillimeter scale (similar to 2) that also contains a calcite-filled convoluted feature that crosscuts itself, and (4 and 5) two normally graded beds of packstone with impact glass and a variety of carbonate grains, each less than 1 cm thick. Beds grade upward from packstone with greenish sand-sized clasts, similar to those in the underlying suevite, to dark gray millimeter-thick laminae similar to the overlying mud/wackestone. These two beds display enrichment of Ni and Cr based on X-ray intensity mapping (see Geochemistry and mineralogy). The base of the subunit is a sharp, stylolitized contact in Section 40R-1, 109.4 cm (617.33 mbsf ) ( Table T1), that overlies the upper suevite of Subunit 2A.

Computed tomography facies analysis
Post-impact sediments are classified according to their lithologic affiliation and divided into different units depending on their composition. Expedition 364 cores were CT scanned with two different energy levels (80 and 135 kV). The higher energy CT scan is more sensitive to density, and the lower energy scan is more sensitive to atomic number. For the purposes of observations made during the Onshore Science Party (OSP), the CT facies described are simply put in context of higher or lower CT values. Although a single CT value is returned for each 0.3 × 0.3 mm pixel within the scanned cores, areas of similar lithology generally return similar CT values. Hence, a clast of a single rock type will be recognizable because all pixels within the region of the clast are colored similarly. Within the post-impact succession, layers of similar lithology will display similar CT values represented by a grayscale color scheme. The X-Z slice images of bulk density (ρ b ) and effective atomic number (Z eff ) are also discussed. One can therefore define a CT facies to describe sections of the cores that have similar patterns in the CT images and dual energy-derived products.

Computed tomography facies of individual rock types
The marlstone lithology is divided into marlstone and dark marlstone/claystone. CT scans associated with the former consist mainly of light gray to dark gray intervals. Both intervals corre-IODP Proceedings 11 Volume 364 spond mainly to low ρ b and high Z eff . In a few cases, ρ b and Z eff vary between high and moderate values, complicating the recognition of a clear pattern. Bioturbated areas occur locally as black intervals. A few light gray to white intervals occur within the marlstones and are associated with high ρ b and low Z eff . The dark marlstone/claystone lithology consists of alternations of light gray, dark gray, and black intervals. The light gray intervals are mainly associated with low ρ b and high Z eff . However, high ρ b and high Z eff are also common within these intervals. The dark gray intervals correspond to high ρ b and low Z eff , but moderate values for both properties are present. The black intervals are mainly associated with relatively moderate values for ρ b and Z eff , but several areas also display relatively high or low values for either ρ b or Z eff .
Generally, even if certain patterns can be associated with the two lithologies, variances are common, making a clear definition of the CT facies challenging without further detailed study.
The limestone lithology is divided into wackestone, packstone, and grainstone. CT scans of the wackestone and packstone intervals show alternations of variable thickness (from a few millimeters to an entire core section) of light to dark gray and black intervals. These intervals are associated with a broad spectrum of ρ b and Z eff that vary between high, moderate, and low values. A pattern cannot be recognized. Within the wackestone, however, white intervals are locally present that are associated with relatively high Z eff compared with the darker intervals. In many cases, an increase in the ichnofabric index correlates with a lighter interval on the CT image interval (up to light gray), whereas density values drop compared to less bioturbated areas.
The grainstone lithology presents itself uniformly as a light interval, mainly light gray and in rare cases white. This lithology is associated with high ρ b and high Z eff relative to the observed values of the other lithologies.
The claystone lithology is associated with a black CT interval that corresponds to relatively low ρ b and low Z eff . In only a few cases are either moderate ρ b or high Z eff present. An exception to this pattern was observed within a bioturbated claystone layer (Section 6R-1) where the recycling of sediment possibly caused a white CT interval ( Figure F14). In areas where claystones experienced silicification, the CT interval still appears black and is associated with relatively low ρ b but relatively moderate Z eff .
Recurring extraordinary features such as pyrite, chert layers or nodules, and mineral-filled cracks appear as pearly white features on the core surface and are always associated with relatively high ρ b and Z eff (Figures F14, F15).

