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Publicly Available Published by De Gruyter January 21, 2013

In search of 3d/4f-metal single-molecule magnets: Nickel(II)/lanthanide(III) coordination clusters

  • Christina D. Polyzou , Constantinos G. Efthymiou , Albert Escuer , Luís Cunha-Silva , Constantina Papatriantafyllopoulou and Spyros P. Perlepes

The importance of 3d/4f-metal cluster chemistry is outlined, and the employment of 2-pyridyl ketone- and 2-pyridyl oxime-based ligands for the preparation of low-nuclearity NiII/LnIII complexes (Ln = lanthanide) is reviewed. The synthetic utility of the “metal complexes as ligands” and “one-pot” approaches is critically discussed. The small nuclearity of the products permits the in-depth analysis of their magnetic properties.


Conference

Eurasia Conference on Chemical Sciences, 12th, Corfu, Greece, 2012-04-16–2012-04-21


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Online erschienen: 2013-1-21
Erschienen im Druck: 2013-1-21

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