Electrochemical Characterization of Nano-Structured Graphene Oxide/CNT Electrodes Containing Sulfur for Lithium Rechargeable Cells
Graphene Oxide (GO)/CNT-sulfur (S) composites were prepared by a method, in which PDDA coated on the CNT could interact with negatively charged GO. It was found that the GO/CNT-S composites showed the enhanced charge transfer by conducting network of GO/CNT and the improved sulfide
ion movement. It is related to the improved surface area, because positively charged CNT would be used as a modifier for graphene sheets exfoliation. Electrochemical performances of prepared composites were evaluated in lithium-ion cells by cyclic voltammetry and galvanostatic cycling. When
applied as the cathode material in lithium sulfur cells, GO/CNT-S composites exhibited a high reversible capacity of 1152.9 mAh g−1 in the first cycle and maintain a satisfactory cyclability. The results indicate that the GO/CNT-S composites based lithium sulfur cells have
a potential to replace the current lithium-ion cells.
Keywords: Carbon Nanotubes; Electrochemical Property; Graphene Oxide; Lithium-Sulfur Cells
Document Type: Research Article
Affiliations: Department of Chemical and Biochemical Engineering, Pusan National University, San 30, Jangjeon-dong, Geumjeong-gu, Busan 609-735, Korea (South)
Publication date: 01 September 2016
- Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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