CT facies of individual subunits
The Post-Impact Sedimentary Rocks interval is divided into seven subunits (1A-1G) ( Table T1). Subunit 1A consists mainly of marlstone and dark marlstone/claystone layers that both appear as alternating sequences of light gray, dark gray, and black intervals on the CT scans ( Figure F14). Overall, the subunit is associated with relatively low ρ b and high Z eff . However, opposite patterns also occur throughout the subunit and seem to become more common toward the bottom.
Similarly, Subunit 1B is represented by alternating light gray, dark gray, and black intervals that appear relatively thicker than those in Subunit 1A. This subunit is also represented by relatively low ρ b and high Z eff , but opposite patterns were also observed. The rarely occurring limestone packages at the bottom of the subunit are associated with light gray intervals on the CT scan and relatively high ρ b and high Z eff . Subunit 1C is also an alternating sequence of light gray, dark gray, and black intervals with relatively low ρ b and high Z eff . Changes within the pattern of ρ b and Z eff are common. The more frequently occurring limestone packages are associated with a light gray interval and relatively high ρ b and high Z eff . In addition, the CT scans mirror the soft-sediment deformation that was observed within the interbedded marlstone lithologies.
Subunit 1D is also composed of light gray, dark gray, and black intervals. However, the black and very light gray (almost white) intervals have increased thickness compared to those in the upper three units. The black intervals are associated with (nonlaminated) marlstone and dark marlstone/claystone layers that have low ρ b and high Z eff , although this association is variable. The light gray inter- Figure F14. Line-scan, CT scan, CT-ρ b (density), and CT-Z eff (atomic number) images (from top to bottom), Hole M0077A. No scales are included for CT density and atomic number images because they are uncalibrated. A. Section 5R-2 illustrates variations in a laminated dark marlstone claystone. B. Section 6R-1 illustrates partially silicified dark blue-gray claystone that stands out in the CT imagery. vals are associated with the limestone packages that correspond to high ρ b and high Z eff . Overall, the subunit shows more areas that are associated with low Z eff than Subunits 1A-1C. Even though these areas cannot be clearly associated with a lithology, they seem to correlate more with the occurrence of marlstone and claystone. Toward the bottom of the subunit, the alternating intervals of the CT scan decrease in thickness. Subunit 1E consists predominantly of a light gray interval with some relatively thin intervals of dark gray and black. The light gray interval was correlated with high but also low Z eff and quite variable density values. The light gray interval corresponds with the presence of limestone, and the darker intervals are associated with marlstone and claystone.
This trend continues in Subunit 1F, which consists mainly of one light gray interval associated with high ρ b and high Z eff that corresponds with the presence of limestone. Dark gray and black intervals become rare to nonexistent throughout the subunit and are only correlated with a few interbedded marlstones and core disturbance.
Subunit 1G (616.58-617.33 mbsf ) was initially described as siltstone during visual core description but was later reclassified as lime mud/wackestone; it has an average CT number of 2314.6 ± 248.8 (2σ). It consists of light to dark gray intervals that are overall associated with relatively high ρ b and high Z eff (Figure F15). At the top of the subunit, laminations of low-CT intensity material were observed; these correspond to green laminae seen in the VCDs. Throughout the subunit, intermittently developed irregular laminae were observed; these become particularly prominent in the lower third of the subunit ( Figure F15). Besides rare occurrences of pyrite, which have high Z eff and ρ b , the mud/wackestone has a very homogeneous Z eff and ρ b distribution. Within the bottom 10 cm of the subunit, horizontally elongate bright spots were observed in CT data; these spots are interconnected, horizontally elongated regions with bulbous shapes. Below this zone, just above the lower contact, is a folded and crumpled layer of material with a slightly brighter CT number. Laminations seen in the CT data in the bottom 5 cm are associated with ρ b variability. The contact with Subunit 2A marks an abrupt drop in CT number and a reduction in the homogeneity of the material (F15).

Biostratigraphy
Coring in Hole M0077A recovered ~110 m of post-impact Paleogene sediments, ranging from middle Eocene (Ypresian) to basal Paleocene (Danian). Biostratigraphic zones are summarized in Figure F16, and semiquantitative abundance counts are summarized in Tables T2 and T3 for foraminifers and nannoplankton, respectively. Preservation varies greatly from very poor to good and is strongly correlated to the induration of the rock, particularly silicified intervals. Planktic and benthic foraminifers and calcareous nannofossils are generally present throughout.
The Eocene section ranges from planktic foraminifer Zones E7b to E5 and calcareous nannofossil Zones CP12 to CP10. This interval is characterized by diverse but variable assemblages of both foraminifers and nannofossils and contains rare to dominant radiolarians, which are often associated with more organic-rich, laminated, and often indurated lithologies that can only be examined in thin section.
A set of stacked unconformities spanning Sections 36R-4 through 37R-1 (~606.5-607.5 mbsf) separate the Paleocene and Eocene sections and separate partial intervals of the uppermost Paleo-cene (including the Paleocene/Eocene Thermal Maximum [PETM]; nannofossil Zone CP8) and upper Paleocene (nannofossil Zone CP5 and planktic foraminifer Zone P4a). The lower Paleocene is complete, however, and ranges from planktic Zones P3b to Pα. Nannofossil zonation is difficult in this interval because the assemblage is dominated by bloom taxa (e.g., Braarudosphaera). Thoracosphaera, a calcareous dinoflagellate common in early Danian marine records, Figure F16. Biostratigraphic zones, Hole M0077A. See Biostratigraphy in the Expedition 364 methods chapter (Gulick et al., 2017) for explanation of zonal scheme. Below Zone Pα is a 75 cm thick brown mud/wackestone that contains a number of Maastrichtian foraminifers and nannoplankton characterizing the "Boundary Cocktail" of Bralower et al. (1998  is very abundant in both thin section and sieved residues from the lower part of Section 39R-3 to the limestone in the upper portion of Section 40R-1 (~616.0-616.5 mbsf). Below Zone Pα, a 75 cm thick brown mud/wackestone contains a number of Maastrichtian foraminifers and nannoplankton characterizing the "Boundary Cocktail" of Bralower et al. (1998).

Planktic foraminifers
Variable preservation in the Eocene section (Cores 1R-36R; 505.70-606.51 mbsf ) hampered shipboard biostratigraphy. During the OSP, core catcher samples collected aboard the L/B Myrtle were supplemented with additional samples from the middle of each core, selected from the least lithified intervals possible. Additionally, a number of thin sections were prepared and analyzed during the OSP to better constrain the assemblage in indurated intervals. Overall, the Eocene section contains a diverse (and variable) assemblage of planktic foraminifers, as well as a large number of radiolarians ( Figure F17), particularly in the upper part of the section.
The base of Core 1R, in Sample 1R-1, 14-15 cm (505.85 mbsf ), contains a middle Eocene assemblage of Zone E7b, indicated by the presence of Turborotalia frontosa. This taxon is not found below Sample 3R-1, 125-126 cm, whereas Acarinina cuneicamerata continues to Sample 21R-3, 0-2 cm (561.14 mbsf ), defining the range of Zone E7a.The assemblage in this zone is characterized by Pseudohastigerina wilcoxensis, species of Acarinina and Subbotina, rare Astrorotalia palmerae (in Cores 15R and 16R), and common radiolarians. Morozovellids are very rare throughout Zone E7 and are not consistent components of the assemblage until nearly the base of the Eocene section. The lowest occurrence (LO) of A. cuneicamerata is followed by very poor preservation to Sample 23R-2, 88-91 cm (566.77 mbsf ), which contains abundant foraminifers, including other Acarininids; the base of Zone E7a is therefore interpolated between these two well-preserved samples at 564.03 mbsf.
Zones E6 and E5 are undifferentiated. The base of Zone E6 is defined as the highest occurrence (HO) of Morozovella subbotinae, but the rarity of Morozovellids throughout the section suggests that the observed HO of M. subbotinae in Sample 32R-3, 58-59 cm (594.84 mbsf ), may be ecologically controlled and thus not a robust biostratigraphic datum. Morozovellids generally become more common below Core 30R and include a typical early Eocene assemblage including Morozovella aragonensis, M. subbotinae, and Morozovella formosa (Figure F18). Additional typical early Eocene planktics, including Acarinina wilcoxensis, Acarinina soldadoensis, Igorina broedermanni, and Planorotalites pseudoscitula, are also present throughout this interval. P. wilcoxensis is less common than it is in Zone E7. Radiolarians also become a less prominent component of most samples in this interval. M. aragonensis, whose base defines the bottom of Zone E5, is present to Sample 36R-3, 6-7 cm (606.17 mbsf ). Deeper samples are poorly preserved until the unconformity separating the Eocene and Paleocene sections, and we believe it is likely that Zone E5 extends to the base of the Eocene section.
The base of Zone CP10 is defined by the LO of D. lodoensis between Samples 36R-2, 19-20 cm (605.22 mbsf ), and 36R-2, 40-42.5 cm (605.43 mbsf ). This species occurs continuously through the upper part of the section, is distinct morphologically and was identified even in poorly preserved samples. From Sample 36R-2, 40-42.5 cm (605.43 mbsf ), to Sample 37R-1, 0-1 cm (607.02 mbsf), samples are heavily recrystallized and nannofossils are rare. Several large, overgrown Discoaster spp. were observed in this interval, in addition to frequent, moderately preserved Discoaster multiradiatus specimens. The absence of robust D. lodoensis indicates that these samples can be assigned to Zone CP9.

