Single-Stage Microwave-Assisted Coconut-Shell-Based Activated Carbon for Removal of Dichlorodiphenyltrichloroethane (DDT) from Aqueous Solution: Optimization and Batch Studies

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Introduction
e global awareness of the threat of toxicity that comes from persistent organic pollutants (POPs) had led to the ban of their usage since the past 40 years ago [1]. POPs can be defined as a group of compounds which is synthetically produced having a high strain on the environment. Since they are significantly resistant to chemicals, they can resist breaking down for many years and continuously exist in the environment [2]. POPs can be recognized based on three main characteristics: (i) be high in toxicity, (ii) persistently bioaccumulate in the organisms' fatty tissue, thus moving to the food chain, and (iii) have the ability to be transferred over long distances in the forms of gaseous or particulate matter [3]. According to Guo et al. [4], there are three main groups under POPs. e first group is pesticides, mainly organochlorine pesticides (OCPs) like dichlorodiphenyltrichloroethane (DDT) and its metabolites. e second group is industrial and technical chemicals such as polychlorinated biphenyls (PCBs), perfluorooctanesulfonate (PFOS), and polybrominated diphenyl ethers (PBDEs). e last group is polychlorinated dibenzo-p-dioxins (PCDDs), polyaromatic hydrocarbons (PAHs), and polychlorinated dibenzofurans (PCDFs) which are formed as byproducts in industrial processes. DDT is one of the most popular pesticides used to increase crop production by killing unwelcomed pests. Unfortunately, serious health effects are observed to be associated with DDT such as nervous system dysfunction [5], endocrine disorder [6], dysfunction of the immune system [7], toxic effect on the reproductive system [8], and carcinogenic properties [9]. DDT has been traced in numerous types of foods, namely fish, milk, poultry, vegetables, fruits, cereals, and flour [10].
Some methods developed to treat wastewater containing DDT and other types of POPs were mechanochemical ball milling [11], bioremediation [12], electrokinetic remediation [3], and electrocoagulation [13]. Alas, these methods are restricted by extensive energy demand, the high cost of chemicals, and the development of secondary pollution. e adsorption process by using activated carbon (AC) as an adsorbent is seen as one of the best methods to treat wastewater containing POPs. Based on its ability to adsorb a wide range of pollutants, AC is also best known as a universal adsorbent. Several works done by researchers proved that AC is extremely versatile in removing pollutants such as cationic dyes [14,15], anionic dyes [16,17], heavy metals [18], phenolic compound [19], antibiotic [20], painkiller [21], carbon dioxide, CO 2 gas [22], hydrogen sulfide, H 2 S gas [23], and many others. Nevertheless, the application of AC is limited by the expensive cost of the precursors or starting materials. Because of that, for the past decade, researchers are actively converting lignocellulosic materials into AC including durian peel [14], peanut shell [24], corncob [18], meranti wood [25], pomegranate peel [26], Glyricidia sepium [27], acacia sawdust [28], durian seed [29], and others. e majority of these materials are wastes from agricultural activities which can be obtained in a large quantity, have continuous supply over the year, and are low in cost. Southeast Asian countries like Malaysia, Indonesia, ailand, Myanmar, and Vietnam can gain economic benefit by converting these unwanted agricultural wastes into AC, besides solving the disposal problem of these wastes. e complex connection between variables and responses which usually follows nonlinear theoretical models can figure out using computational intelligence methods [30]. Two of the most reliable computational intelligence methods are the fuzzy logic model (FLM) and response surface methodology (RSM). RSM was successfully implemented in many research due to its ability to evaluate multiple variables at once at a minimal number of experiments. Furthermore, other benefits of RSM include the ability to analyze the interaction effect between variables, generating three-dimensional (3D) graphs to relate variables and responses, and, last but not least, analysis of variance (ANOVA) is available to validate the results. In this study, an attempt was carried out to convert coconut shell into AC (CSAC) via microwave irradiation technique to adsorb DDT. RSM was employed to obtain optimum preparation conditions of radiation power and radiation time, which resulted in optimum DDT removal and CSAC's yield. To the best of the authors' knowledge, no work on optimizing microwave-induced-CSAC via RSM in adsorbing DDT has been reported in the literature.

