Structure Analysis of Gd2CuO4: a New Modification of the T' Phase

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Published under licence by IOP Publishing Ltd
, , Citation M. Braden et al 1994 EPL 25 625 DOI 10.1209/0295-5075/25/8/011

0295-5075/25/8/625

Abstract

Neutron diffraction on a single crystal of Gd2CuO4 shows a long-range superstructure of the T' phase. The oxygen squares surrounding the Cu sites are rotated around the c-axis (by an angle of 5.2° at room temperature) leading to a reduced orthorhombic symmetry (space group: Acam). The reported structural deformation can explain previous results (weak ferromagnetism and Mössbauer effect) and might help to explain the non-existence of superconductivity in Gd2−xCexCuO4.

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10.1209/0295-5075/25/8/011