Production of Brick Materials from Municipal Solid Waste Ash

A lot of research is currently being done recycling, into how to reuse the waste we produce in our daily lives. This paper presents some of the results from a continuous study of recycling municipal solid waste ash (MSW-ash) into brick materials. In present study, the mixture of municipal solid waste ash and clay are used to make standard bricks fired at 900°C & 950°C. Physical characteristics including density, firing shrinkage, compressive strength and water absorption test of brick materials are reported and discussed. The results of test indicated that the municipal solid waste ash proportion and firing temperature were the two key factors determining the quality of bricks.


INTRODUCTION
Accumulation of waste can be considered as one of the main sources for the environmental pollution.In the last few years, many researchers were interested in studying the problem of industrial wastes.Landfilling of municipal solid waste are not universally, environmentally sustainable and economically feasible disposal methods.Incineration of municipal solid waste is also a seemingly unsustainable solution as emissions from the burning waste (ash) contain various hazardous substances 1 .Recycling of municipal solid waste ash by incorporating them into building or ceramic materials is a practical solution to the pollution problem.
This paper describes some of the procedures and results from a study on incorporating municipal solid waste ash (MSW-ash) into brick specimens.Properties (density, linear shrinkage, compressive strength and water absorption test) of brick specimens with different MSW-ash additions are presented and discussed.
The materials used in this research work are municipal solid waste ash (MSW-ash) and clay.The MSW-ash and clay mixtures were then intruded into a series of standard bricks molds (8.0 X 4.5 X 2.5 cm).After forming, the specimens were dried in open atmosphere (3 days) and then in an oven dried for 24 hours at 110 °C.Then dried samples were fired at 900 and 950 °C respectively for 1 hour in a muffle furnace.The physical parameters of fired brick specimens, viz, density, firing shrinkage, compressive strength, and water absorption determined.The bulk density was evaluated by dividing accurately measured mass of sintered samples by external volume (dimensional method ).The firing shrinkage (%) was evaluated using the formula.Where by Lg and Ls are the accurate by measured length of green and sintered samples, respectively 3 .The Compressive strength was tested using Compressive testing machine.The rate of pressure applied to brick break and break point was measured for compressive strength.The Compressive strength was calculated using the formula 4 .
The Water absorption (%) of the sintered brick was determined using the procedure outlined in the Indian Standards Specifications 5 .The Water absorption (%) was calculated using the formula 2&6 .
Where by W 1 and W 2 are the weight of the fired specimen and weight of the brick specimen after 24 hours of immersion in water.

RESULTS AND DISCUSSION
At least five samples were used in each test for all categories and the average values are presented and discussed in this section.In the present study, the brick materials are analyzed Density, Firing shrinkage , Compressive strength and Water absorption test and this reports are summarized in table 1.

Density of bricks
The brick specimens made with clay normally have a bulk density of approximately 2.00 g/cm 3 .The measurements of bulk density for different proportions of MSW-ash brick fired at two temperatures (900 and 950°C) are demonstrated in figure 1.As shown, the bulk density of brick specimens is inversely proportional to the quantity of MSW-ash added in the mixture.This finding is closely related to the quantity of water absorbed as demonstrated in figure 4. When brick absorb more water, it exhibits a large pore size, resulting in a light density 6 .The firing temperature can also affect the bulk density of the bricks 6 .The results show that increasing the temperature results in an increase in bulk density.In the present investigation, a linear relationship between the density and MSWash proportion in the mixture for two temperatures are observed.

Firing shrinkage of bricks
The quality of brick can be further assured according shrinkage to the degree of firing 6&7 .Normally good quality brick exhibits shrinkage below 8%.For a brick, the shrinkage is 2.55 -0.42 (%) and 2.85 -0.50 (%) at firing temperatures of 900°C and 950 °C.The firing temperature is another parameter affecting the degree of shrinkage 6 & 7 .High shrinkage causes destruction of bricks both in firing and drying stages of production.Shrinkage in bricks occurs as chemically and mechanically bound water is lost.A linear relationship between the shrinkage and the MSW-ash proportion was observed for 5 to 25 % MSW-ash added.In general, increasing the firing temperature results in an increase in shrinkage (fig.2).

Compressive strength of bricks
The compressing test is the most important test for assuring the engineering quality of building materials 7 & 8 .The variation in Compressive strength of the brick specimen made from clay -MSW ash mixture is shown in figure 3.
The results indicate that the strength is greatly dependent on amount of MSW-ash in the brick and the firing temperature.Fig. 3 shows that the compressive strength of bricks decreases with the increase of the MSW-ash mix in the bricks.

Water absorption test of bricks
Water absorption is a key factor affecting the durability of brick.The less water infiltrates into brick, the more durability of the brick and resistance to the natural environment are expected 7 .Thus, the internal structure of the brick must be intensive enough to avoid the intrusion of water.The Water absorption was determined by using the standard procedure 9 described in ASTM C67 (1998).
Fig. 4 shows the results of the test for different proportions of MSW-ash in the mixture fired at two temperatures.As shown, the water absorption for the bricks increases with increased MSW-ash addition and decreased firing temperature, thereby decreasing its weathering resistance 6 .According to the criterion of Water absorption of bricks in ASTM C67 (1998), the ratio is below 17% for first class brick and 17 to 22% for second class brick.When the mixture contains less than 10% MSW-ash and is fired at 900°C and 950 °C, the brick products, should belong to the first-class category based on the percentage of absorbed water.

CONCLUSIONS
This research work has demonstrated a feasible way of using incinerated municipal solid waste ash (MSW-ash) as clay substitute to produce quality bricks.Different measurements of both clay -ash admixtures and brick were carried out to evaluate the factors that could affect brick quality.Major findings in the study are as follows.´In order to yield a good quality brick, the proportion of MSW-ash in the mixture and firing temperature are important key factors controlling the shrinkage in the firing process.
Increasing the firing temperature results in an increase in shrinkage.´The bulk density of brick samples is directly proportional to the firing temperature and the density of the brick samples gradually decreases with increasing MSW-ash addition.´The results of compressive strength tests on the bricks made from both clay and municipal solid waste -ash indicate that the strength is greatly dependent on the amount of MSWash in the brick and the firing temperature.´The amount of water absorption is inversely proportional to firing temperature and the amount of water absorption is also directly proportional to quantity of MSW-ash added.
It is concluded from the present studies, the optimum amount of municipal solid waste -ash could be mixed with clay to produce good bonding of brick was 5% by weight and fired at 950 °C gives the most favourable results.