Materials.
e coconut shell was obtained from a local market in Nibong Tebal, Pulau Pinang. Once received, the raw coconut shell was washed thoroughly with water and dried in an oven for 24 hours at a temperature of 110°C. en, the dried coconut shell was ground into smaller pieces between the size of 0.5 and 1 mm. Nitrogen, N 2 gas, and carbon dioxide, CO 2 gas, utilized during carbonization and activation processes were obtained from MOX Gases Berhad, Malaysia. DDT was supplied from Modern Lab Sdn. Bhd.

Preparation of CSAC.
e dried coconut shell was subjected to an activation process via the microwave irradiation technique. 50 g of char was loaded inside a Pyrex glass tube and, then, placed inside the microwave's chamber. e microwave was turned on at different radiation power levels of 364, 490, and 616 Watt and different radiation times of 2, 4, and 6 minutes. During this activation process, CO 2 has flowed through the microwave at a flowrate of 150 cm 3 / min. CO 2 was crucial at this stage to provide a gasification effect on the sample, thus enhancing the development of the pore on the sample. e resulted product at the end of this process is called CSAC. e yield of CSAC was calculated using the following equation: where W f and W i are the weight of CSAC and dried weight of coconut shell, respectively.

Sample Analysis System.
e Agilent 1260 High-Performance Liquid Chromatography (HPLC), Eclipse C-18 column was used to identify the concentration of DDT in the water solution. In this method, the liquid samples were pump in a solvent known as the mobile phase at high pressure through a separation column. e separation column is a stationary phase consisting of packing materials made of densely packed, often chemically functionalized beads. e difference in the analyte's affinity for the solvent (mobile phase) and stationary phase enables separation to occur. e detection wavelength was set at 238 nm.

Characterization Methods.
Characterization of CSAC was made in terms of surface area, pore characteristic, surface morphology, proximate analysis, surface chemistry, and zeta potential. e surface area, pore volume, and average pore diameter of samples were determined by using a volumetric adsorption analyzer (Model: Micromeritics ASAP 2020), which was based on nitrogen gas adsorption at 77 K. e surface area was measured from adsorption isotherm using Brunauer-Emmett-Teller (BET) equation. Total pore volume was estimated to be the liquid volume of nitrogen at a relative pressure of 0.99. e surface morphology of samples was examined using a scanning electron microscope (SEM) ((Model: LEO SUPRA 55VP, Germany). Proximate analysis of the sample was carried out using STA (Model Perkin Elmer STA 6000, USA). From the STA result, the moisture, volatile matter, fixed carbon, and ash contents can be obtained by considering the weight of the sample as 100%. e chemical characteristics of the surface functional group of CSAC were detected by mixing the AC sample in K-Br pellets recorded with Fourier transform infrared (FTIR) spectroscope (Model: IR Prestige 21 Shimadzu, Japan) in 400-4000 cm −1 wavenumber range. e zeta potential of CSAC was determined using a zeta potential analyzer (Zetasizer Nano Series DKSH).

Experimental Design.
Another aim in this research was to optimize the conditions in preparing CSAC by utilizing a standard RSM design called Central Composite Design (CCD). Software known as Design Expert (STAT-EASE Inc., Minneapolis, USA) version 6.0.6 was used to fulfill the optimization purpose. Radiation power (X 1 ) and radiation time (X 2 ) were selected as the variables whereas DDT removal (Y 1 ) and CSAC's yield (Y 2 ) were chosen as responses. Table 1 presents the variables and responses, together with experimental ranges and levels. Since 2 variables were studied, a design matrix with 13 experiments was generated which comprised 5 factorial points, 3 axial points, and 5 replicates. e replication was fruitful in determining the error of experiments. e quadratic model developed by RSM was expressed as follows: where Y is the predicted response; b 0 , b i , b ij, and b ii are the constant coefficient, linear coefficient, interaction coefficient, and quadratic coefficient, respectively; x i and x j are the coded values of the AWAC preparation variables; and e i is the error. e adsorption process was conducted by placing 200 mL of DDT solution with an initial concentration of 20 mg/L into 13 conical flasks. ese conical flasks were assembled inside a water bath shaker and accurately weighed 0.2 g of CSAC was added into each flask. e speed and temperature of the water bath shaker were fixed at 150 rpm and 30°C, respectively.

