Comparative and Equilibrium Studies on Anionic and Cationic Dyes Removal by Nano-Alumina-Doped Catechol Formaldehyde Composite

Department of Industrial Biotechnology, Government College of Technology, Coimbatore 641013, TN, India Department of Chemical Engineering, School of Mechanical, Chemical and Materials Engineering, Adama Science and Technology University, Adama 1888, Ethiopia Laboratory for Bioremediation Research, Unit Operations Laboratory, Department of Biotechnology, Kumaraguru College of Technology, Coimbatore, TN, India Department of Petrochemical Engineering, JCT College of Engineering and Technology, Coimbatore, TN, India Department of Chemistry, College of Science, King Saud University, Riyadh, Saudi Arabia


Introduction
Dyes are color-forming complex compounds and naturally get adsorbed over the surface of the substrate. Because of this property, it has majorly been used for various industrial applications such as textiles, cosmetics, pulp, and paper, and so on [1][2][3][4]. Generally, the dyes are classified into two main groups, namely natural dyes and synthetic dyes. Anionic and cationic dyes come under the category of synthetic dyes, and cationic dyes are significantly more harmful than the other one [5,6]. It is estimated that the amount of dyes used all over the world to be in the range of 10,000 tons per year [7]. Owing to the increase in population, the usage of dyes in the industries has also been elevated.
Even though industries have many advanced eco-friendly technologies and recycling techniques for treating wastewater, the entire dyes present in the sewer could not entirely be eliminated. It is well documented that CR is a highly watersoluble dye and a significant pollutant in the wastewater draining from the textile, pulp and paper, printing, and dyeing industries [8]. SF is a basic azo dye and water-soluble synthetic dye. It has majorly been used in the dyeing of leather, fibers, cotton, wool, paper, and silk. Because of its over usage as a colorant in many industries, it acts as a model compound for dyes. ese widely used dyes are major hazardous to the environment and also cause severe illnesses such as skin allergies, tumor, and mutation to humans [9,10]. ese dyes are nonbiodegradable, and thus, typical conventional practices are not sufficient to eliminate them. As a result, various physicochemical approaches were developed for taking them away from wastewater. But neither of the techniques was fruitful in providing complete removal of dyes in wastewater [11,12]. As the adsorption technique has high-quality treatment processes, it was favored for the expulsion of toxins, for example, dyes. Also, this technique is most desirable for dye removal because of its smooth operation, simpler design setup [13][14][15][16][17][18][19].
is procedure, for the most part, comprises two principle segments viz., adsorbent and adsorbate. Adsorbates are referred to as dyes in the fluid, while adsorbents are the substances added to the dye solution to capture the coloring complexes [20,21]. Some of the research outcomes revealed that the production of adsorbents from different low-cost materials such as clays, agricultural waste (rice husk, maize cob, and coconut shell), siliceous materials (perlite, silica beads, and alunite), zeolites, metal oxides (iron and alumina), and others (chitosan, starch, and cotton as biosorbents) is making this process inexpensive [15,22]. Among them, the polymer composites have majorly been preferred and considered as adsorbents to remove the synthetic dyes from the sewer [23][24][25][26][27]. Since it is more effective in the process, thereby, it could contribute to resolving water pollution problems [28].
Although several studies have been reported on the polymeric composite adsorbents for separating the dyes from the wastewater, doping of any of the adsorbent material in a polymeric matrix followed by carbonization and activation makes polymeric composite adsorbents [29][30][31]. At this stage, there is still a need of more investigations on polymeric composite adsorbents on dye removal to make this process more effective and commercial. So far, no study has been carried out to remove the commercial dyes, namely CR and SF, in the wastewater using Alumina Polymeric Composite (APC). Hence, the present study was aimed to prepare alumina nanoparticle adsorbent doped with catechol formaldehyde resin and used as an adsorbent to check its feasibility in the dye removal. is polymeric composite adsorbent was prepared by the suspension polymerization technique [32]. CR, an anionic dye and SF, a cationic dye, were selected to evaluate the adsorption efficiency of prepared alumina polymeric matrix composite in the aqueous solutions [33][34][35][36]. e equilibrium data obtained were examined using different kinetic and isotherm models to understand the adsorption mechanism.

