The State of the Art: Application of Green Technology in Sustainable Pavement

Joint USTB-Virginia Tech Laboratory on Multifunctional Materials, National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083, China Lehigh University, Bethlehem, PA 18015, USA Institute of Highway Engineering, RWTH Aachen University, D52074 Aachen, Germany University of Science and Technology Beijing, Beijing 100083, China National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083, China School of Transportation Science & Engineering, Harbin Institute of Technology, Harbin 150090, China Virginia Tech, Blacksburg, VA 24061, USA


Introduction
With the rapid urbanization, there are increasing movements of human beings and goods with transportation infrastructures.Pavements, for example, have been constructed over billions of miles long worldwide, with more than 4 million miles in the United States (Figure 1(a)).In the meantime, there is an increase in energy consumption, leading to environmental pollution and global warming.In 2016, the annual energy consumption worldwide is over 13,000 Mtoe [1], among which the U.S. alone consumed over 2,456 Mtoe [2]. Figure 1(b) shows the annual energy consumption in the U.S. from 1950 to 2015, demonstrating an increasing trend of energy consumption by different infrastructure sectors.On the contrary, Figure 1(c) presents a general increasing trend of SO 2 emission worldwide from 1850 to 2010.Consequently, a sustainability concern arises.Given the limited supply of traditional energy such as coal, petroleum, and natural gas, how can we satisfy the future human needs, consume energy efficiently, and also preserve the surrounding environment?
In this respect, there have been many studies working on the development of green technologies in order to implement the sustainability concept in pavements.As a part of the global effort, implementations of sustainable pavements have been conducted on developing efficient technology to harvest renewable energy.Typical sources of renewable energies are solar radiations, geothermal heat, and vibrations due to hydro, wind, wave, and mechanical load [6].Pavements are continuously exposed to three of them: solar radiation, geothermal heat, and traffic-induced load, and all of the three energy sources provide a good opportunity to harvest renewable energy from pavements.Traffic-induced vibrations on pavements can be harvested by piezoelectric energy harvesters.Solar radiations and resulting thermal gradients in pavement layers, as well as geothermal heat, can be transformed into useful energies through solar energy harvesting, thermoelectric energy harvesting, geothermal energy harvesting, and composite energy harvesting.
On the contrary, more than 90% of urban roads are covered with impervious surfaces, normally with a wellcompacted (sub-) base layer covered with asphalt/concrete surface layers.e impervious pavement systems lead to the in ltration reduction and enlargement of peak ow, rendering urban ash oods and reduced water to recharge and reuse.Because of all these, impervious pavements have changed the city natural ecology and hydrological characteristics signi cantly [7].In rainy days, accumulated water on the wet pavement surface is a major cause of tra c accidents, leading to signi cant socioeconomic losses.Comparing with the plant-soil system, the impermeable pavement system has lower speci c heat capacity and higher solar absorptivity, which results in a high-temperature urban 2 Advances in Materials Science and Engineering surrounded by the low-temperature suburb, the so-called urban heat island (UHI) e ect [8].To address the wet pavement problem and UHI, countermeasure strategies have been developed around the world.One of the environmental-friendly countermeasures is the permeable pavement system, which is to make urban surfaces more water-permeable and environmental-friendly.Australia has adopted the term "water sensitive urban design" (WSUD) to manage the water balance and maintain the water quality since 1990.In the United States, the strategies of best management practice (BMP) and low-impact development (LID) have been developed for the storm water runo management and sustainable urban construction.Sustainable drainage systems (SuDS) in the United Kingdom consist of technologies to drain storm water/surface water in a manner, which is more sustainable [9].