Equilibrium Study.
e equilibrium study was conducted to understand the effect of different initial concentrations and contact time on the adsorption uptakes and percentage removal of DDT. 200 mL of this adsorbate at initial concentrations of 5, 10, 15, and 20 mg/L were prepared in an Erlenmeyer flask. en, 0.2 g of CSAC was added to each of these flasks. After that, these Erlenmeyer flasks were loaded inside a water bath shaker for the adsorption process to take place for 24 h. e speed of agitation was fixed at 150 rpm and the temperature of the water bath shaker was set at 30°C. DDT solution was altered to have pH 7 using 0.1 M NaOH.
is pH was chosen to avoid the existence of excess H + or OH − ions in adsorbate solution from inducing the surface area of CSAC, thus affecting its adsorption capacity. is research was interested to verify the potential of CSAC's adsorption capacity at a neutral state.
e following equations were utilized to determine adsorption uptakes and percentage removal of adsorbates, respectively: where q e is the amount of adsorbate adsorbed by an adsorbent at equilibrium (mg/g), C o is the initial concentration of adsorbate solution (mg/L), C e is the concentration of adsorbate solution at equilibrium (mg/L), V is the volume of solution (mL), and M is the mass of adsorbent used (g). e study of adsorption isotherm was carried out by fitting the experimental equilibrium data onto three isotherm models namely Langmuir, Freundlich, and Temkin. e suitability of the isotherm equations in fitting the equilibrium data was evaluated by making a comparison between the correlation coefficients, R 2 value. e model which has a better agreement with the adsorption equilibrium data has an R 2 value approaching unity, indicating that the model was fitted well. ese isotherm equations are as follows: Langmuir [31] equation is as follows: Freundlich [32] equation is as follows: Temkin [33] equation is as follows: Here, Q m is maximum adsorption capacity; K L is the constant of Langmuir; K F and n F are constants of Freundlich; B and A are constants of Temkin, R is the universal gas constant, and T is the temperature.

Kinetic Study.
e method of evaluation of batch kinetic studies was identical to the batch equilibrium experiments. e aqueous adsorbate samples of each respective flask were withdrawn at predetermined time intervals ranging from 15 to 180 min. Adsorbate solutions with four different initial concentrations of 5, 10, 15, and 20 mg/L were used. CSAC's mass, the volume of solution, the temperature of the solution, and the agitation speed of the water bath shaker were International Journal of Chemical Engineering set to be 0.2 g, 200 mL, 30°C, and 150 rpm, respectively. Kinetic models of pseudo-first-order and pseudo-secondorder were used to fit the kinetic data and their equations are given as follows.
Pseudo-first-order (PFO) [34] is as follows: Pseudo-second-order (PSO) [35] is as follows: Besides comparing the correlation factor R 2 to find the best model that fits kinetics data, the normalized standard deviation was used too. Normalized standard deviation measured the variance between experimental data and data obtained using the kinetics model equation. e model that fitted the kinetics data the best yielded a low value of normalized standard deviation. e equation used to find normalized standard deviation is as follows: where q t,exp is the measured amount of adsorbate adsorbed at the time, q t,cal is the calculated amount of adsorbate adsorbed at time t, and n is the number of data points.