APC Preparation.
A sterile 250 mL beaker contains catechol (50 g) with few drops of water was heated at 150°C till the catechol switched over to the molten state. To that, 63 mL of formaldehyde solvent (37%), 1.5 mL of triethylamine and 3.5 g of hexamine were added and continuously stirred for 30 min for proper mixing. In this reaction, triethylamine acts as a catalyst, while hexamine acts as a cross-linking agent among the catechol and formaldehyde. Subsequently, the reaction mixture was heated at 31°C for 40 min until the solution turned into the whitish-yellow color emulsion. A 3 g of polyvinyl alcohol (PVA), a stabilizing agent, and 0.5 g of aluminum oxide were added to the whitish-yellow color emulsion within 15 min and continuously heated until it turns into a crystalline state. en, the crystals were cooled by keeping them for 8 h at room temperature. e prepared crystal was washed twice with deionized water, acetone, and ethanol separately and placed in a hot air oven to remove moisture content. e dried crystals (i.e., APC) were made into powdered form with uniform particle size and utilized as an adsorbent for further experiments. e synthesized APC was characterized using particle size analyzer, zeta potential, BET (Brunauer-Emmett-Teller) analysis, FTIR (Fourier transform infrared spectroscopy), and FESEM-EDAX (field emission scanning electron microscopy with energy dispersive X-ray spectroscopy).

Batch Experiment.
e pH of working dye solutions of CR and SF dyes were adjusted into pH 2 and pH 10, respectively, by adding 0.5 M HCL and 0.5 M NaOH. About 0.1 g of APC was added into 25 mL of each dye solution, the flask was covered with coil and kept in an orbital shaker at 200 rpm for different time intervals. After the desired time was attained, the mixture of dye solution with APC was filtered and the optical density of filtrate was examined by using UV-Spectrometer (Shimadzu UV-vis 2550, Japan) to determine the adsorption efficiency, i.e., the concentration of solution after adsorption. A similar procedure was continued to evaluate the effects of various experimental parameters such as initial dye concentration, pH of the dye solutions, process temperature, and contact time for the different regular intervals. e removal percentage of dyes calculated using the following equation: where C i and C 0 (mg l −1 ) are initial and final concentrations of the dyes in the aqueous solution. e dye adsorption capacity q t (mg/g) at any time t, was determined as follows: where C t (mg/L) is the concentration of dye at any time t, V (L) is the volume of dye solution, and M (g) is the amount of APC. e exhausted APC was rejuvenated using acetone, hot water, dilute HCl, dilute NaOH solution, and dilute NaCl solution in order to find a suitable regenerating solvent.