Benthic foraminifers
Benthic foraminifer abundance varies significantly throughout the Eocene (Figure F20). Generally, they appear to be more common in the upper portion of the Eocene section than in the lower portion, and their abundance appears anticorrelated with radiolarians. They are almost always estimated to represent less than 5% of the total foraminiferal assemblage. Several intervals of higher benthic diversity are listed in the abundance table (Table T2). These intervals are, roughly, in Cores 1R-6R (505-514 mbsf ), 14R-17R (537-548 mbsf ), and 36R (604-606 mbsf ). Many other samples, often dark and organic rich, are nearly devoid of benthic foraminifers, including samples in which the benthic population consists of a single specimen.

Planktic foraminifers
The stacked unconformities that characterize the bottom of Core 36R and the upper part of Core 37R are summarized in Figure  F21. The bottom of Core 36R (Sample 36R-4, 1-17 cm) is characterized by a bioturbated interval containing abundant larger benthic foraminifers Discocyclina sp. and Asterocyclina, echinoid spines, fish debris, pyrite, and impact glass that has been altered to clay (including several examples with visible vesicles), all of which suggests extensive reworking. This reworked interval extends into the upper 4 cm of Section 37R-1, below which is a 21 cm thick interval (37R-1, 4-26 cm; 607.06-607.27 mbsf ) of laminated black shale almost entirely barren of foraminifers. Calcareous nannofossils mark this interval as equivalent to the PETM. Sieved residues of this black shale, which disaggregates easily, contain carbonate debris (especially echinoid spines), fish teeth, and reworked impact glass, similar to the sandy interval above. One sample (37R-1, 5-5.5 cm; 607.06 mbsf ) contains a few foraminifers that are discolored and abraded and therefore likely reworked. All samples within this black shale contain a component of volcanic glass (including biotite, angular glass shards, and euhedral sanidine crystals).
The PETM black shale clearly unconformably overlies a hardground; the uppermost sample in the hardground (Sample 37R-1, 29-31 cm; 607.31 mbsf ) is barren and entirely composed of sugary calcite. The next several samples (37R-1, 35-39 cm, and 37R-1, 50-52 cm; 607.37 and 607.52 mbsf ) are better preserved and contain a diverse assemblage of late Paleocene planktic foraminifers assigned to Zone P4a based on the presence of Globanomalina pseudomenardii. Overall, these samples contain abundant Morozovellids, including Morozovella angulata, Morozovella acuta, abundant Subbotina spp., Acarinina spp., and few Igorina albeari. Section 37R-1, 58-65 cm, contains rip-up clasts, indicating another disconformity overlying a claystone with an erosionally scoured top. This interval was not sampled during the OSP, but we assume that Zone P4a extends to the base of the rip-up clast layer.
Sample 37R-1, 74-77 cm (607.76 mbsf ), begins a long interval of poorly preserved microfossils in indurated limestone that extends Figure F20. Abundance counts of specimens observed in thin section.   Figure F22). This zone extends to the base of the limestone section in Sample 40R-1, 34 cm (616.34 mbsf ). Based on our sampling resolution (which was conservative to preserve core material through this critical interval), it is not clear if Zone P0 is present. The first sample observed in the limestone already contained an abundant, relatively well preserved assemblage of P. eugubina. Thin section analysis and sieved residues both yielded a large number of the calcareous dinoflagellate Thoracosphaera spp. in  Zone Pα, a bloom event that is found in a large number of lower Danian sediments across the world (Figure F22). Two samples were taken for paleontological analysis in the brown mud/wackestone interval 40R-1, 34-109 cm (Samples 40R-1, 42-43 cm [616.66 mbsf ], and 40R-1, 97-98 cm [617.21 mbsf ]). Both samples contain reworked Cretaceous planktic and benthic foraminifers, including members of the genera Heterohelix, Laeviheterohelix, and Rugoglobigerina ( Figure F22).