Regeneration Study.
Regeneration of CSAC was done by reactivating the saturated CSAC via microwave irradiation technique at 616 Watt for 9 minutes under the flow of CO 2 gas at 150 cm 3 /min. Once reactivated, the regenerated CSAC (CSAC n ) was weighted and tested in adsorption studies. is regeneration process was repeated until 5 regeneration cycles. e formula used to calculate the weight loss percentage of CSAC n is as follows: where W CSAC is the weight of saturated CSAC (n � 0), W CSACn is the weight of regenerated CSAC at n times, and n is the number of the regeneration cycle. e adsorption test on adsorbates using CSAC n was carried out at a temperature of 30°C, pH 7 of adsorbate solution, adsorbate concentration of 10 mg/L, and dosage of 0.2 g of CSAC n per 200 ml of solution volume.

Characteristics of CSAC.
e CSAC was found to pose high BET surface area and total pore volume which were 625.61 m 2 /g and 0.42 cm 3 /g, respectively. According to Yusop et al. [15], the gasification effect of CO 2 gas onto coconut shell was responsible for creating pores network. ese gas molecules penetrate deep into the interior surface of the coconut shell creating more pores. e effectiveness of the microwave irradiation technique was proven when the surface area, as well as total pore volume, was found to rise due to the removal of water and volatile matter from the coconut shell. When these components evaporate and leave the sample, vacant spaces associated with the pores network were developed. e average pore diameter for CSAC was 4.55 nm, thus confirming that all CSAC mainly contain mesoporous structure. Further verification on the type of pores was made in terms of N 2 adsorption-desorption isotherms as shown in Figure 1. Based on this figure, the adsorption-desorption curve for precursor was found to follow isotherm type I which confirmed the existence of micropores on the precursor. On contrary, the N 2 adsorption-desorption curve for CSAC was observed to be similar to isotherm type IV which can be identified from the hysteresis loop corresponding to the adsorption of adsorbate on mesopores [15]. e SEM image of the coconut shell and CSAC are shown in Figure 2. It can be observed that the surface of the coconut shell was rough and uneven whereas CSAC was filled with cavities distributed all over the surface. ese cavities are the one referred to as the pores which play a major role as an active site to adsorb adsorbate molecules. Carbonization and activation processes succeeded in creating pores in CSAC. ese pores were formed from the vacant spaces previously occupied by moisture and volatile matter components. Due to the inability of these components to withstand the heat treatment, they evaporated and left the sample [14].
e elemental spectrum and quantitative results for CSAC are shown in Figures 3 and 4, respectively. ese results were obtained using Energy Dispersive X-Ray Analysis (EDX). Based on both figures, it was found that the carbon atom appears in CSAC at the highest atomic composition and weight percentage of 87.15% and 81.75%, respectively. Other elements such as oxygen, aluminum, silicon, sulfur, and iron existed in CSAC in less than 13.85% and 18.25% in terms of atomic composition and weight percentage, respectively. High composition of carbon atoms in CSAC was desired as they made up the matrix in CSAC. e existence of a low percentage of inorganic elements in CSAC was an indication that coconut shell is a good precursor for activated carbon production in the first place.
e existence of polar compounds on the surface of an adsorbent very much depends on the nature of the precursor used and the method of activation employed. To verify these polar compounds, FTIR analysis was conducted, and its spectrum is given in Figure 5. e summary of bandwidth peaks together with their corresponding compounds is given in Table 2. It was revealed that the surface of CSAC was packed with a variety of polar compounds such as alcohol, nitrile, alkene, alkyne, aldehyde, and carboxylic which correspond to functional groups of O-H, C-N, C�C, C≡C, C-O, and COOH, respectively. ese functional groups attract charged adsorbates, thus increasing the adsorption capacity of CSAC. For further confirmation, zeta potential distribution is given in Figure 6. e zeta potential reading on CSAC's surface was found to be -21 mv. is indicated the surface of CSAC was negatively charged in nature and 4 International Journal of Chemical Engineering CSAC has a negative surface charge (more OH − available) which contributed to the stability of the sample. A similar result was found in the research conducted by Yusop et al. [15] where the zeta potential for acacia wood-based AC was found to be negative as well.