In the area of green technologies for sustainable pavements, numerous studies have been conducted to critically review the emerging technologies and designs with di erent focuses.Dawson et al. described the advantages and limitations of energy harvesting techniques for pavements, focusing on the designs and construction issues in the collection, storage, and usage of energy [10].Duarte and Ferreira reviewed the energy harvesting technologies for pavement applications, with general discussions on technologies to harvest solar and vehicle-induced energies [6].Wang et al. comprehensively summarized working principles and application methods of energy harvesting techniques in roadways and bridges, with discussions on the emerging research trends and challenges [11].However, none of them provided any descriptions about possible methods to reduce environmental impacts by using the same geomaterials with alternative pavement designs, such as permeable pavements.Conversely, Scholz and Grabowiecki discussed the advantages and disadvantages of di erent permeable pavement systems, without any description of making use of excessive energy from pavements [7].Shi and Lai quantitatively summarized the number and speci c research topic of green and low carbon technology in different countries from 1994 to 2010, without presenting detailed technical designs or addressing limitations for any green technology [12].
is paper complements that work with a critical review about previous e orts of green technology developments for the applications to road pavements, in terms of both energy harvesting technologies and permeable pavement systems.
e rst major contribution of this paper is that green technologies are comprehensively reviewed based on over 100 recent publications, including articles, reports, and book chapters.e second one is that the design of each green technology is reviewed, covering material types, energy conversion e ciencies, advantages and limitations, as well as implementation challenges.It also points out the great bene t of the integrated design by implementing both energy harvesting and permeable pavement in the same pavement structure.is paper serves as a useful starting point to new researchers in this eld, and it also facilitates practitioners to choose the most appropriate technology for their local pavements.e rest of this paper is organized as follows, as shown in Figure 2. First, di erent energy harvesting technologies for pavements are presented, in the aspects of materials, fundamental mechanics, energy e ciency, and advantages and limitations.After that, permeable pavement systems are presented, with discussions of designs, e ciencies, limitations, and the state of practice.Major ndings and future research recommendations are presented at the end of this paper.

Energy Harvesting Technology in Pavement
Figure 2: Outline of this study.

Advances in Materials Science and Engineering
Energy collected from pavements in the form of electricity can either be carried away for powering electric devices of signage and tra c lights, or deicing in cold weather, and monitoring pavement features such as temperature, deection, and tra c.

Piezoelectric Energy Harvesting Technology
2.1.1.Piezoelectric Materials.Piezoelectricity was discovered by Jacques and Pierrer Curie in 1880 [15].e piezoelectric e ect refers to a reversible process of using piezoelectric materials to generate electrical energy in response to applied mechanical stress.e direct piezoelectric e ect represents the generation of electric charge with piezoelectric materials from an applied mechanical loading, whereas the reverse piezoelectric e ect refers to the generation of mechanical strain resulting from an applied electrical force.
e direct piezoelectric e ect is utilized to directly harvest energy from pavements with piezoelectric materials, and the reverse piezoelectric e ect is useful to detect very low-frequency vibrations [16], which will be discussed later.
As shown in Table 1, prevalent piezoelectric materials include inorganic piezoelectric materials, organic piezoelectric materials, and composite piezoelectric materials.Inorganic piezoelectric materials applied in pavements include piezoelectric crystalline and piezoelectric ceramics.Piezoelectric ceramics are usually applied as sensors for pavement monitoring.Due to the fragile nature, piezoelectric ceramic materials are less resistant to the vibration loading at high frequency [17]; the advantages of piezoelectric ceramics are greater physical properties and high electromechanical conversion e ciency.For example, PZT (lead zirconate titanate) is one of the most popular piezoelectric ceramics.Its electromechanical coupling factor is nearly twice as high as that of barium titanate ceramics, and its mechanical properties and temperature stability are signi cantly higher than that of barium titanate ceramics [18].By contrast, piezoelectric crystalline materials are usually obtained from necessary treatments of raw polycrystalline materials through molding, high-temperature sintering, and ne grain random harvesting [18,19].