Calcareous nannofossils
The interval from Sample 37R-1, 5.4 cm, to Sample 37R-1, 26.0 cm (607.074-607.28 mbsf), is characterized by black shale with abundant organic matter and pyrite observed in smear slide. Samples 37R-1, 6-7 cm (607.08 mbsf), and 37R-1, 11-13 cm (607.13 mbsf ), contain frequent, moderately well preserved D. multiradiatus and Discoaster salisburgensis in addition to Discoaster falcatus, Sphenolithus primus, T. pertusus, and Toweius eminens. The crossover in occurrence of species of Fasciculithus (including Fasciculithus tympaniformis and members of the Fasciculithus schaubii and Fasciculithus alanii groups) and Z. bijugatus strongly suggests that the black shale interval represents the middle PETM within Zone CP8 (Raffi et al., 2009). This correlation is corroborated by the presence of rare excursion taxa (D. salisburgensis var. anartios) that are restricted to the PETM interval (Bybell and Self-Trail, 1995;Bralower and Self-Trail, 2016 that these samples correlate to Zones CP2-CP3. The age of this interval cannot be restricted further because Ellipsolithus macellus, the marker for the base of Zone CP3, has an inconsistent record throughout the hole, and its absence cannot be used reliably. The LO of C. danicus in Sample 38R-2, 90-92 cm (612.5 mbsf ), marks the base of Zone CP2.

Benthic foraminifers
Benthic foraminifers are relatively common in the Paleocene section. The PETM interval is barren. The lowermost sample of black shale (37R-1, 25-26 cm; 607.27 mbsf ) contains several larger benthic foraminifers that appear to have been reworked from the underlying hardground in addition to the other reworked debris found throughout. The hardground contains a number of larger benthic foraminifers visible on the face of the core (see Lithology) that seem to indicate a shallow-water environment, but the large amount of reworked material in the upper portion of the hardground (including altered impact glass, pyrite, and fish debris) would instead suggest reworking from a shallow-water environment outside the crater.
The uppermost sample collected in the hardground was barren; the next two samples (37R-1, 35-39 cm [607.37 mbsf ], and 37R-1, 50-52 cm [607.52 mbsf ]), assigned to Zone P4a, contain a relatively abundant (estimated at 5%-10% benthics, greater than most of the Eocene section) benthic foraminiferal assemblage composed primarily of Bulimina spp., Gyroidina spp., and Cibicidoides spp. This assemblage is broadly indicative of an upper bathyal (300-400 m) depositional environment. Benthic foraminifers are generally rarer through the rest of the Paleocene section. Benthic foraminifer abundance is highest in a sample taken from a claystone (37R-2, 135-136 cm; 609.85 mbsf ), which contains a well-preserved assemblage of mostly large Cibicidoides spp. and Gyroidina spp. Downhole, benthic abundance is generally very low. Thin section analysis also suggests a low-diversity, low-abundance assemblage of benthics through the base of Zone Pα. The lack of diversity precludes an assemblage-based water depth estimate, but the very high planktic:benthic ratio suggests relatively deep waters or seafloor conditions not conducive to benthic life.

Discrete sample measurements
A total of 75 samples from the Post-Impact Sedimentary Rocks interval (Core 1R to Section 40R-1, 109.4 cm; 505.7-617.33 mbsf ) were measured using a superconducting magnetometer. The majority of samples were acquired at a standard resolution of one sample per core. Cores 37R-39R were sampled at a higher resolution of one sample per ~25 cm. The natural remanent magnetization (NRM) was measured for all samples, as well as remanence following stepwise alternating field (AF) demagnetization (in increments of 5 mT) up to maximum applied fields of 15 or 20 mT, depending on the sample. To test whether the remanence present at 15 mT was an overprint, further AF demagnetization to 100 mT was conducted on two samples (34R-2, 44.0-46.5 cm, and 35R-2, 88.0-90.5 cm).

Remanent magnetization
The major components of the post-impact sedimentary rocks include marlstone, claystone, shale, and limestone ( Figure F23A). The initial NRMs of these sedimentary rocks are on the order of 1 × 10 -10 to 8 × 10 -9 Am 2 (for sample volumes of ~12.25 cm 3 ) ( Figure  F23B). The NRMs of the packstone intervals near the base of the column are approximately one order of magnitude higher than those of the overlying sedimentary rocks. This observation is consistent with the multisensor core logger (MSCL) magnetic susceptibility data, which indicate the presence of more ferromagnetic material within the packstone when compared with the overlying sedimentary rocks.
Following AF demagnetization to 15 mT, the remaining magnetizations within sedimentary rocks range between 3 × 10 -11 and 4 × 10 -9 Am 2 . These intensities are often comparable to the magnetic moment of the sample holder of the magnetometer sample handling system (10 -11 to 10 -10 Am 2 ). Due to the typically weak nature of the NRM, the data for most samples are too noisy to determine clear magnetization directions via principal component analysis ( Figure  F24A). The magnetization in most of the sedimentary rocks appears to be dominated by a positive inclination (indicative of normal polarity) and low-coercivity component that is still present after AF demagnetization to 15 mT. At the 15 mT demagnetization step, the mean inclination of all samples exhibiting normal polarity was 50.9° (Figure F23B), essentially equivalent to the 50.7° inclination of the present local magnetic field (determined via the International Geomagnetic Reference Field calculator) at the drilling site within the Chicxulub crater. The two samples that were AF demagnetized to 100 mT changed magnetization directions from positive inclination to negative inclination midexperiment ( Figure F24B). The prevalence of positive inclination data throughout the entire sedimentary column (despite the fact that much of the Post-Impact Sedimentary Rocks interval [Unit 1] was almost certainly lithified during periods of reversed polarity; see Biostratigraphy and Age model and mass accumulation rates) suggests that a pervasive normal polarity remagnetization of these sedimentary rocks likely occurred within the low-coercivity fraction of magnetic grains within the post-impact sedimentary rocks. The normal polarity overprint identified in Unit 1 may either be a viscous remanent magnetization acquired from long-term exposure to the geomagnetic field or a drilling-induced remanent magnetization (e.g., Jackson and Van der Voo, 1985). Both of these forms of remanence may be acquired in the direction of the ambient magnetic field at the time of drilling, so further characterization of rock magnetic properties is required to conclusively differentiate between the two mechanisms. However, as described in Downhole logging, the magnetic field within the borehole periodically (everỹ 15 m) varied between 35 and 50 μT. These sinusoidal fluctuations in field intensity coincided with fluctuations in borehole tilt and scraping patterns etched on the borehole walls seen in downhole images. The fact that such large variations in borehole magnetic field intensity correlate so well with drilling-related properties suggests that drilling-induced remagnetization has likely occurred within the core.
For applications such as magnetostratigraphy, it is important that original detrital remanent magnetizations are properly characterized. Because samples may not typically be demagnetized to >20 mT during OSP standard measurements, full characterization of the underlying primary detrital remanent magnetization components will be reserved for postexpedition research, when demagnetization to higher AF levels will be able to remove overprints. Therefore, a detailed magnetostratigraphy and age model will be developed postexpedition.

