The review surveys new data on the directed construction of supramolecular organic–inorganic compounds from macrocyclic cavitand cucurbit[6]uril (C36H36N24O12)and mono- and polynuclear aqua complexes. Due to the presence of polarized carbonyl groups, cucurbit[6]uril forms strong complexes with alkali, alkaline earth and rare-earth metal ions, and hydrogen-bonded supramolecular adducts with cluster and polynuclear aqua complexes of transitional metals. A wide variety of supramolecular compounds and their unique structures are described.
Conference
Mendeleev Congress on General and Applied Chemistry, XVII, Kazan, Tatarstan, Russia, 2003-09-21–2003-09-26
Online erschienen: 2009-1-1
Erschienen im Druck: 2004-9-30
© 2013 Walter de Gruyter GmbH, Berlin/Boston