Organic piezoelectric materials are also known as the piezoelectric polymers.In 1969, it was found that PVDF (polyvinylidene uoride) had strong piezoelectric properties after uniaxial stretching and polarizing at high temperature with strong electric eld.Piezoelectric polymer materials have the characteristics of high elasticity conversion eciency, low density, and low impedance.e materials are usually soft and therefore easy to be made as di erent sizes, which can adapt well to the high-frequency vibration environment [23].PVDF has very stable chemical properties with high toughness.erefore, it is more resistant to fatigue damage compared with piezoelectric ceramics.
Combining the advantages of both inorganic and organic piezoelectric materials, composite piezoelectric materials are composite materials that include piezoelectric ceramics, crystalline, and polymers.Compared with the monophasic piezoelectric materials, composite piezoelectric materials can overcome the limitation of low energy harvesting e ciency.In particular, an obvious advantage of composite piezoelectric materials is great exibility, which is desirable for manufacturing curved transducers [24], which will be further discussed in the following subsection.

Piezoelectric Transducers.
Piezoelectric materials have been applied to produce transducers to detect external mechanical loadings, such as compressive deformations and low-frequency/acceleration motions.E ciency and power density of a piezoelectric energy harvester are capable to harvest the maximum energy at its resonance frequency [26].An energy harvester needs to be designed according to the vibration frequency of targeted motions, such as human motions and travelling vehicles [26,27].Depending on the installation mechanism of piezoelectric materials shown in Figure 4, piezoelectric transducers can be classi ed as cymbal transducers, cantilever transducers, and other transducers.
Table 2 presents the design of an example piezoelectric transducer and electric output.e cymbal transducer is usually adhesive by epoxy resin on both sides of the piezoelectric ceramic.It is wired with conductive epoxy resin that is adhesive on the metal end cap on the edge of a piezoelectric ceramic along the polarization direction.When the upper metal end begins to bear the loading, through the coupling e ect of piezoelectric wafer interface, the radial vibration of a piezoelectric wafer modal superposition occurs, and then, the output alternating voltage is generated.
is type of transducer had the advantage of enhanced horizontal polarization, leading to a greater density of power output.
ere have been many application studies of piezoelectric cymbal transducers in pavements.Lv et al. considered a layered model of di erent thickness and diameter to collect the energy generated on the asphalt [31].e conventional piezoelectric ceramic transducer is composed of PZT ceramic and hardened steel.e mechanism is that through the deformation caused by the vehicle, the impact load directly a ected the PZT ceramic polarization center, and a relative displacement occurs.e positive and negative developed a new type of a bridge transducer based on beryllium design to polarize piezoelectric ceramics along its length with novel electrode designs [28].Xiong and Wang successfully collected the deformation energy of asphalt pavement, which was caused by moving vehicles, to generate electricity with the piezoelectric energy collector in order to power a stop sign.In their design, six PZT piezoelectric ceramic plates were installed in every prototype piezoelectric energy collector, which was eventually installed in the asphalt pavement in a weight station by an interstate highway [40].Cantilever transducers represent transducers with a thin piezoelectric lm attached at the free end of a cantilever beam to harvest energy from vibrations.As expected, the deformation of the piezoelectric plate is increased by adjusting the resonant frequency of the piezoelectric structure.e power output is proportional to the proof mass [27].e cantilever beam structure can generate more power by repeatedly striking and vibrating the piezoelectric cantilever  Advances in Materials Science and Engineering beam, where the vibration energy can be continuously converted into electric energy [37].Since cantilever transducer piezoelectric energy is random and intermit, the circuit in nonworking time still consumes energy, which may cause unnecessary energy loss [36].