Results and Discussion
3.1. Characterization of the Adsorbent. e particle size of synthesized alumina doped polymeric composites was determined after the carbonization and activation for different systematic time intervals (60, 90, and 120 min) at 400°C. e measured particle size for 60, 90, and 120 min carbonized material was found to be 651.4, 525.5, and 503.7 nm, respectively.
e results showed that 120 min carbonized material produced small-sized particles when compared to short-time heat exposed materials. e observed effects on the variation of particle sizes were similar to the study outcomes reported elsewhere [37]. e particle size distribution of APC after carbonization at 400°C for 120 min analyzed by a particle size analyzer is represented in Figure 1(a). Further experiments in this study were carried out with the materials carbonized at 400°C for 120 min exposure time. Figure 1(b) impersonates the values of zeta potential, from which the surface charge of the APC is determined. Up to pH 6.5, the APC zeta potential value diminished precisely. en the value continually decreased for the increase in pH and after the pH value reached 9.0, the zeta potential value decreased rapidly. From these results, it was decided that the isoelectric point of the APC is 6.0. is depicted that the layer of the adsorbent charged negatively and it expedited the positive (cationic) species. Similarly, the solution pH value exceeds 6.0, then the surface layer of the adsorbent positively charged and it expedited the negative (anionic) species. is explained the effective adsorption of anionic dye CR in a medium that has acidic nature, whereas the cationic dye SF showed efficient adsorption in a medium that has basic nature. e BET analysis is mostly used to determine the definitive exterior area, from which the size of the pores can also be estimated. is data is also very useful to anticipate the dissolution rate since the definitive exterior area is proportional to the dissolution rate. From the BET analysis, the following information was obtained: the initial pore volume (0.947 cm 3 /g), average pore diameter (2.76 nm), BET surface area (2.781 m 2 /g), and monolayer volume (0.2434 cm 3 /g). e FTIR analysis is an important technique that gives the information on functional groups of various compounds and helps to identify the chemical structural changes of polymeric, organic, and inorganic materials. e response of functional groups to IR rays may fluctuate over a wide range, depending on the interaction of atoms within the molecule. Hence, the infrared light range 400-4000 cm −1 was utilized to examine the test samples and look out the chemical properties in the FTIR investigation. e observed FTIR spectra of the composite before and after the adsorption of two different dyes are illustrated in Figure 2. It can be seen from Figure 2(a) that adsorption bands between the range 3500 to 4000 cm −1 for the APC before adsorption indicated the presence of many aromatic groups clustered to form the polymeric matrix. In the same image, it can be observed that the peak around the 500 cm −1 region showed the presence of alumina in the APC. e broad FTIR peak at 3500 cm −1 range represents O-H stretching; the peak at 3685 cm −1 indicates the presence of phenolic O-H group in the composite before adsorption. e medium broad band observed at the range 600-800 cm −1 of spectra of APC after adsorption was due to the frequency of azo group, amine group in CR dye and C-S stretching, and methyl group in SF dye.
Similar results were observed on the adsorption study of cationic and anionic dyes on polymer-modified yeast adsorbents [38]. e adsorption peak at 1652 cm −1 range is attributed to the stretching vibration of C�O. e FESEM is used to characterize the surface morphology of APC before and after the adsorption dyes, and the observed results are shown in Figures 3(a)-3(c). e outcomes of FESEM analysis revealed that tested samples (APC) were cylindrical rod-shaped with a size range of 500-800 nm. As depicted in Figure 3(a), the FESEM image of APC illustrated that pores were formed well on the matrix with alumina incorporated polymeric materials. It also confirmed that alumina was well embedded with the polymeric matrix and homogeneously spread over the porous surface of the catechol and formaldehyde matrix cross-linked by hexamine. Similar observations were also documented in the analysis of magnetic oxide embedded bentonite clay for Cr (III) adsorption [39]. e well-impregnated and distributed small-sized alumina particles on the polymer matrix could make a considerable increase in the surface area of APC. It would be an indicative measure of a suitable adsorbent for adsorbing more dyes in the process. e adsorption of dyes created distinct changes in the physical structure of the materials taken. e FESEM images after dye adsorption indicated that the nonporous structure was due to the presence of dye constituents in the matrix of APC. It was evident that the chosen dyes adsorbed well on the porous surface of prepared APC. e chemical elemental composition of APC was analyzed using Energy Dispersive Analysis X-Ray (EDAX). e EDAX spectra of composite confirmed the presence of Al, C, and O elements in the composite. It is also estimated that the composition of carbon (72%) was very high, and the oxygen (26%) and alumina (12%) were in the ratio of 2 : 1, respectively.