Age model and mass accumulation rates
The age model for Site M0077 was constructed using planktic foraminifer and nannoplankton age datums ( Figure F25; Table T4). Paleomagnetic reversal datums are excluded because of pervasive magnetic overprinting and low confidence in the shipboard demagnetization data collected from the Post-Impact Sedimentary Rocks interval (see Paleomagnetism). Sedimentation rates vary widely throughout the interval. The Eocene is characterized by high sedimentation rates (average = 2.3 cm/ky), whereas the Paleocene is characterized by low sedimentation rates (average = 0.22 cm/ky).
The age model was applied to dry bulk density data to generate mass accumulation rates (MARs), including rates for organic carbon and bulk carbonate (Figures F26, F27). In general, organic carbon accumulation is highest in the younger Eocene after rising from nearly zero at the base of the Eocene interval; the carbonate MAR is generally high throughout but also increases from the base of the Eocene interval to a peak at 50 ± 0.5 Ma. Geochemical data are not plotted for the Paleocene because (1) multiple unconformities in the upper Paleocene prevent the calculation of a sedimentation rate and (2) the low accumulation rate in the early Paleocene would not plot at the same scale (i.e., MAR averages 0.09 g/cm 2 /ky in the early Paleocene, two orders of magnitude lower than the Eocene average).

Age model
Seventeen age-diagnostic planktic foraminifer and calcareous nannofossil datums were recognized, ranging from 48.3 to 66.03 Ma (following ages reported in Gradstein et al., 2012). These datums were used to construct an age-depth model ( Figure F25). Datums are reported as the midpoint between the sample containing the datum and the adjacent sample. In most instances, this stratigraphic error is negligible. However, the lowest occurrences of two marker taxa (Acarinina cuneicamerata at the base of Zone E7a and Tribachiatus orthostylus at the base of Zone CP11) occur above a zone of very poor preservation and thus have a stratigraphic uncertainty of several meters (error bars on Figure F25).
Stacked highest and lowest occurrence datums at the base of Core 36R and in Section 37R-1 (~607 mbsf ) indicate that several unconformities are stacked in a short interval. These occurrences are plotted as lowest occurrence datums on the age-depth plot, but they likely do not represent the "true" lowest occurrences of these taxa, and these intervals could fall anywhere within the total range of these species.
It was not possible to apply magnetostratigraphic constraints to the age model for the sedimentary column because the majority of sediment samples carried a pervasive normal polarity magnetic overprint that represents either viscous contamination from the geomagnetic field or drilling-induced magnetization. Because this overprint was not fully removed by AF demagnetization to the maximum applied field levels of 15-20 mT, the underlying detrital remanent magnetization (i.e., the characteristic component utilized for polarity magnetostratigraphy) could not be identified during the OSP.

Linear sedimentation rate
Biostratigraphic datums not interpreted to be truncated by unconformities were used to create a linear sedimentation rate curve ( Figure F25). This curve shows very high sedimentation rates in the Eocene (Cores 1R-36R), averaging 2.3 cm/ky. In the Paleocene (Core 37R through Section 40R-1), sedimentation rates are much lower and average 0.22 cm/ky.

Mass accumulation rates
Linear sedimentation rates are multiplied by dry bulk density to obtain MARs of the bulk sediments. A 500 ky time step was selected for the MAR calculation for the Eocene (Cores 1R-36R) based on the sample spacing of the dry bulk density and geochemical measurements taken during the OSP (Figure F26). The MAR for the Eocene is plotted and ranges from 3.7 to 6.0 g/cm 2 /ky. Error envelopes are calculated for the MAR based on the stratigraphic uncertainty in position of the foraminiferal datums (and therefore uncertainty in the exact sedimentation rate). The MAR is not calculated for sediments between the unconformities spanning Core 36R and Section 37R-1.
Three dry bulk density measurements were taken in the Paleocene post-impact interval in Cores 37R-39R (the sample from Core 40R was below the top of the suevite and is therefore excluded). Obviously, a 500 ky time step is not appropriate for such broadly spaced data; the average MAR for these three cores is 0.09 ± 0.02 g/cm 2 /ky. MARs are multiplied by percent abundance geochemical data to obtain MARs of specific components. MARs for organic carbon and bulk carbonate are plotted in Figures F27 and F28. MARs for Cores 37R-40R are not plotted on these figures due to scale changes; early Paleocene (Zones Pα-P3b) accumulation rates average 0.0045 ± 0.0010 g/cm 2 /ky for organic carbon and 0.89 ± 0.20 g/cm 2 /ky for carbonate, significantly lower than Eocene rates.

Geochemistry and mineralogy
Discrete bulk X-ray fluorescence (XRF), total carbon, and X-ray diffraction data on Core 3R through Section 39R-2 (506.12-615.77 mbsf ) provide a picture of bulk chemistry and mineralogy for the Post-Impact Sedimentary Rocks interval. Additional XRF linescan and μXRF mapping of Section 40R-1 provide a detailed examination of this key succession that represents the transition from the Upper Peak Ring interval to the Post-Impact Sedimentary Rocks interval. CaCO 3 500 ky max.
CaCO 3 500 ky min. Figure F26. MAR for the Eocene interval calculated at a 500 ky time interval, Hole M0077A. Maximum and minimum rates are based on the stratigraphic uncertainty of datum depths. Major and trace elements and carbon and sulfur content
The majority of the samples have variable CaO contents (average ± 1σ = 30.06 ± 11.48 wt%), reflecting the abundance of marlstone and limestone as major lithologies in this section. The CaO content is negatively correlated with the SiO 2 content and linearly correlated to the carbonate carbon (C carb ) content with a slope reflecting the stoichiometry of CaCO 3 (CaO:C carb = 1:1 in molar ratio or 56:12 in weight ratio) (Figure F30). Such abundant carbonate components lower the sum of major elements that are detectable by XRF to much less than 100% (average ± 1σ = 65.22 ± 4.98 wt%) (Table T5).

