Abstract
In this work the results of studies on the prepolymeric method of obtaining poly(urethane-urea)s from oligocarbonatediols and isophoronediisocyanate (IPDI), cured with water vapor, are presented. α,ω-Bis(2-hydroxyethoxycarbonylamino)alkanes (dihydroxydiurethanes, DHDU) incorporated into the structure of oligocarbonatediols and as pseudo-chain extenders were used for the synthesis of prepolymers. The oligocarbonatediols were obtained by the thermal polymerization of trimethylene carbonate (TMC) using 1,3-propanediol and DHDU as initiators. The poly(urethane-urea)s obtained exhibited very good mechanical properties (e.g.: tensile strength of 45.5 MPa and elongation at break up to 580%).
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Pawłowski, P., Szymański, A., Kozakiewicz, J. et al. Poly(urethane-urea)s Based on Oligocarbonatediols Comprising Bis(carbamate)alkanes. Polym J 37, 742–753 (2005). https://doi.org/10.1295/polymj.37.742
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DOI: https://doi.org/10.1295/polymj.37.742