Adsorption-induced anchoring transition in cylindrically confined liquid-crystal hydrophobic aerosil dispersions

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Published 15 December 2004 2005 EDP Sciences
, , Citation T. Jin and D. Finotello 2005 EPL 69 221 DOI 10.1209/epl/i2004-10322-3

0295-5075/69/2/221

Abstract

An adsorption-induced anchoring transition was found by confining liquid-crystal hydrophobic aerosil dispersions to cylindrical pores. The aerosil effects on the director configurations and on the orientational-order wetting at the pore walls were determined by DNMR. The aerosil spheres are adsorbed at the pore wall, hindering the planar anchoring and inducing an axial-to-radial structural transition dependent on increasing aerosil density. The orientational-order surface wetting in the isotropic phase is modified by the aerosil-introduced disorder from quasi-complete to partial to non-wetting.

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10.1209/epl/i2004-10322-3