Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Notes
Studies on the Constituents of Syringa Species. XII.
New Glycosides from the Leaves of Syringa reticulata (BLUME) HARA
Koichi MachidaEriko UnagamiHiromi OjimaMasao Kikuchi
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2003 Volume 51 Issue 7 Pages 883-884

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Abstract

Three new glycosides, 6′-O-α-D-galactopyranosylsyringopicroside (1), secologanoside 7-methyl ester (2) and (+)-lariciresinol 4′-O-β-D-glucopyranosyl-(13)-β-D-glucopyranoside (3), were isolated from the leaves of Syringa reticulata. Their structures were established on the basis of chemical and spectral data. Compound 1 is the first naturally occurring iridoid di-glycoside having melibiose. Comparison of the spectral data of 2 and that previously recognized as secologanoside 7-methyl ester led to the conclusion that the recognized structure should be revised to the sodium salt of secoxyloganin (2′).

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© 2003 The Pharmaceutical Society of Japan
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