Cantilever transducers have been applied to harvest energy from motions of humans and vehicles [15,17,18].Kuang et al.'s cantilever transducer harvested energy from human motions, with the average power output of 5.8 mW, and the dual-piezoelectric chips pulled out by the repulsive magnetic force could produce higher energy output [37].Chen et al. presented a self-powered cantilever transducer for road speed bumps, with the basic idea to detect travelling vehicles by waking up the circuit [36].
e tire pressure of a travelling vehicle can be measured with remote monitoring systems, with the maximum power output achieved with the tire contact patch on the top of the energy harvester [41].
e other transducers, such as piezoelectric crystal pile, cylindrical piezoelectric structure and electromagnetic piezoelectric energy harvesting, have also gotten increasing attention.ere have been composite forms of piezoelectric ceramic strip and steel substrate.Faisal et al. developed a piezoelectric coupling energy collector with piezoelectric films on top of a rectangular steel plate [23].Zhao et al. developed several types of piezoelectric sensor configurations by stacking several prismatic PZT elements in circular, square, or hexagonal shapes, in order to investigate the influence of cross-sectional shape on energy output [35].Papagiannakis et al. developed two piezoelectric prototypes with stacked cylindrical or prismatic piezoelectric elements to harvest the kinetic energy from travelling traffic Note.In the "31 mode," "3" represents the polarization direction of the piezoelectric layer, and "1" represents the stress direction; NA: not available.[46].Energy harvested from the harvesters can be stored in batteries, which can power other electric sensors and tra c and signal lights [13,40].With a large-scale application of piezoelectric technology in pavements and on bridges, it is helpful to reduce the nonrenewable fossil fuel power consumption, which contributes to more resilient and sustainable pavement infrastructures.[10].Figure 5 presents the heating e ect of pavements due to the solar radiation.e horizontal axis represents albedo, which is the proportion of incident energy re ected.e solar energy coe cient increases with the increase of albedo [47].Pavement surfaces are commonly hot in warm weather, leading to the urban heat island e ect and even structural failures.In this respect, collecting solar energy from pavements and removing the excessive heat due to solar radiations could eliminate both urban heat island e ect and structural failure potentials [10].

Solar Energy Harvester.
To harvest solar energy for a su cient period of time during daylight hours, many energy harvesting technologies have been developed.e discovery of high-purity silicon photovoltaic cells accelerates the development of solar energy harvesting. is innovation allows us to create a pavement surface that remains clean and absorbs solar radiations in the meantime.As shown in Figure 6, prevalent methods to harvesting solar energy include installing solar panels along roadways, installing solar panels underneath a transparent top layer as photovoltaic pavements, and pavement solar collectors with embedding pipe systems to extract heat.In Figure 6(a), solar panels are installed along roadways to harvest solar radiations, contributing to reduction in external energy usage and greenhouse gas emissions [49].
is design has been widely utilized in practice for powering tra c lights and signal lights along roadways.Previous research found that photovoltaic technology has the greatest peak productivity than the other green technologies for energy harvesting, but the productivity is limited by illumination conditions [50].
Photovoltaic pavement surfaces consist of a highstrength transparent layer on the top, with solar panels installed underneath.e top layer serves as a water proof layer, which allows sunlight to pass through.e solar panel layer converts solar energy into electric energy.A 100 ft 2 solar walkway at the George Washington University generates the average peak capacity of 400 Watt, which is capable to power 450 LED pathway lights below the panel [51].Fouad et al. evaluated the cost-bene t of photoelectric pavements by considering the environmental, photovoltaic, installation, and cost.rough continuous research, the negative e ects are expected to be eliminated and the performance of photovoltaic conversion is expected to be improved [52].Photovoltaic pavements are made of tempered glass, to be installed on roads, parking lots, and bike lanes, and sometimes solar cells are installed between two Surface temperature (°C) Figure 5: Albedo and surface temperature for di erent types of pavements (based on [10,48]).
Advances in Materials Science and Engineering porous rubber layers [53].Northmore and Tighe studied the performance of a pavement with a transparent surface with an embedded solar cell through a nite element model of various structure designs.ey believed that a solar pavement can be designed to withstand the tra c load [54].Qin et al. established a small-scale pilot project on the use of pavement solar energy with an automatic data-acquisition system and evaluated the e ectiveness of pavement solar systems in energy conversion [55].Despite the aforementioned exploratory studies, photoelectric roads are still not ready for practical applications yet due to high installation costs and concerns about potential short service life.
