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The Na-Sn (Sodium-Tin) system

  • Section II: Phase Diagram Evaluations
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Journal of Phase Equilibria

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Cited References

  1. C.T. Heycock and F.H. Neville, “The Lowering of the Freezing Point of Na by the Addition of Other Metals,”J. Chem. Soc., 55, 666–676 (1889). (Equi Diagram; Experimental)

    Google Scholar 

  2. G. Tammann, “On the Constitution of Alloys,”Z. Phys. Chem., 3(5), 441–449(1889)in German. (Equi Diagram; Experimental)

    Google Scholar 

  3. C.T. Heycock and F.H. Neville, “The Molecular Weights of Metals in Solution,”J. Chem. Soc., 57, 376–393 (1890). (Equi Diagram; Experimental)

    Google Scholar 

  4. H. Bailey, “An Alloy of Sn and Na with a Definite Composition,”Chem. News, 65(1676), 18 (1892). (Equi Diagram; Experimental)

    Google Scholar 

  5. P. Lebeau, “On the Preparation of Alkaline Arsenides and Optimonides and of Some Alkali Metal Alloys,”C. R. Acad. Sci. (Paris), 130, 502–505 (1900) in French. (Equi Diagram; Experimental)

    Google Scholar 

  6. F. Haber and M. Sack, “Cathode Phenomena as Evidence of the Formation of Alkali Alloys from Cathode Materials,”Z. Elektrochem., 8(18), 245–255 (1902) in German. (Equi Diagram; Experimental)

    Article  Google Scholar 

  7. M. Sack, “On the Origin and Significance of Na Alloys during Cathodic Polarization,”Z. Anorg. Chem., 34(3), 286–352 (1903) in German. (Equi Diagram; Experimental)

    Article  Google Scholar 

  8. C.H. Mathewson, “On Na-Sn Compounds,”Z. Anorg. Chem., 46(1), 94–112 (1905) in German. (Equi Diagram; Experimental; #)

    Article  Google Scholar 

  9. A.G. Vournasos, “On Bismuthides and Intermetallic Compounds,”Ber. Deutsch. Chem. Ges., 44, 3266–3271 (1911) in German. (Equi Diagram; Experimental)

    Article  Google Scholar 

  10. R. Kremann and J. Gmachl-Pammer, “Electromotive Properties of Certain Binary Alloys. V. Electromotive Behavior of Sn-Na Alloys,”Z. Metallkde., 12, 257–262 (1920) in German. (Equi Diagram; Experimental)

    Google Scholar 

  11. W. Biltz and W. Holverscheit, “The Systematic Affinity Principle. XXX. The Heats of Formation of Intermetallic Compounds. VI. Sn Alloys,”Z. Anorg. Chem., 140, 261–276 (1924) in German. (Thermo; Experimental)

    Article  Google Scholar 

  12. C.A. Kraus and H.F. Kurtz, “Reduction of Metals from Their Salts by Means of Other Metals in Liquid Ammonia Solution,”J. Am. Chem. Soc., 47(1), 43–60 (1925). (Equi Diagram; Experimental)

    Article  Google Scholar 

  13. F.W. Bergstrom, “The Action of Solutions of Ammono Bases in Liquid Ammonia on Elements More Electronegative Than Ni,”J. Phys. Chem., 30(1), 12–19(1926). (Equi Diagram; Experimental)

    Article  Google Scholar 

  14. W. Hume-Rothery, “The Nature Properties and Conditions of Formation of Intermetallic Compounds, with Special Reference to Certain Compounds of Sn,”J. Inst. Metals, 35, 295–348 (1926). (Equi Diagram; Experimental)

    Google Scholar 

  15. W. Hume-Rothery, “The System Na-Sn,”J. Chem. Soc., 131, 947–963 (1928). (Equi Diagram; Experimental; #)

    Article  Google Scholar 

  16. E. Zintl and A. Harder, “Metals and Alloys. II. Polyplumbides, Polystannides, and their Transition into Metal Phases,”Z. Phys. Chem.A, 154(1-2), 47–91 (1931) in German. (Equi Diagram; Experimental)