Regression Model Development.
e complete matrix of experimental design in preparing CSAC is shown in Table 3. e software had suggested a quadratic model suit CSAC's yield, Y 2 : Figures 7(a) and 7(b) present the predicted versus actual plots for DDT removal and CSAC's yield, respectively. ese plots were validated by using three parameters namely correlation coefficient, R 2 , standard deviation (SD), and last but not least, adequate precision (AP). Equations (11) and (12) produce satisfactory high R 2 values of 0.9855 and 0.8786, respectively, which reflected 98.55% and 87.86% of the total variation in the responses of DDT removal and CSAC's yield, respectively, coming from the variables studied. Moreover, low SD values were obtained for equations (11) and (12) of 1.57 and 3.89, respectively, which confirmed that only a small deviation of predicted data from actual data has occurred. In terms of AP, equations (11) and (12) generated 31.53 and 10.93, respectively. AP measured signal to noise ratio. Since these values were greater than 4, then these models were adequate to navigate the design space.

Analysis of Variance (ANOVA).
Analysis of variance (ANOVA) is useful to help us understand the experimental data better. If the value produced by ANOVA for Prob > F and F value are less than 0.05 and high, respectively, it indicates that the term model is significant to the response and the result is not random [36,37]. e results of ANOVA for DDT removal and CSAC's yield are shown in Table 4, respectively. e models of these responses were both significant due to Prob > F value for DDT removal and CSAC's yield were <0.0001 and 0.0042, respectively. Lack of fit was observed to be insignificant for both responses studied, thus concluding that variables used had a notable effect on the responses and the models fitted the experimental data nicely [20].
Based on Table 4, the terms of X 1 (radiation power), X 2 (radiation time), and X 1 2 (quadratic effect of radiation power) were found to be significant for DDT removal response whereas other terms not mentioned were not significant. F values obtained for radiation power and radiation time were 399.51 and 38.97, respectively, thus signifying that radiation power affects DDT removal way, superior compared to radiation time. Based on Table 4, significant terms for CSAC's yield response were found to be X 1 (radiation power), X 2 (radiation time), X 1 2 (quadratic effect of radiation power), and X 2 2 (quadratic effect of radiation time), while other terms not mentioned were insignificant. F-value was found to be 18.53 and 6.69 for radiation power and radiation time, respectively. is implied that radiation power caused a greater impact on CSAC's yield response compared to radiation time.

ree-Dimensional (3D) Response Surface of CSAC.
e pattern of variables in affecting the responses can be recognized better by observing the three-dimensional (3D) response surface. e 3D response surface plot for DDT    Figure 8(a), DDT removal was at the lowest point when both radiation power and radiation time were at the lowest values within the studied range. At low radiation power (<490 W), increasing the radiation time had caused no significant change in DDT removal. At low radiation power, not enough energy was created to change the volatile matter from solid to gas form and thus was unable to eliminate them to create more pores. erefore, adding more radiation time would not be helpful to create pores on CSAC as well. As the result, no significant change in the adsorption capacity of DDT was observed. However, at radiation power above 490 W, an increase in radiation time had caused a great increase in DDT removal. At high radiation power, an aggressive cracking reaction took place that enhanced the removal of volatile matter from the sample, creating more pores. e gasification effect of CO 2 became more combative at higher temperatures and bombarded the external and internal surface of the sample, developing more pores which directly contributed to the higher adsorption capacity of DDT. e highest DDT removal was obtained when both radiation power and radiation time were at the maximum values within the studied range.
Based on Figure 8(b), both radiation power and radiation time were observed to pose a negative impact on CSAC's yield. When radiation power was at the lowest value within the studied range, CSAC's yield was found to be at the maximum value. As radiation power increased, CSAC's yield reduced significantly. Similarly, increasing radiation time caused CSAC's yield to decrease as well. At high radiation power, an aggressive volatilization process occurred which led to a reduction in CSAC's weight. According to Yusop et al. [15], an increase in radiation time permitted the volatilization process to be elongated, therefore decreasing CSAC's yield even more. At the highest values of radiation power and radiation time within the studied range, the lowest CSAC yield was found to exist. A similar trend was found in the study of removing cationic dye by acacia woodbased AC where the maximum level of radiation power and radiation time produced a minimum level of AC's yield [15].