Pavement solar collectors with the embedding pipe system collect heat due to solar radiations with the pipe system in the asphalt pavement structure and store as electric energy, depicted in Figure 6(c).e design uses similar pipe systems as in the design of geothermal energy harvesting, with the harvested thermal energy generated from solar radiations rather than from a geothermal source.e rst pavement solar collector with embedded pipe systems was implemented by Sedgwick and Patrick with a grid of plastic pipes 20 mm underneath the asphalt surface in a tennis court, demonstrating a relatively constant temperature [60].Wu et al. proposed the use of black asphalt pavements as solar collectors for direct cooling and heating in snow removal in the winter [61].Major problems are to maintain temperature in the pipe system and to eliminate pipe clogging over time.ere are many factors a ecting the heat collecting e ect, including the latitude of pavement, the albedo of the surface layer, the diameter, distance, and burial depth of pips, and the emissivity and thermal conductivity of the surface layer [62].Pavements at a low latitude are usually exposed to greater solar radiations; therefore, the bene t of solar pavements increases with a decrease of latitude [63].On the contrary, albedo has a great in uence on the performance of the solar energy harvester, as the temperature of pavement surface increases with albedo [64].In addition, to maximize the energy harvesting e ciency, the pipe diameter and burial depth need to be carefully selected, with the uid velocity setting in an optimal range [59].It is worth mentioning that solar energy projects along roadways raise some new concerns, such as safety concerns due to the re ection and glint e ects [65].8 Advances in Materials Science and Engineering ermoelectric Pavements.Collecting the heat from pavements is capable to generate electricity and provide heat to the surrounding building and eliminates the UHI effect [63,66].
ermoelectric materials can be used as energy collectors in pavement applications.Table 3 shows three common thermoelectric materials.At present, the most widely used thermoelectric materials are carbon fiberreinforced cement composite materials, cement-based composite materials, pyroelectric materials, and so on.Wei et al. carried out an energy harvesting experiment based on the thermoelectric behavior of carbon fiber-reinforced cement composites (CFRC).
e collected outdoor heat energy was converted into electrical energy [67].Rew et al. studied the effects of powdery carbon-based additives on asphalt composites, including graphite and carbon black.
e electrical conductivity was evaluated by experiments, which provided a basic foundation for the application of carbon-based powder conductive additives to the multifunctional application of asphalt composites [68].
Cement-based materials are based on the carbonate cement, with a variety of ceramic fiber, carbon, wire, or mineral fiber as a reinforcement by adding filler, chemical additives constitute, and composite materials.New cementbased materials have increased the functional conductivity.Ghahari et al. added ZnO nanoparticles in cement paste to improve the thermal properties of cement paste and systematically studied the possibility to harvest heat storage in concrete structure.e thermoelectric properties of ZnOcement composite surface showed its thermal energy recovery potential on concrete structure and pavement [69,72].
Pyroelectric materials are materials that generate electricity at an elevated temperature.In the case of mechanical loading condition, the pyroelectric coefficient of pyroelectric materials is measured as the sum of the primary pyroelectric coefficient at constant strain and the secondary pyroelectric coefficient due to piezoelectric contribution from thermal expansion.Pyroelectric materials can be broadly classified into three categories: single crystals, polycrystalline ceramics, and polymers [73].Bhattacharjee et al. conducted research on the pyroelectric material consisting of lithium tantalate (LiTaO 3 ), ordinary Portland cement, and carbon nanofiber.eir results showed that lithium titanate crystals have excellent thermoelectric properties and are excellent candidates for pyroelectric energy harvesters, to produce electricity for other sensing devices [70].Batra et al. theoretically studied the energy harvesting capacity of existing pyroelectric elements and transducers by capturing thermal energy from pavement heat.With temperature data from the MEPDG climate database, they discovered that the energy collected by thermoelectric power was a viable technique for the automatic power supply of low-power demand devices [74].
e thermoelectric generator (TEG) for waste heat harvesting can also be controlled by thermoelectric effects, also known as Seebeck effects.e energy harvester system with the thermal module device can capture the energy from the pavement temperature gradient according to the Seebeck effect [20].