Effect of pH on Adsorption.
Determination of the impact of pH is essential in the adsorption experiments. e adsorption of CR and SF dyes onto APC was investigated for different pH from 2 to 11. e observed results are illustrated in Figure 4(a). e removal percentage of CR dye solution was plotted against the pH at 25 mL of 30 mg/L initial dye solution, 0.1 g APC dose, and 55°C for prefixed process time. As represented in Figure 4(a), the removal percentage of CR solution reduced from 98 to 36.8% when the solution pH was changed from 2 to 4. At the acidic range, the percentage of dye removal for CR was higher initially and suddenly decreased with an increase in pH, mostly in the first region. From this study, the optimum pH was determined as 2 at which the maximum 98% removal of CR dye was observed. With decreasing pH, weak base groups were protonated and acquired a net positive charge on the APC surface. is brought out an electrostatic attraction between the surface of the APC and CR. As a result, a high removal percentage was observed.
SF has a pKa value of 6.4 and a pH 10. e SF removal percentage was witnessed in the basic pH range, whereas with a gradual decrease in pH, it showed an indicative Journal of Chemistry 3 reduction in the dye removal. e percentage removal of dye ranges from 35 to 64% removal when pH varied from 3 to 11. e maximum removal of color was attained at pH 10.0, and the removal percentage of SF at this optimum pH was 64%. At pH 10, further investigation was carried out with a low pka value at 55°C. As SF is a basic dye, a strong electrostatic repulsion exists between the positively charged ions present in the SF solution and   Journal of Chemistry the positively charged APC surface due to the protonation of the functional groups, which resulted in low removal percentage. Also, with an increase in pH of the SF solution, a significant rate of dye removal was noted, as represented in Figure 4(a). At high pH, consecutive deprotonation of the positively charged groups present on the surface of APC existed. It led to the strong electrostatic desirability between SF and APC.

Effect of Temperature on Adsorption.
At four different temperatures (25, 35, 45, and 55°C), the experiments were carried out for adsorption of CR and SF onto the APC material. Figure 4(b) represents that increase in temperature resulted in the increased percentage of dye removal. It denoted that high temperature favored the CR and SF removal from aqueous solution. e solubility of dyes decreased when the temperature increased and hence, it led to a high adsorption rate-a similar result for the adsorption of dyes reported in the literature [5]. Due to the rise in the mobility of the dye molecules at high temperatures, there was an increase in dye adsorption. erefore, the adsorptive uptake of CR and SF increased with an increase in temperature could partially be attributed to chemisorption.

Effect of Initial Dye Concentrations and Contact Time.
e investigation about the influence of different initial dye concentrations of CR and SF by APC is represented in Figures 4(c) and 4(d). e active sites of the adsorbent were surrounded by much more CR and SF ions when the concentration of CR or SF solution was higher. e efficiency of the adsorption phenomenon was higher in CR than SF. e removal percentage was higher for low dye concentration of 30 ppm and 10 ppm for CR and SF, respectively. e value of q e increased when the initial CR and SF dye concentrations were increased. e removal percentage was improved with contact time and became constant at a particular time. So the value of q em was raised with the augmentation of initial CR and SF dye concentrations. Otherwise, it could be seen that initial dye concentration increased when the percentage removal of dye decreased. At the minimum dye concentrations, entire dye molecules present in the reaction mixture interacted well to the binding sites of APC, enabling about 98% for CR adsorption and 64% for SF. However, all adsorbents were saturated at an absolute concentration and had a limited number of binding sites.
ere were more dye molecules persisting unabsorbed in the solution at higher concentrations. It might be a reason that the saturation of binding sites resulted in decreased adsorption efficiency. A similar outcome was observed for adsorption of CR and SF on alumina-nickel composites [40].

Effect of Adsorbent Dosage.
e adsorbent dose is an essential parameter for the examination of adsorption studies, which determined the percentage removal of given initial dye concentration. For analyzing the impact of adsorbent dosage on the adsorption of CR and SF dyes, the adsorbent dose was varied from 0.05 to 0.3 g/L at 55°C with optimized pH and time.
e number of dye molecules adsorbed over APC by changing the dosage of APC is illustrated in Figure 4(e). It showed that the adsorption of CR and SF increased as the amount of adsorbent was increased from 0.2 to 0.3 g/L for CR and 0.25 to 0.3 g/L for SF and then maintained constant. is was due to the number of active sites increased on alumina polymer matrix with the increase in the adsorbent dosage to a certain level. erefore, 0.2 g/L and 0.25 g/L of APC for CR and SF dye, respectively, were taken as the optimum adsorbent dose for further experiments.

