Skip to main content
SpringerLink
Log in

Oxidative dehydrogenation of ethylbenzene with carbon dioxide over zeolite-supported iron oxide catalysts

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

Oxidative dehydrogenation of ethylbenzene with carbon dioxide was carried out over ZSM-5 zeolite-supported iron oxide catalysts. In the presence of carbon dioxide, ethylbenzene was predominantly converted into styrene by oxidation. It was found that carbon dioxide in this reaction plays a role as a soft oxidant to greatly improve catalytic activity. An active phase for the dehydrogenation with carbon dioxide was suggested as rather reduced and isolated magnetite-like phase having oxygen deficiency in zeolite matrix.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. B. Delmon and J. T. Yates, Studies in Surface Science and Catalysis, Elsevier, Amsterdam, vol. 114 (1998).

    Google Scholar 

  2. H. Arakawa, Stud. Surf. Sci. Catal. 114, 19 (1998).

    Google Scholar 

  3. J. N. Amor, Stud. Surf. Sci. Catal. 114, 141 (1998).

    Google Scholar 

  4. S.-E. Park, J.-S. Chang, and J. S. Yoo, Enviromental Challenges and Greenhouse Gas Control for Fossil Fuel Utilization in the 21st Century. Kluwer Academic/Plenum Publishers, New York (2001) (in press).

    Google Scholar 

  5. J. S. Yoo, P. S. Lin and S. D. Elfine, Appl. Catal. 106, 259 (1993).

    Google Scholar 

  6. J. S. Yoo, Catal. Today 41, 409 (1998).

    Google Scholar 

  7. O. V. Krylov and A. Kh. Mamedov, Ind. Eng. Chem. Res. 34, 474 (1995).

    Google Scholar 

  8. J.-S. Chang, S.-E. Park and M. S. Park, Chem. Lett. 1123 (1997).

  9. J.-N. Park, J. Noh, J.-S. Chang and S.-E. Park, Catal. Lett. 65, 75 (1999).

    Google Scholar 

  10. Y.-S. Choi, Y.-K. Park, J.-S. Chang, S.-E. Park and A. K. Cheetham, Catal. Lett. 69, 93 (2000).

    Google Scholar 

  11. S.-E. Park, J.-S. Chang and M. S. Park, Prep. ACS Fuel Chem. Div. 41, 1387 (1996).

    Google Scholar 

  12. J.-S. Chang, S.-E. Park, J. W. Yoo and J. N. Park, J. Catal. 195, 1 (2000).

    Google Scholar 

  13. Y. Ohtsuka, J. Catal. 186, 160 (1999).

    Google Scholar 

  14. F. Cavani and F. Trifiro, Appl. Catal. 133, 219 (1995).

    Google Scholar 

  15. N. Mimura, I. Takahara, M. Saito, T. Hattori, K. Ohkuma and M. Ando, Catal. Today 45, 61 (1998).

    Google Scholar 

  16. M. Sugino, H. Shimada, T. Turuda, H. Miura, N. Ikenaga and M. Suzuki, Appl. Catal. 121, 125 (1995).

    Google Scholar 

  17. T. Hirano, Appl. Catal. 28, 119 (1986).

    Google Scholar 

  18. J. Matsui, T. Sodesawa and F. Nozaki, Appl. Catal. 67, 179 (1991).

    Google Scholar 

  19. C. R. F. Lund and J. A. Dumesic, J. Phys. Chem. 85, 3175 (1981).

    Google Scholar 

  20. M. Kruk, M. Jaroniec, C. H. Ko and Ryong Ryoo, Chem. Mater. 12, 1961 (2000).

    Google Scholar 

  21. J.-S. Chang, S.-E. Park, W. Y. Kim, M. Anpo and H. Yamashita, Stud. Surf. Sci. Catal. 114, 387 (1998).

    Google Scholar 

  22. Y. Tamaura and M. Tabata, Nature 346, 255 (1990).

    Google Scholar 

  23. J.-S. Chang, S.-E. Park, H. S. Roh and Y. K. Park, Bull. Kor. Chem. Soc. 19 (12), 1342 (1998).

    Google Scholar 

  24. M. T. Sananes, I. J. Ellison, S. Sajip, A. Burrows, C. J. Kiely, J. C. Volta and G. J. Huchings, J. Chem. Soc., Faraday Soc. 92 (1), 137 (1996).

    Google Scholar 

  25. B. Pugin, J. Mol. Catal. 107, 273 (1996).

    Google Scholar 

  26. B. Notari, Stud. Surf. Sci. Catal. 60, 343 (1988).

    Google Scholar 

Download references

Authors
  1. Min Seok Park
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jong-San Chang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Dae Sung Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Sang-Eon Park
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Park, M.S., Chang, JS., Kim, D.S. et al. Oxidative dehydrogenation of ethylbenzene with carbon dioxide over zeolite-supported iron oxide catalysts. Research on Chemical Intermediates 28, 461–469 (2002). https://doi.org/10.1163/156856702760346879

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1163/156856702760346879

Keywords

Search

Navigation