On the Interdiffusion Coefficient in Entangled Polymeric Mixtures

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Published under licence by IOP Publishing Ltd
, , Citation W. Hess and H. L. Frisch 1988 EPL 5 391 DOI 10.1209/0295-5075/5/5/002

0295-5075/5/5/391

Abstract

Using an expression for the tracer diffusion coefficient which is obtained from a microscopic concept of entanglement friction, it is shown that two concurring expressions for the interdiffusion coefficient, Dfast and Dslow, are the same. The interdiffusion process in a mixture of two polymers is dominated by the fast component.

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10.1209/0295-5075/5/5/002