Expand this Topic clickable element to expand a topic
Skip to content
Optica Publishing Group

High-resolution spectroscopy of matrix-isolated ReO4 molecules

Not Accessible

Your library or personal account may give you access

Abstract

The temperature-dependent linewidth of the saturable infrared active ν3 vibrational mode (10.8 μm) of ReO4 molecules in pure-KI host crystals has been measured between 2 and 600 K. Below 20 K the absorption line is inhomogeneously broadened and has a 0.016-cm−1 width (FWHM). Above 30 K the transition is homogeneously broadened by elastic acoustic phonon-scattering processes. The low-temperature inhomogeneous width of ReO4 molecules in KI:RbI alloys is 2 orders of magnitude larger than for the pure KI crystal, and the absorption is coincident with the 10.8-μm P(42) CO2 laser line at all temperatures.

© 1981 Optical Society of America

Full Article  |  PDF Article
More Like This
Infrared hole-burning spectroscopy of matrix-isolated ReO4 molecules

A. R. Chraplyvy, W. E. Moerner, and A. J. Sievers
Opt. Lett. 6(9) 431-433 (1981)

CO2 laser saturation of internal-vibrational modes of molecular impurities in alkali halides

A. R. Chraplyvy and A. J. Sievers
Opt. Lett. 3(3) 112-114 (1978)

Persistent infrared hole-burning spectroscopy of matrix-isolated CN molecules

R. C. Spitzer, W. P. Ambrose, and A. J. Sievers
Opt. Lett. 11(7) 428-430 (1986)

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Figures (4)

You do not have subscription access to this journal. Figure files are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Equations (1)

You do not have subscription access to this journal. Equations are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Select as filters


Select Topics Cancel
© Copyright 2024 | Optica Publishing Group. All Rights Reserved