Optimization of CSAC' s Preparation Variables.
Radiation power and radiation time were known to pose a positive effect on adsorption capacity and a negative effect on AC's yield. Due to this contradicted effect, RSM based on CCD was exploited in this research to search for optimum values of DDT removal and CSAC's yield. In doing so, variables were set to be in the range while responses were set to be maximum. Table 5 shows the validation model for CSAC's preparation. It was found that optimum radiation power and radiation time were 502 W and 6 min, which resulted in 84.83% of DDT removal and 37.91% of CSAC's yield. e excellence of the models developed in this study to predict the responses was proven by the small error percentage obtained of 2.79% and 2.11% for DDT removal and CSAC's yield, respectively.

Equilibrium Studies.
e plot of DDT uptakes and DDT percentage removal by CSAC versus time at different initial concentrations are given in Figures 9 and 10, respectively.
It was observed that DDT uptakes and percentage removal increased with time until a constant value was reached.
is constant value indicated a saturation point where CSAC had reached its limit in adsorbing DDT. At the beginning of the adsorption process, CSAC had plenty of active sites ready to be occupied by the DDT's molecules. After sometimes, the number of active sites available on CSAC decreased and repulsion between DDT's molecules in International Journal of Chemical Engineering the solid phase and bulk phase started to occur and get stronger [38]. In the end, an equilibrium state was achieved where the rate of adsorption and rate of desorption were equal [39].
As the initial concentration increased from 5 to 30 mg/L, adsorption uptakes of DDT increased from 4.32 to 15.32 mg/ g. is phenomenon can be explained by the greater mass transfer driving force developed at a higher initial concentration to overcome mass transfer resistance between adsorbates in the bulk phase and adsorbates in the solid phase, thus resulted in higher adsorbate uptakes [40]. On contrary, as the initial concentration of DDT increased, the percentage removal of DDT was noticed to decrease from 86.44 to 49.33%. Low percentage removal at higher initial concentrations occurred because the ratio of an initial number of adsorbates' molecules to the available surface area was high, making the active sites to be saturated easily [41].

Isotherm Study.
ree adsorption isotherms of Langmuir, Freundlich, and Temkin were used in this study. e parameters and constants generated from these isotherms can provide information comprised of adsorbates molecules distribution on the surface of adsorbents at equilibrium [42] and adsorption capacity of adsorbents [43]. e plots of linearized equations for Langmuir, Freundlich, and Temkin for DDTuptakes by CSAC are given in Figure 11. Parameters of isotherms used in this study are summarized in Table 6. e correlation coefficient R 2 was evaluated to determine which isotherm model suited the DDT-CSAC adsorption system the best. It was found that this adsorption system was best described by Langmuir isotherm due to the high R 2 obtained of 0.9995. Langmuir isotherm signified that adsorption of DDT onto CSAC formed a monolayer coverage with maximum Langmuir monolayer adsorption capacity, and Q m was found to be 14.51 mg/g. e adsorption capacity of DDT obtained in this study was compared with other studies and is summarized in Table 7. One important parameter that can be evaluated from the Freundlich isotherm is the heterogeneity factor, n F . Since the n F value of this adsorption system was between 1 and 10, it signified that this adsorption process was favorable.

Kinetic Study.
Two kinetics models namely pseudo-firstorder (PFO) and pseudo-second-order (PSO) were employed in this study to give better insight into the kinetic behaviour of the adsorption systems studied. e important findings in kinetics studies included the determination of the kinetic rate constant and the type of adsorption associated with the rate-limiting step, which is either physisorption or chemisorption. e linearized plots of PFO and PSO for DDT uptakes by CSAC are given in Figures 12(a) and 12(b), respectively. Table 8 shows the kinetic parameters for the DDT-CSAC adsorption system.
PSO was found to fit the kinetic data the best for the DDT-CSAC adsorption system due to high R 2 and relatively low error percentages of >0.95 and <11.90%, respectively. erefore, the rate-limiting step for this adsorption system may be contributed by chemisorption. A low error percentage was desired because it signified that the kinetic model succeeded in predicting the adsorption capacity of adsorbates at equilibrium. e value of k 2 showed a trend where this value decreased when the initial concentration of DDT increased. At higher concentrations, the ratio of      adsorbate to the available surface area was high, resulting in a slower adsorption process and lower rate constant [49].