    Google Scholar 

  17. E. Zintl and A. Harder, “Metals and Alloys. XXI. Stoichiometry of Binary Na Compounds,”Z. Phys. Chem. B, 34(3-4), 238–254 (1936) in German. (Crys Structure; Experimental)

    Google Scholar 

  18. W. Biltz, “The Heats of Formation of Intermetallic Compounds,”Z. Metallkde., 29, 73–79 (1937) in German. (Thermo; Compilation)

    Google Scholar 

  19. O. Kubaschewski and W. Seith, “Heats of Formation of NonFerrous Alloys,”Z. Metallkde., 30, 7–9 (1938) in German. (Thermo; Experimental)

    Google Scholar 

  20. K. Hauffe and A.L. Vierk, “Activity Measurements in Liquid Na Alloys with Wide Departure from Ideal Behavior,”Z. Elektrochem., 53(3), 151–161 (1949) in German. (Thermo; Experimental)

    Google Scholar 

  21. N.L. Pokrovskii and N.D. Galanini, “Properties of Metallic Solutions. IV. Surface Tension of Sn and Sn-Na Alloys,”Zh. Fiz. Khim., 23, 324–331 (1949) in Russian. (Equi Diagram; Experimental)

    Google Scholar 

  22. R.L. McKisson and L.A. Bromley, “Heats of Formation of NaSn Alloys Determined with a New High-Temperature Calorimeter,”J. Met., 4(1), 33–38 (1952). (Thermo; Experimental)

    Google Scholar 

  23. Yu. K. Delimars’kii and A.A. Kolotii, “Electrochemical Study of the System Sn-Na,”Zh. Fiz. Khim., 28, 1169–1173 (1954) in Russian. (Thermo; Experimental)

    Google Scholar 

  24. O. Kubaschewski and J.A. Catterall,Thermochemical Data of Alloys, Pergamon Press, London, 23–24(1956). (Thermo; Review)

    Google Scholar 

  25. A.G. Morachevskii and M.F. Lantratov, “Enthalpy of Mixing in the Na-Sn System,”Zh. Obshch. Khim., 29(7), 2109–2113 (1959) in Russian; TR:J. Gen. Chem. USSR, 29(7), 2075–2079 (1959). (Thermo; Experimental)

    Google Scholar 

  26. T. Kleinstuber, Ph.D. thesis, Univ. of Munich (1961); in [73Hul]. (Thermo; Experimental)

  27. N.L. Pokrovskii and T.G. Smimova, “Effects of Additions of Na and Zn on the Structure and Microhardness of Sn,”Fiz. Met. Metalloved. Akad. Nauk SSR, 12(5), 708–713 (1961) in Russian; TR:Phys. Met. Metallog. USSR, 12(5), 75–80 (1961). (Equi Diagram; Experimental)

    Google Scholar 

  28. G.J. Lamprecht, P. Crowther, and D.M. Kemp, “Solubility of Metals in Liquid Na. I. The System Na-Sn,”J. Phys. Chem., 71(13), 4209–4212 (1967). (Equi Diagram; Experimental)

    Article  Google Scholar 

  29. G. Bruzzone, “The Dl3 Structure Type in Intermetallic Compounds.”Acta Crystallogr, B, 25(16), 1206–1207 (1969). (Equi Diagram; Experimental)

    Article  Google Scholar 

  30. D.T.N. Yuan and F.A. Kröger, “Na Activity in Liquid Na-Sn Alloys,”J. Phys. Chem., 73(7), 2390–2392 (1969). (Thermo; Experimental)

    Article  Google Scholar 

  31. P. Hubberstey and A.W. Castleman, “Thermodynamic Properties of Solutions of Group IV Metals in Liquid Na. 2. Na-Sn,”J. Electrochem. Soc., 110(7), 967–970 (1972). (Equi Diagram,Thermo; Experimental)

    Article  Google Scholar 

  32. R. Hultgren, P.D. Desai, D.T. Hawkins, M. Gleiser, and K.K. Kelley,Selected Values of the Thermodynamic Properties of Binary Alloys, American Society for Metals, Metals Park, OH (1973). (Thermo; Compilation)

    Google Scholar 

  33. P. Hubberstey and R.J. Pulham “Solubility of Sn and Ge in Liquid Na,”J. Chem. Soc. Dalton Trans., (14), 1541–1544 (1974). (Equi Diagram; Experimental)