Carbon and sulfur
Contents of total carbon (C total ), organic carbon (C org ), C carb , and sulfur in the 37 samples from Cores 3R-39R (506.17-614.91 mbsf) are presented in Table T6, and their depth profiles are shown in Figure F31. Reproducibility is within 0.7% for C total and C org and 1.3% for sulfur.
The C carb contents are variable (average ± 1σ = 6.31 ± 2.36 wt%), which quantitatively translates to a total average CaCO 3 content of ~50 wt%. The C org contents (average ± 1σ = 1.01 ± 0.93 wt%) are also variably high. About 85% of the C total contents (average ± 1σ = 7.32 ± 2.58 wt%) are dominated by C carb . Most samples have low sulfur contents (average ± 1σ = 0.38 ± 0.23 wt%), except for one sample at 568.07 mbsf (3.77 wt%). When this high-sulfur sample is included for calculation, the average content is 0.47 ± 0.60 wt% (Table T6). A positive correlation exists between the C org and S contents, suggesting a cogenetic origin.

Trace elements
Trace element compositions of the 37 samples from Cores 3R-39R (506.17-614.91 mbsf) are presented in Table T7, and their depth profiles are shown in Figure F32. Reproducibility was 0.7% for Sr, 0.6% for Zr, and 1.3% for S. Other trace elements exhibit relative errors estimated to be on the order of 5%.
These trace elements show coherent geochemical behaviors; the depth profiles appear to be similar to 535 mbsf. However, below that depth, differences among them become apparent. Trace elements such as Zn, Cr, Ni, and Cu show good positive correlations (R 2 ≥ 0.76) with C org concentrations ( Figure F33).

Section 40R-1: linescan data
The XRF linescan of Section 40R-1 resulted in 140 spot analyses over 142 cm. Data from this scan are plotted as total count rate for the elements Ca, Fe, S, Ni, Pb, Zn, Br, Rb, Zr, K, Si, Al, Sr, Ti, Ba, and Mn versus depth alongside a linescan image and lithostratigraphic column in Figures F34, F35, and F36. This core section is divided into limestone (Subunit 1F) (see Lithology) at the top from 607.27 to 616.58 mbsf, mud/wackestone (Subunit 1G) in the center from 616.58 to 617.33 mbsf and in the interval where suevite begins (Subunit 2A; 617.33-617.66 mbsf ). Subunit 1F is dominated by Ca, with a small spike in S and Fe at 616.29 mbsf. Subunit 1G is also dominated by Ca, with localized enrichments in S and Fe that correlate with relative depletions in Ca. These data indicate that Subunits 1F and 1G are dominantly lime-   stones that contain localized sulfide mineralization. These two limestone intervals are chemically distinct due to the relatively higher Mn, Fe, and Sr concentrations in the mud/wackestone (Sub-unit 1G) that contrast with relatively higher concentrations of Ba, Si, K, Rb, and Pb in Subunit 1F. The contact between Subunits 1F and 1G is characterized by a relative increase in Zr, Rb, Br, S, K, Pb, S, Fe, Ti, and Ba and a significant relative decrease in Ca. Across a distance of 3 to 5 cm (616.54-616.59 mbsf ), sulfide mineralization is evident through the spikes in Fe, S, Ba, and Pb concentrations. This is accompanied by a moderate relative enrichment in Rb, Zr, and Ti and a weak relative enrichment in Si, Al, Sr, Ni, and K.
The contact (~3-5 cm wide in Section 40R-1) between Subunit 1G and the silicate-enriched suevite (Subunit 2A) is characterized by depletion in Ca similar in magnitude to the drop in Ca at the boundary between Subunits 1F and 1G. In the same zone, Ba, Sr, and Pb appear relatively enriched. In this boundary interval, a conspicuous, localized relative Ni enrichment was detected that does not correspond to an S enrichment.
Relative Ca and Si abundances within Section 40R-1 clearly outline the depths that are dominated by CaCO 3 (Figure F34) and silicate minerals (Figure F36). In addition, the abundance of S in this core section shows the occurrence of sulfide or sulfate mineralization. Generally, elements such as Fe, Ni, and Pb correlate with spikes in the S signal, suggesting that these are mostly sulfide mineralizations of pyrite and related assemblages. In contrast, Ca is distinctly anticorrelated with S, which suggests that Ca-sulfates such as gypsum and anhydrite are not the sources of the S excursions.
μXRF Interval 1 (616.54-616.60 mbsf ) The mapped areas (Figures F37, F38) capture a lithologic boundary between the brown mud/wackestone (Subunit 1G) at the   bottom and the greenish to white marlstone, wackestone, and packstone (Subunit 1F) at the top. Subunit 1F is relatively enriched in Si and K compared to Subunit 1G, which has relatively larger concentrations of Mn and Mg. Iron sulfide mineralization occurs as 1 cm nodules and ~1 mm grains in 0.5 mm thick layers in Subunit 1F; Cr is enriched in some of these iron sulfide domains. Cr is also enriched in the boundary layer between Subunit 1G and the greenish transition layer at the bottom of Subunit 1F. A 0.5 mm thick, green marly layer inclined in the upper part of Subunit 1G displays relative enrichment in K, Si, and Cr.
μXRF Interval 2 (~617.00-617.08 mbsf) The second scanned μXRF interval comprises part of Subunit 1G. The mapped region ( Figure F39) captures a carbonate rock that shows a pronounced Mn concentration and millimeter-thick layers enriched in Fe, Si, and Ti. Toward the top of the mapped region, a diffuse relative Si enrichment is apparent.  The third scanned μXRF interval comprises the major lithologic transition between suevite (Subunit 2A) and mud/wackestone (Subunit 1G) ( Figure F40). The mapped region captures the basal part of the brown mud/wackestone, which exhibits contorted pipe structures near the contact to 2.5 cm thick sandy layers (617.315-617.33 mbsf ) that transition to cross-bedded, size-sorted suevite with sand-sized components.
In 0.5 cm thick layers in Subunit 1G and especially in the sandy transition layers, mineral components occur that are relatively enriched in Cr, Fe, Mg, Ti, and Ni. Ni is also enriched in millimeterthick discontinuous layers in the sandy, suevitic transition zone. These Ni-enriched layers do not appear to be correlated with enrichments in any other elements that were mapped.
Subunit 1G also contains <0.5 mm layers that are enriched in Fe and S and some that are very thin and enriched in Si. The contorted pipe structures near the bottom of Subunit 1G are relatively enriched in Mn, whereas they appear relatively depleted in Si.
Our X-ray intensity maps show a relatively sharp boundary between Subunit 1G and the underlying suevite (Subunit 2A) that is characterized by a strong relative enrichment in Si and K and a relative depletion of Ca below, compared to the mud/wackestone (Subunit 1G) above.
μXRF Interval 4 (617.44-617.54 mbsf ) The fourth scanned μXRF interval comprises size-sorted suevite ( Figure F41). The mapped region captures diffuse, subvertical structures that are a few millimeters to 3 cm wide. Compared to the host suevite, these vein networks are relatively depleted in Si and K and enriched in Ca, Mg, and Mn.