Regeneration Study.
Regeneration study is vital in promoting sustainability and reducing the cost of producing new CSAC. However, any AC can only bear to be regenerated several times only due to the significant loss in weight percentage and adsorption performance. Figure 13 shows the regeneration plot for DDT-CSAC n studied.
Based on the regeneration plot, it was revealed that both weights of CSAC n and the adsorption efficiency had dropped on every regeneration cycle. To be exact, the weight loss percentage of CSAC n had occurred from 100% to 57% after 5 regeneration cycles. Similarly, the adsorption efficiency of CSAC n in removing DDT had decreased from 100% to 83% after 5 regeneration cycles. e reduction in weight and adsorption efficiency can be explained by the ruptured carbon matrix that made up CSAC's structure after it was reactivated using the microwave irradiation technique. is   Adsorbate initial concentration (mg/L) q e , exp (mg/g) Pseudo-first-order Pseudo-second-order q e , cal (mg/g) k 1 (s −1 ) R 2 ∆q t (%) q e , cal (mg/g) k 2 (L/mol.s) R 2 ∆q t (%) 5 4 leads to the damaged of pores, thus reducing the number of active sites for the adsorption process to take place. For the economic reason, it is best to stop the regeneration cycle after 4 times only because, at the 5 th regeneration cycle, the weight of CSAC n had dropped almost half than the original weight and became less efficient.

Conclusions
Coconut-shell-based AC (CSAC) was successfully synthesized with the aid of microwave irradiation technique together with CO 2 gasification. CSAC showed moderately high BET surface and pore volume of 625.61 m 2 /g and 0.42 cm 3 /g, respectively. e average pore diameter for CSAC was found to be 4.55 nm which lies in the mesopores region. N 2 adsorption-desorption curves on CSAC followed isotherm type IV which further confirmed the domination of mesopores type of pores on CSAC. e elemental spectrum showed that 87.15% of CSAC has consisted of the carbon atom, which made up the matrix. A high percentage of carbon proved that coconut shell is the best choice of precursor in the first place. FTIR spectrum confirmed the existence of many polar groups on CSAC's surface such as alcohol (O-H), nitrile (C-N), alkene (C�C), alkyne (C≡C), aldehyde (C�O), and carboxylic acid (COOH). In nature, CSAC's surface was negatively charged due to the zeta potential value of −21 mV. Optimization study revealed that the optimum preparation conditions of CSAC were 502 W and 6 min for radiation power and radiation time, respectively, which resulted in 84.83% of DDT removal and 37.91% of CSAC's yield. A small error percentage of 2.79% and 2.11% for responses of radiation power and radiation time, respectively, signified the success of the models developed to predict actual data. An equilibrium study divulged that the adsorption uptakes of DDT increased from 4.32 to 15.32 mg/g as the initial concentration increased from 5 to 30 mg/L. Conversely, DDT percentage removal dropped from 86.44 to 49.33% as the initial concentration increased from 5 to 30 mg/L. DDT-CSAC adsorption system followed Langmuir isotherm with monolayer adsorption capacity, Q m of 14.51 mg/g. is adsorption system was favorable due to the fact that the n F parameter from Freundlich isotherm was found to be 2.71. In terms of kinetic, the adsorption of DDT onto CSAC was best described by PSO which signified the role of chemisorption in the adsorption process. As initial concentration increased from 5 to 30 mg/L, the rate constant k 2 decreased from 0.91 to 0.13 L/mol.s due to a slower adsorption process at higher initial concentration. Regeneration study divulged that both adsorption performance and CSAC's weight decreased from 100 to 83% and 100 to 57%, respectively, after 5 regeneration cycles.

Data Availability
Data are available upon request to the corresponding author via e-mail.

Conflicts of Interest
e authors declare that they have no conflicts of interest.