Adsorption Isotherm Studies
Establishment of equilibrium correlation based on adsorption data is necessary for the optimization and design of adsorption process. To investigate the batch adsorption data Langmuir, Freudlich and Temkin isotherms were employed.

Langmuir Isotherm.
Langmuir isotherm studies say that adsorption proceeds on monolayer surface and energy will be the same on the sites of adsorption. Adsorption isotherm provides valuable information such as equilibrium sorption capacity and certain constants whose values express the surface properties and affinity of the adsorbent. e linear equation of Langmuir isotherm is symbolized as in the following equation [41]: where q m is the maximum monolayer capacity (mg/g); K L is the Langmuir isotherm constant (L/mg). e graph was plotted C e /q e against C e at various temperatures (25,35,45, and 55°C) in Figures 5(a) and 5(b) from which q m and K L values were calculated. From Table 1 for CR dye, q m and K L values increased with an increase in temperature till 45°C and then an insignificant increment was noticed. e estimated correlation coefficients value (R 2 ) ranges from 0.917 to 0.994. For SF dye, the q m value decreased and K L value increased with an increase in temperature, and the R 2 was determined in ranges from 0.890 to 0.932. It was confirmed from the value of R 2 that both adsorption data measured for CR and SF onto APC reasonably fitted with the Langmuir isotherm. A similar isotherm response was found for the adsorption of Pb(II), Zn(II), and Cd(II) on hyacinth weed [42].

Freundlich Isotherm.
Freundlich isotherm studies reveal that the adsorption takes place on the heterogeneous surface and the energy of adsorption will be non-uniform [39]. e linear equation of Freundlich isotherm can be denoted as the following equation [43]: where K f is the Freundlich isotherm constant (mg/g) and n is the adsorption intensity.    APC fitted with the Freundlich isotherm rather than the Langmuir isotherm. e estimated adsorption data of SF onto APC was also fitting good with Freundlich isotherm. Similar isotherm results were also reported in reactive dyes removal using biomaterial-based polymer composites [44].

Temkin Isotherm.
e Temkin equation reveals that the heat of adsorption weakens with the increase in the area of surface coverage. e linear equation for Temkin isotherm can be represented as the following equation: where A T is the Temkin isotherm equilibrium binding constant (L/g), B T is the Temkin isotherm constant, R is the universal gas constant (8.314 J/mol/K), T is the temperature at 298 K, and B is the constant related to the heat of adsorption (J/mol). e graph was plotted between q e against ln C e at different temperatures (25, 35, 45,

Adsorption Kinetics
e uptake of CR and SF onto APC at temperatures extending from 25 to 55°C and its diffusion processes were studied at an initial CR concentration of 30 mg/L and SF concentration of 10 mg/L for the same range of temperature, pH 2 and 10 for CR and SF, respectively. e experimental data was investigated with five kinetic models: pseudo-firstorder, pseudo-second-order, Bhangam kinetic model, intraparticle diffusion, and Elovich model.

Pseudo-First-Order Kinetic Model.
e pseudo-firstorder kinetic model is more suitable for lower concentrations of solute. e pseudo-first-order kinetic model equation is expressed by the following equation [46]: where K 1 is the rate constant of first-order adsorption (min −1 ). e straight-line plot of log (q e − q t ) against t is given in Figures 7(a) and 7(b) which indicates log (q e ) as slope and intercept equal to K 1 /2.303. e amount of solute adsorbed per g of APC at equilibrium (q e ) and the first-order rate constant (K 1 ) could be evaluated from the slope and the intercept and the values are tabulated in Table 2. From the graph, the dye adsorption by APC did not obey the pseudofirst-order kinetics for both CR and SF. Similar outcome was observed in iron-doped phenolic resin-based activated carbon of micro-and nanoparticles for arsenic removal [47].

