K/Si(100) 2 × 1: A Case Study for the Transfer of Charge between Alkali Metals and Semiconductor Surfaces

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, , Citation E. M. Oellig et al 1988 EPL 5 727 DOI 10.1209/0295-5075/5/8/011

0295-5075/5/8/727

Abstract

Experimental data and theoretical calculations for K/Si(100) 2 × 1 provide a picture of the interface interaction essentially similar to the one established for adsorption of alkali metals on metals in contradiction with recent calculations. In particular, the transfer of charge from K to Si decreases with coverage and it is far from being complete at saturation coverage. The K-Si bond length and the charge transfer indicate that the bonding has a substantial covalent character.

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10.1209/0295-5075/5/8/011