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Fluctuations and Phase Behavior of Fluid Membrane Vesicles

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Published under licence by IOP Publishing Ltd
, , Citation D. C. Morse and S. T. Milner 1994 EPL 26 565 DOI 10.1209/0295-5075/26/8/002

0295-5075/26/8/565

Abstract

We consider the behavior of a dilute phase of bilayer surfactant vesicles. We show that the free energy of a single vesicle increases logarithmically with vesicle size, due to a previously unappreciated finite-size contribution to the fluctuation free energy, in contrast to previous studies, which assumed a logarithmic decrease of the free energy due to thermal softening of the bending rigidity. This result leads to qualitatively different predictions for the behavior of an equilibrium vesicle phase.

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10.1209/0295-5075/26/8/002