Porosity
Porosities range from 5% to 38%. Porosities have a mean value of 27% to 581 mbsf (Subunits 1A-1D) and a mean value of 20% from 581 to 617 mbsf (Subunits 1E-1G) ( Figure F43). In general, porosities are inversely correlated with velocities, with higher porosities corresponding to zones of lower velocity. There is a sharp increase to porosities of ~35% in the underlying suevite (Subunit 2A).

Density
Bulk densities range from 1.8 to 2.6 g/cm 3 with a mean value of 2.0 g/cm 3 to 581 mbsf (Subunits 1A-1D) and a mean value of 2.3 g/cm 3 from 581 to 617 mbsf (Subunits 1E-1G) ( Figure F43). In general, bulk densities follow the same trend as velocities. Densities decrease sharply to 2.0 g/cm 3 in the underlying suevite (Subunit 2A). There is good correspondence between bulk densities measured on discrete samples and bulk densities measured using gamma ray attenuation using the MSCL, although more variation is observed in the MSCL values.

Thermal conductivity
Thermal conductivity values range from 1.4 to 2.6 W/(m·K) with a mean value of 1.8 W/(m·K) to 581 mbsf (Subunits 1A-1D) and a mean value of 2.2 W/(m·K) from 581 to 617 mbsf (Subunits 1E-1G) ( Figure F43). There is a sharp decrease to 1.6 W/(m·K) in the underlying suevite (Subunit 2A). Thermal conductivity values follow the same trend as P-wave velocities and bulk densities.

Resistivity
In general, resistivities measured by the MSCL vary from 1 to 10 Ωm with a mean value of 5 Ωm ( Figure F43). Unlike other physical property measurements, there is no obvious difference in values between Subunits 1A-1D and 1E-1G. Resistivities decrease sharply to 1.5 Ωm in the underlying suevite (Subunit 2A). MSCL resistivities are consistently higher but follow the same trend as that measured in the downhole log. This difference might be explained by the differences in the volume of rock investigated by each of the tools used (MSCL measures a smaller volume than wireline) or the invasion of borehole fluids into the surrounding rock.

Magnetic susceptibility
Magnetic susceptibility values measured by the MSCL are low ( Figure F44). Values range from 0 to 1 × 10 -5 SI to 604 mbsf and increase to a mean value of 1.5 × 10 -5 SI below 604 mbsf. Values increase in the uppermost 10 m of the underlying suevite (Subunit 2A) from 2 × 10 -5 to 37 × 10 -5 SI. Magnetic susceptibility values measured by the MSCL are consistently lower than those measured by the wireline downhole log as a result of the difference in volume investigated between the tools used (MSCL measures a smaller volume than wireline) (e.g., Dubuisson et al., 1995). The MSCL and wireline log trends are similar (compare values in Subunit 2A) de- spite a malfunction of the logging tool (see Downhole logging in the Expedition 364 methods chapter [Gulick et al., 2017]).

Natural gamma radiation
In general, natural gamma radiation (NGR) values measured by the MSCL vary from 0 to 35 counts/s. The NGR mean value is 16.5 counts/s in the upper marlstone section to 581 mbsf (Subunits 1A-1D) and 11.5 counts/s in the lower limestone section from 581 to 617 mbsf (Subunits 1E-1G) ( Figure F44). Some local changes in NGR values correspond to lithostratigraphic subunits (e.g., 597 mbsf ). Values increase sharply to 25-40 counts/s in the underlying suevite (Subunit 2A). The trend of NGR values measured by the MSCL in counts per second is in good agreement with the one from the wireline downhole log in American Petroleum Institute (API) units.

Color reflectance
Similar to many other physical property measurements, there is a change in color reflectance values at ~581 mbsf, the Subunit 1D/1E boundary ( Figure F44). L*, a*, and b* mean values are 32, 1, and 10, respectively, in Subunits 1A-1D and 55, -1, and 5, respectively, in Subunits 1E-1G. There is a sharp decrease in L* values, an increase in a* values, and a smaller decrease in b* values at the contact with the underlying suevite (Subunit 2A). Figure F43. P-wave velocity, porosity, density, thermal conductivity, and resistivity from discrete core samples and downhole measurements, Hole M0077A. mbsf = discrete samples and MSCL, WSF = downhole logs. Yellow curves = downhole measurements of sonic velocity and conductivity converted to resistivity.

