Reaction of ammonium imidodisulfate and cyclohexylamine at 170° results in quantitative formation of cyclohexylammonium cyclohexanesulfamate according to the following equation:
HN(SO₃NH₄)₂+4C₆H₁₁NH₂=2C₆H₁₁NHSO₃HC₆H₁₁NH₂+3NH₃
If this reaction is carried out at refluxing temperature and ordinary pressure, cyclohexylammonium imidodisulfate is obtained according to the following equation:
NH(SO₃NH₄)₂+2C₆H₁₁NH₂=HN(SO₃HC₆H₁₁NH₂)₂+2NH₃
In this reaction, if ammonium chloride, ammonium nitrate, or cyclohexylamine hydrochloride is added during the reaction, cyclohexylammonium cyclohexanesulfamate is obtained by the first equation.