Pseudo-Second-Order Kinetics.
e pseudo-second-order model developed on the assumption of chemisorption which involves valence and electrostatic forces via sharing of electrons between the dye and the adsorbent. is is given by the following equation [48]: where k 2 is the rate constant. e plot of (t/q t ) versus time gives the plot for the pseudo-second-order model. Table 2 presents the value of k 2 and q e for CR and SF dye adsorption at four different temperatures. From Table 2 and Figures 7(c) and 7(d), the pseudo-second-order equation fitted well with the experimental data, as the correlation coefficient (R 2 ) was close to unity and extremely high R 2 was obtained for both CR and SF adsorption process compared with the first-order equation. As the experimental data fitted well with the pseudo-second-order model, the adsorption process was solely dependent on both APC and dyes concentration. is adsorption mechanism was chemically rate controlled. Similar kinetic results were obtained for basic dyes removal from aqueous solutions onto apricot stone activated carbon [49].

Bhangam Kinetic
Model. Bhangam's model is a pore distribution model that can determine the rate-controlling step in the adsorption process, which is given by the following equation: e plot of log q t versus log t represents the Bhangam kinetic model. e graph was plotted for an initial dye concentration of 30 mg/L and 10 mg/L for CR and SF, respectively, as shown in Figures 8(a) and 8(b). e correlation coefficients (R 2 ) obtained ranged from 0.811 to 0.976 for CR and SF, respectively, as shown in Table 2. Nonlinear curve was obtained for CR but a linear curve resulted in the case of SF adsorption. is indicated that the rate-limiting step was the adsorbate diffusion into pore or matrix for CR. Similar kinetics observed for the adsorption of CR and SF onto kenaf core fiber [46].

Intraparticle Diffusion
Model. Transport of dye molecules from the bulk of the solution into the adsorbent is normally via an intraparticle diffusion, which is regularly the rate-limiting step in the adsorption process. Intraparticle diffusion model, according to which the amount adsorbed at time t, q t , reads as follows: where k p is the intraparticle diffusion rate constant (mg g −1 min 0.5 ), C (mg g −1 ) is a constant related to the thickness 8 Journal of Chemistry     of the boundary layer. e graph plotted between q t versus t 0.5 provided a straight line, as presented in Figures 8(c) and 8(d). From the graph, k p and C was determined from the slope and intercept. Values of C indicated the thickness of the boundary layer; i.e., the larger intercept, the greater the boundary layer effect. e small value of the intraparticle diffusion constant indicated that the boundary layer has a less significant effect on the diffusion and is shown in Table 2.
A similar result was reported for basic dyes adsorption onto activated carbon [50].

Elovich Model.
Elovich equation is also used to describe second-order kinetic assuming that the actual solid adsorbent surfaces are energetically heterogeneous. e Elovich equation is given as follows: is simplified equation (11) is as follows:   q t � β ln(αβ) + β ln tq t .

(11)
Elovich constants α and β were calculated from the plot of q e versus ln (t), as shown in Figures 9(a) and 9(b). e correlation coefficient (R 2 ) ranged from 0.804 to 0.875 for CR and from 0.946 to 0.978 for SF as shown in Table 2. α value increased for both CR and SF as temperature increased. Similar kinetic results were reported for acid dye removal by dead fungal biomass of T. harzianum [51]. is model fitted well for SF adsorption than the CR. It was concluded that SF followed chemisorption as it fitted well with the Elovich model. A similar kinetic result of the adsorption process was reported in the adsorption of dye by chitosan systems [52].