Downhole logging
Downhole logging measurements in the Post-Impact Sedimentary Rocks interval were conducted during the second logging session, from 697 m wireline log depth below seafloor (WSF) to the base of the casing at ~507 m WSF (see Figure F26 in the Expedition 364 methods chapter [Gulick et al., 2017]).

Wireline logs
From 507 to 697 m WSF, the hole was very stable, and borehole conditions were excellent. Wireline log data quality is very good (Figure F45), except for the conductivity and magnetic susceptibility measurements, which experienced technical problems during acquisition (see Downhole logging in the Expedition 364 methods chapter [Gulick et al., 2017]). The downhole logs are in agreement with the physical properties measurements performed on wholeround cores and discrete samples (see Physical properties). The gamma ray logs from the various tool strings and runs match well, and only a small number of minor postacquisition depth-shift adjustments (generally less than 5 cm) were required to align the various passes. The base of casing was located at 507.35 m WSF on the acoustic borehole image (ABI) (Figure F45). From 503 to 507 m WSF, gamma ray values are lower than those acquired from farther downhole due to attenuation of the signal through the pipe.
Wireline logs are characterized by moderate to low variability as illustrated in Figure F45. Conductivity (IL) log values range between ~300 and 1080 mmho with an average conductivity of ~700 mmho. Conductivity and sonic logs are anticorrelated, although the conductivity log is of lower resolution. Sonic P-wave velocities range between 1400 and 5500 m/s with an average of ~2800 m/s. Figure F44. Magnetic susceptibility, NGR, and L*, a*, and b* from discrete core samples and downhole measurements, Hole M0077A. mbsf = discrete samples and MSCL, WSF = downhole logs. cps = MSCL values, API = downhole measurements. The maximum velocity was observed at ~607 m WSF, and it correlates with a high-amplitude interval (bright yellow) on the ABI and with chert layers in Core 36R ( Figure F46C) (606.3-607 m WSF; 606.1-606.7 mbsf ). Magnetic susceptibility is low throughout the Post-Impact Sedimentary Rocks interval, as expected for carbonate formations. The borehole fluid temperature (T°f luid ) ranges from 43.6°C below the pipe to 47.2°C at the base of the interval. Borehole fluid conductivity (Cond fluid ) ranges between 76,800 and 81,800 μS/cm, gradually increasing downhole. The fluid parameter logs were acquired shortly after the drilling, so these measurements should only be used qualitatively. The borehole fluid temperature likely reflects a minimum value for the in situ temperature of the formation, whereas the borehole conductivity is affected by the recent drilling operations and the presence of drill mud and seawater in the hole. The ABIs are excellent quality ( Figure F46) due to the high resolution and low logging speed at which the images were acquired and the regular width of the borehole, as shown by the maximum acoustic caliper (ACCAL-max), which gives a mean diameter around 15.6 cm. Traveltime cross sections at several depths indicate that the borehole shape is almost circular. Locally, borehole enlargements (spikes on the ACCAL-max) were observed and correlate in depth Figure F45. Wireline downhole log data, Hole M0077A. Res from IL = resistivity from induction, IL = conductivity, V P = P-wave velocity, MSUS = magnetic susceptibility, GR = total gamma ray, T°(fluid) = borehole fluid temperature, Cond(fluid) = conductivity, Magn.Field = local magnetic field, ABI TT = traveltime acoustic image, ACCAL-max = maximum acoustic borehole diameter, ABI TT cross section = traveltime cross section of the borehole. See Downhole logging in the Expedition 364 methods chapter (Gulick et al., 2017)  with low-amplitude intervals on the ABIs. These likely reflect softer sediments that have been washed out during coring (e.g., ~560-566 m WSF; Figure F45). The ABIs correlate well with the line-scan core data, although a small depth offset is observed between the two data sets (less than ~0.2 m in Figure F46). It should be noted that the ABIs do not necessarily correlate with changes in rock color but rather reflect changes in hardness or rugosity. The character of the logs changes downhole. The sonic log shows larger changes in P-wave velocity values below ~583 m WSF with a slightly increasing trend downhole, whereas the conductivity of the formation decreases. A small decrease in mean gamma ray values was observed below ~590 m WSF. A spike in gamma ray values at ~607 m WSF correlates with a dark layer in Section 37R-1 (Figure F46C), which may correspond to the PETM (see Biostratigraphy).
From 507 to 697 m WSF, the tilt and azimuth given by the ABI tool display sinusoidal and oscillating downhole trends (with a wavelength of about ~15 m) ( Figure F45). These trends may be drilling induced or an effect of a decentralized tool during wireline data acquisition. The magnetic field also follows this trend, and the cause of this oscillation remains to be determined.

Vertical seismic profile
The three-component VSP collected from 500.0 to 650.0 m WSF is generally good quality. The vertical component of the VSP shows a broad-spectrum waveform up to 350 Hz with dominant frequencies at 25 and 64 Hz ( Figure F47A).
First-arrival traveltimes were picked (Figure F47B), and a moving-window algorithm was used to determine the change in P-wave velocity with depth ( Figure F47C). A high-velocity region lies between 590 and 610 m WSF. The signal between 500 and 507 m WSF is affected by the proximity of the pipe. Tube waves are secondary arrivals below 500 m WSF, terminating between 520 and 540 m WSF, and were likely produced by the casing. The radial and azimuthal horizontal component data are of reasonably good quality ( Figure F48). Figure F46. Core-log integration data between downhole logging amplitude ABIs (ABI amplitude) and core line-scan images, Hole M077A. Core images should be shifted downward by as much as 0.21 to align them with the wireline data.   Figure F47. VSP, Hole M0077A. A. Vertical component data recorded at receiver depths between 500.0 and 620.0 m WSF. Noisy traces were removed. Data are stacked and plotted with an automatic gain control. A top mute was applied to remove noise prior to the first breaks. T = possible tube waves. B. One-way traveltime for first-break picks. C. Differential P-wave velocity.