Abstract
The paper presents information on the synthesis and properties of a composite material consisting of an electronically conducting polymer and a polyanion. This kind of materials are of current interest. Polypyrrole- carboxymethyl cellulose composite have been studied on two different substrates: platinum and indium tin oxide. Electrochemical, SEM, and U.V-visible techniques have been used. The mechanism in both electrodes seem to be the same, but the morphology was quite different with the same electrodeposition conditions. Dendritycal growth on indium tin oxide in special conditions has been observed.
Similar content being viewed by others
Article PDF
References
J. Wang, S. P. Chem, and M. S. Lin, J. Electroanal. Chem., 273, 231 (1989).
S. Dang, Z. Sund, and Z. Lu, Analyst, 113, 1525 (1983).
H. Mao and P. G. Pickup, J. Electroanal. Chem., 265, 127 (1989).
H. S. White, G. P. Kittlesen, and M. S. Wrighton, J. Am. Chem. Soc., 106, 7389 (1984).
H. Yoneyama, K. Wakamoto, and H. Tamura, J. Electrochem. Soc., 132, 2414 (1985).
P. J. Nigrey, D. Macinnes, J.r., G. MacDiarmid, and A. J. Heegon, J. Electrochem. Soc., 128, 1651 (1981).
H. Shirakawa, S. Okada, M. Aizawa, J. Yoshitake, and S. Suzuki, Synth. Met., 4, 43 (1981).
B. Zinger and L. L. Miller, J. Am. Chem. Soc., 106, 6861 (1984).
L. L. Miller and Q. X. Zhon, Macromolecules, 20, 1594 (1987).
S. Asavapiriyanont, G. K. Chandler, G. A. Gunawardena, and D. Pletcher, J. Electroanal, Chem., 177, 229 (1984).
P. G. Pickup and R. A. Osteryoung, J. Am. Chem. Soc., 106, 2294 (1984).
R. E. Noftleand and D. Pletcher, J. Electroanal. Chem., 229, 227 (1987).
B. R. Scharifker, E. Garcia-Pastoriza, and W. Marino, J. Electroanal. Chem., 300, 85 (1991).
R. John and G. Wallace, J. Electroanal. Chem., 306, 157 (1991).
D. Rosseins Ky, N. Norse, R. Slade, G. Hix, R. Mortimer, and D. Walton, Electrochim. Acta, 36, 733 (1991).
I. Rodríguez, M. Marcos, and J. González Velasco, Electrochim. Acta, 32, 1181 (1987).
A. Díaz, J. Grownley, J. Bargon, G. P. Gardini, and J. Torance, J. Electroanal. Chem., 121, 355 (1981).
J. L. Bredas, R. Silbey, D. S. Boudreaux, and R. R. Chance, J. Am. Chem. Soc., 105, 6555 (1983).
D. J. Fermín and B. R. Scharifker, J. Electroanal. Chem., 357, 273 (1993).
B. R. Scharifker and D. J. Fermín, J. Electroanal. Chem., 365, 35 (1994).
M. Ghalamians, T. N. Suresk Duman, A. Q. Contractor, Proc.-Indian Acad. Sci., Chem. Sci., 97, 457 (1986).
T. F. Otero, P. Herrasti, P. Ocón, and C. R. Alves, Electrochim. Acta, 43, 1089 (1998).
G. de T. Andrade, M. J. Aguirre, and S. R. Biaggio, Electrochim. Acta, 44, 633 (1998).
T. F. Otero and E. De Larreta-Azelain, J. Chem. Phys., 86, 131 (1987).
M. Zhou and J. Heinze, Electrochim. Acta., 44, 1733 (1999).
M. M. Mullins and R. F. Sekerka, J. Appl. Phys., 34, 323 (1963).
J. S. Langer, Rev. Mod. Phys., 52, 1 (1980).
J. H. Kaufman, O. R. Melroy, F. F. Abraham, A. I. Nazzal, and A. Kapitulnik, Synthetic Metals, 18, 19 (1987).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Alves, C., Herrasti, P., Ocón, P. et al. Electrodeposition of Polypyrrole/Carboxymethyl Cellulose on Platinum and Indium Tin Oxide. Polym J 33, 255–262 (2001). https://doi.org/10.1295/polymj.33.255
Issue Date:
DOI: https://doi.org/10.1295/polymj.33.255
Keywords
This article is cited by
-
Hydrazone-linked soybean protein isolate-carboxymethyl cellulose conjugates for pH-responsive controlled release of pesticides
Polymer Journal (2019)
-
Polyaniline- and poly(ethylenedioxythiophene)-cellulose nanocomposite electrodes for supercapacitors
Journal of Solid State Electrochemistry (2014)