Adsorption ermodynamics.
e process of spontaneity approval is based on the thermodynamic study of the adsorption process. e study of adsorption thermodynamics was used to interpret the adsorption mechanism, either physical or chemical. For the adsorption of CR and SF, the thermodynamic parameters (∆G°, ∆H°, ∆S°) were determined using the Van't Hoff equation. e relationship between the parameters is given as follows: Van't Hoff equation is obtained as follows: where K C is the equilibrium constant (dimensionless). e change in enthalpy (∆H°) and the change in entropy (∆S°) were determined from the slope and intercept of equation (11), respectively. Gibbs energy change was determined directly from equation (10). Table 3 lists the value of thermodynamic parameters for both CR and SF at four different temperatures, respectively. e negative value of ∆G at all experimented temperatures concluded that the adsorption process occurred spontaneously. In contrast, the positive value of ΔH°indicated that the adsorption had occurred in an endothermic manner. As well as the positive value of ΔS°s uggested the arrangement of dye molecules onto APC very well with more randomness as temperature increased from 25 to 55°C. Here, as temperature increased, the equilibrium constant also increased. is proved that the rate of adsorption increased with an increase in temperature. e value of entropy and enthalpy for the adsorption of CR and SF indicated the endothermic nature of the adsorption process. An endothermic reaction is generally associated with chemisorption [53].

Regeneration and Comparison with Other Adsorbents.
e comparison of desorption efficiency is presented in Figure 10. e physical adsorption was not a predominant factor, while sodium hydroxide, which conformed high desorption efficiency 93% for CR and 87% SF representing the chemical binding of dye adsorbent of interface route. Apart from the other solvent such as HCl and NaCl of H + and Cl − was obtained and neutralized in the distilled water, which was approved by the chemisorption of the dye molecules. APC was regenerated after CR and SF dyes adsorption several times and used for readsorption experiments. Regenerated APC was found good at least for 4 cycles (Figure 11). e comparison of adsorption capabilities of various adsorbents for CR and SF dyes is presented in Table 4. It is clear from Table 4 that the prepared APC was moderately good compared with other adsorbents for CR and SF.

Conclusion
e adsorbent Alumina doped synthetic polymeric composite was synthesized by ball milling method. A yield of 81.5% was obtained by this method. Here, it was used to remove synthetic dyes such as CR and SF. Characterizations such as particle size distribution, zeta potential, BET, FTIR, and FESEM with EDAX were performed for the APC composite to study the nature of the synthesized particle. e particle size analysis of the synthetic polymeric composite estimated was about 503.7 nm. FTIR study revealed that the presence of functional groups in the composite before and after adsorption process. FE SEM and EDAX characterization was done, which gave the surface image and the composition of the composite. A comparison of anionic and cationic dye using APC was studied. e effect of parameters for the adsorption process such as the effect of pH, temperature, adsorbent dosage, initial dye concentration, and contact time for CR and SF adsorption were studied. A significant interaction was observed in CR and SF removal with the combination of parameters. e maximum adsorption of CR and SF dyes was obtained with pH 2 and 10, respectively, at the process temperature of 55°C. Several isotherm models were used to fit the experimental data point. e Langmuir isotherm, Freundlich isotherm, and Temkin isotherm were studied. Among them, observed experimental data were well fitted with Freundlich isotherm. It suggests that the mechanism can be a chemical adsorption process onto the surface binding sites of the adsorbent. e kinetic modeling of the CR and SF onto the composite indicates that the adsorption process fits into pseudo-second-order kinetics with a correlation coefficient higher than 0.9. e removal percentage and adsorption capacity of CR was higher than that of cationic dye SF over a wide range of aqueous concentrations by the APC. us, the results suggest that the APC could be a potential adsorbent for the removal of anionic dyes from aqueous solution.

Data Availability
No data were used to support this study.

Conflicts of Interest
e authors declare that there are no conflicts of interest regarding the publication of this paper.

Authors' Contributions
V. Karthik and N. Sivarajasekar were responsible for methodology, project administration, and supervision. P. Selvakumar framed the conceptualization, investigation, and writing of the original draft. P. Megavarshini, N. Brinda, and J. Kiruthika performed the experiment and wrote the original draft. K. Balasubramani involved in methodology, supervision, reviewing, and editing. Tansir Ahamad and Mu. Naushad carried out reviewing and editing.