Commercially, thermoelectric materials have a great energy productivity at the great heat flux condition (over 180 °C) [75].In pavements, the temperature gradient may be lower, resulting in a smaller heat flux.As a result, for wide pavement applications, the thermoelectric energy harvester should be optimized in terms of both material design and device design to yield a better energy conversion efficiency.

Geothermal Pavements.
On the contrary, natural geothermal resources refer to thermal energy-stored underground soils.
e natural geothermal resources are mainly caused by the high-temperature melts in shallow crust and the decay of some radioactive elements.As shown in Figure 7, geothermal energy is collected with pipe networks to generate electricity in many countries, such as Mexico [76] and Turkey [77]; geothermal energy is also applicable to heat pavements for deicing [78].In the pipe networks, fluid operation parameters, such as temperature and flow rate, have a great influence on the thermal exchange [61].
erefore, the pipe networks should be carefully designed, in terms of pipe diameter and installation depth, among others, to achieve the optimal fluid operation parameters and the maximal energy conversion efficiency.
Harvested geothermal energy has many applications, and ore advanced techniques for geothermal energy harvesting are still under development.Geothermal energy harvesting for melting snow begins from 1940s at Oregon in the United States, and its iron piping system failed due to external corrosions and serious leakages after 50 years' service.Later on, plastic pipes are frequently used as the replacement of metal pipes to avoid corrosion.Wang et al. proposed a small-scale geothermal system to melt ice on concrete pavements, and experimental results showed that the melting process of ice and snow consists of a staring period, a linear period, and an accelerated period [78].Zhou et al. verified the applicability for storing thermal energy and deicing in winter [61].Liu et al. analyzed the heat transfer and snow melting of asphalt concrete pavement and paved the pavement with electric heating pipes [79,80].Mauro and Grossman proposed a low-enthalpy geothermal energy harvester.e geothermal temperature gradient was generated by materials with a great thermal conductivity to eliminate annual street temperature fluctuations [81].Low cost and rich raw materials Low thermoelectric performances [71,72] Advances in Materials Science and Engineering Successful applications of geothermal energy harvesting to heat airport pavements demonstrated that geothermal energy harvesting has safety and environmental bene ts, despite a higher initial investment than the traditional snow removal methods [82][83][84][85].Although geothermal energy is an attractive renewable energy source, it may have an inherent limitation of geographically and geologically limited availability.Popular applications are for surface deicing and snow removal in airports, bridges, and sidewalks.

Composite Energy Harvesting
Technology.Some other studies try to incorporate multiple energy harvesting technologies together.Figure 8 depicts three example designs of composite energy harvesters.It is found that piezoelectric materials usually have the thermoelectric e ect.Tao and Hu investigated the electrical response of the PVDF with both mechanical and thermal stimulations, nding that PVDF microsensors are very e ective in energy conversion [86].Meanwhile, several other studies have demonstrated that harvesting energy through the hybrid piezo-pyroelectric e ect from pavements with PVDF is likely to generate a greater electric output compared to only harvesting mechanical energy from the piezoelectric e ect [17,87].However, current research on the hybrid piezoelectric-thermal energy system remains in laboratory tests, seldom applied to pavement structures in eld applications yet.
