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Study of Anion Effects on Separation Phenomenon for the Vinyloctylimidazolium Based Ionic Liquid Polymer Stationary Phases in GC

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Abstract

Poly-vinyloctylimidazolium ionic liquid polymers with different counter ions (bromide, hexafluorophosphate and bis-trifluoromethanesulfonylimide) were directly coated in capillary fused silica tubing as the stationary phases for gas chromatography. The anion effects on the polymers were examined and discussed. The results suggest that the poly-vinyloctylimidazolium, bis-trifluoromethanesulfonylimide capillary column has the highest thermal stability and separation efficiency. Column-to-column reproducibility was also studied. The results indicate that anions significantly influence ionic liquid polymers which give them potential to extend the range of options for the stationary phases in gas chromatography.

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References

  1. Welton T (1999) Chem Rev 99:2071–2084

    Article  CAS  Google Scholar 

  2. Liu JF, Jonsson JA, Jiang GB (2005) TrAC, Trends Anal Chem 24:20–27

    Article  CAS  Google Scholar 

  3. Koel M (2005) Crit Rev Anal Chem 35:177–192

    Article  CAS  Google Scholar 

  4. Zhao H (2006) Chem Eng Commun 193:1660–1677

    Article  CAS  Google Scholar 

  5. Anderson JL, Armstron DW, Wei GT (2006) Anal Chem 78:2892–2902

    Article  Google Scholar 

  6. Armstrong DW, He L, Liu YS (1999) Anal Chem 71:3873–3876

    Article  CAS  Google Scholar 

  7. Anderson JL, Ding J, Welton T, Armstrong DW (2002) J Am Chem Soc 124:14247–14254

    Article  CAS  Google Scholar 

  8. Anderson JL, Armstrong DW (2003) Anal Chem 75:4851–4858

    Article  CAS  Google Scholar 

  9. Ding J, Welton T, Armstrong DW (2004) Anal Chem 76:6819–6822

    Article  CAS  Google Scholar 

  10. Anderson JL, Armstrong DW (2005) Anal Chem 77:6453–6462

    Article  CAS  Google Scholar 

  11. Berthod A, He L, Armstrong DW (2001) Chromatographia 53:63–68

    Article  CAS  Google Scholar 

  12. Yuan LM, Ren CX, Li L, Ai P, Yan ZH, Zi M, Li ZY (2006) Anal Chem 78:6384–6390

    Article  CAS  Google Scholar 

  13. Liu SJ, Zhou F, Zhao L, Xiao XH, Liu X, Jiang SX (2004) Chem Let 33:496–497

    Article  CAS  Google Scholar 

  14. Qiu H, Jiang S, Liu X, Zhao L (2006) J Chromatogr A 1116:46–50

    Article  CAS  Google Scholar 

  15. Marcilla R, Blazquez JA, Rodriguez J, Pomposo JA, Mecerreyes D (2004) J Polym Sci Part A: Polym Chem 42:208–212

    Article  CAS  Google Scholar 

  16. Bouche J, Verzele M (1968) J Gas Chromatogr 6:501–505

    CAS  Google Scholar 

  17. Papaiconomou N, Yakelis N, Salminen J, Bergman R, Prausnitz JM (2006) J Chem Eng Data 51:1389–1393

    Article  CAS  Google Scholar 

  18. Abraham MH (1993) Chem Soc Rev 22:73–83

    Article  CAS  Google Scholar 

  19. Abraham MH, Whiting GS, Doherty RM, Shuely WJ (1990) J Chromatogr 518:329–348

    Article  CAS  Google Scholar 

  20. Berthod A, Kozak JJ, Anderson JL, Ding J, Armstrong DW (2007) Theor Chem Acc 117:127–135

    Article  CAS  Google Scholar 

Download references

Acknowledgement

The authors are grateful to Professors Hui-Lien Tsai and Hua-Fen Hsu for their generous assistance, and the National Science Council for financial support (NSC. 95-2113-M-006-018).

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Authors and Affiliations

  1. Department of Chemistry, National Cheng Kung University, No.1, Ta-Hsueh Road, Tainan, 70101, Taiwan, ROC

    Yu-Nung Hsieh & Chun-Hsiung Kuei

  2. Department of Cosmetic Science, Chia Nan University of Pharmacy and Science, 60 Erh-Jen Road, Sec.1 Pao-An, Jen-Te Hsiang, Tainan, 717, Taiwan, ROC

    Wen-Yueh Ho

  3. Department of Chemical Engineering, I-Shou University, Kaohsiung, 1 Sec. 1, Syuecheng Rd, Dashu Township, Kaohsiung County, Taiwan, ROC

    Richard S. Horng

  4. Department of Chemical and Materials Engineering, Cheng Shiu University, 840, Cheng Ching Rd., Niaosong, Kaohsiung, 83347, Taiwan, ROC

    Ping-Chih Huang & Ching-Yun Hsu

  5. Department of Electrical Engineering, Cheng Shiu University, 840, Cheng Ching Rd., Niaosong, Kaohsiung, 83347, Taiwan, ROC

    Hong-Hsin Huang

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  1. Yu-Nung Hsieh
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  2. Wen-Yueh Ho
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  3. Richard S. Horng
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  4. Ping-Chih Huang
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  5. Ching-Yun Hsu
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  6. Hong-Hsin Huang
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  7. Chun-Hsiung Kuei
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Correspondence to Chun-Hsiung Kuei.

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Hsieh, YN., Ho, WY., Horng, R.S. et al. Study of Anion Effects on Separation Phenomenon for the Vinyloctylimidazolium Based Ionic Liquid Polymer Stationary Phases in GC. Chroma 66, 607–611 (2007). https://doi.org/10.1365/s10337-007-0334-3

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  • DOI: https://doi.org/10.1365/s10337-007-0334-3

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