  34. W. Müller and K. Volk, “Crystal Structure of Na3.7Sn or Na15Sn4,”Z. Naturforsch. B, 30(7-8), 494–496 (1975). (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  35. E.A. Maiorova and A.G. Morachevskii, “Thermodynamic Properties of Dilute Solutions of Na in Sn,”Zh. Prikl. Khim. (Leningrad), 49(11), 2537–2539 (1976) in Russian; TR:J. Appl. Chem USSR, 49(11), 2535–2537 (1976). (Thermo; Experimental)

    Google Scholar 

  36. W. Müller and K. Volk, “Crystal Structure of NaSn,”Z. Naturforsch. B, 32(6), 709–710 (1977). (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  37. W. Müller and K. Volk, “Structures of Na9Sn4 and Na15Sn4,”Z. Naturforsch. B, 33(3), 275–278 (1978). (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  38. M. Rivier and A.D. Pelton, “Thermodynamic Properties of Liquid Sn-Na Alloys by emf Measurements with Beta Alumina Electrolytes,”J. Electrochem. Soc., 125(9), 1377–1382 (1978). (Thermo; Experimental)

    Article  Google Scholar 

  39. O.Ya. Gukov and Yu.Ya. Gukova, “Intermetallic Compounds in the NaSn System,” Deposited Document SPSTL 777 Khp-D80, 4 pages (1980) in Russian. (Equi Diagram; Experimental)

  40. A. Rais, N.E. Cusack, and F.E. Neale, “Simultaneous Measurement of Resistivity and Thermodynamic Properties of Liquid Na-In and Na-Sn Alloys,”J. Phys. F, 12(6), 1091–1100(1982). (Thermo;Experimental)

    Article  ADS  Google Scholar 

  41. S. Tamaki, T. Ishiguro, and S. Takeda, “Thermodynamic Properties of Liquid Na-Sn Alloys,”J. Phys. F, 12(8), 1613–1624 (1982). (Thermo; Experimental)

    Article  ADS  Google Scholar 

  42. B.P. Alblas, W. Van der Lugt, J. Dijkatra, K. Geertama, and C. Van Dijk, “Structure of Liquid Na-Sn Alloys,”J. Phys. F, 13(12), 2465–2477 (1983). (Thermo; Experimental)

    Article  ADS  Google Scholar 

  43. R. Alqasmi and J.J. Egan, “Thermodynamics of Liquid Sn-Na Alloys Using CaF2 Solid Electrolytes,”Ber. Bunsenges. Phys. Chem., 87(9), 815–817 (1983). (Thermo; Experimental)

    Google Scholar 

  44. M.L. Saboungi and T.P. Corbin, “Dilute Solutions of Na in Molten Bi and Sn: emf Measurements and Interpretation,”J. Phys. F, 14(1), 13–21 (1984). (Thermo; Experimental)

    Article  ADS  Google Scholar 

  45. M. Iwase, S. Sugino, E. Ichise, and Y. Waseda, “Application of Na+-Ion-Conducting Al2O3 to Thermodynamic Studies of Liquid Na-Based Alloys,”J. Chem. Thermodyn., 17(7), 601–609 (1985). (Thermo; Experimental)

    Article  Google Scholar 

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Authors and Affiliations

  1. Centre de Recherche en Calcul Thermochimique, École Polytechnique, Station “Centre-ville” Montréal, P O Box 6079, H3C 3A7, Quebec, Canada

    J. Sangster & C. W. Bale

  2. Sangster Research Laboratories, Suite 402, 3475 rue de la Montagne, Montréal, H3G 2A4, Québec, Canada

    J. Sangster

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Additional information

This work was partially supported by the United States Department of Energy funds through the Joint Program on Critical Compilation of Physical and Chemical Data coordinated through the Office of Standard Reference Data, National Bureau of Standards. Literature searched through 1991. Dr. Bale is the Alloy Phase Diagram Program Category Co-Editor for binary alkali systems.

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Sangster, J., Bale, C.W. The Na-Sn (Sodium-Tin) system. JPE 19, 76–81 (1998). https://doi.org/10.1361/105497198770342797

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