Similarly, electric power output can also be signi cantly increased by combining solar concentrators with piezoelectric energy harvesting circuits [89,90].In order to improve the e ciency of energy harvesting to provide more power for street lights, Arnab et al. combined piezoelectric materials with solar panels, as shown in Figure 8(b), to improve energy harvesting e ciency [90].Sathiyamoorthy and Bharathi designed a hybrid energy harvester with solar panels, piezoelectric devices, and wind turbines, aiming at harvesting renewable energy from pavements as much as possible to power tra c lights and houses [91].
As shown in Figure 8(c), the solar-geothermal energy harvesting system is to harvest both solar and geothermal energies.In such a system, solar energy is collected by solar panels, and the pavement heat is collected by a water circulation system.All the harvested energy is stored as hot water in the energy storage tank, to heat up the surrounding buildings or generate electricity to power the nearby electric devices.en, the energy storage tank releases cold water into the system, and a new circulation begins.Zhu and Turchi proposed such a harvesting system named centralized solar power (CSP) generation, which uses the harvested solar energy to provide additional thermal energy for the power generation of a geothermal plant [92].Harvesting both solar and geothermal energy can lead to an increase of 11.6% in the electric output, based on the thermodynamic simulations [93].
In addition, there are some other hybrid energy systems that make full use of at least one of the aforementioned energy harvesting techniques.For instance, Liu et al. analyzed a hybrid geothermal-fossil power system, by using geothermal energy to preheat the feed water before the power generation in a coal-red power plant [94].Buonomano et al. simulated a trigeneration system with a turbine, making use of solar and geothermal energies [95].Such a great variety of composite energy harvester designs are intensively studied via pilot studies and numerical simulations, with a great potential for future practical applications.

Permeable Pavement
Permeable pavements can recover the natural hydrological cycle and relief the urban ood risk and the urban heat island e ect.In general, permeable pavements are implemented by using porous materials with large voids to directly allow the   Advances in Materials Science and Engineering rainwater seeping through the pavement surface (Figure 9).In case of rain event, water can quickly in ltrate through the pavement structure into subsoil, which consequently reduces the pressure of urban drainage system and facilitates the water supply of natural cycle [7].In the meantime, the evaporation of water can bring away excessive heat within the pavement structure, reducing the urban heat island e ect [96,97].Because of these superior environmental-friendly features, permeable pavement systems are particularly suitable for applications in residential, commercial, and industrial areas under light tra c loads [97,98].
To achieve the high permeability, a void-rich pavement structure is currently recognized as the most feasible and e ective way, such as porous asphalt (PA), porous concrete (PC), and permeable interlocking concrete pavement (PICP) [7,102].In this case, an open-graded grain size distribution ensures the expected void contents and pore structures of pavement.Di erent models and design methods were proposed by considering the grain size distribution to analyze the e ect on the hydraulics property [103][104][105].Furthermore, the water-purifying evaluation of three types of permeable pavement structure was also investigated especially for cold regions [106,107].To optimize the hydraulic conductivity of permeable pavement, a combined scheme was created by enhancing surface runo controlling results of bioretention ponds, in ltration galleries, and permeable pavement [108].To fundamentally understand the void distribution in the open-graded asphalt concrete, X-ray computer tomography (XCT) was performed, where the e ect of void diameter, void tortuosity, and minimum sectional dimension on the hydraulics property was analyzed [109][110][111].Based on XCT measurements, a permeability numerical model was proposed for the open-graded asphalt concrete.In addition to the high hydraulic conductivity, the porous structure can also reduce the air-pumping e ect between tire and pavement interactions, which is the major cause of tra c noises (above 1,000 Hz) [112,113].
e absorption properties of porous pavement structure also contribute to noise reduction, following the same absorption principle as acoustical wall treatment [98,105,112,114].
Apart from the functionality, mechanical properties of permeable pavement were also widely investigated to evaluate the durability.To make life-cycle maintenance strategy for permeability deterioration, an arti cial soiling test to simulate the soiling process during life-time of porous asphalt was developed [112].To clarify the mechanical response of permeable pavement, wide fatigue behaviors were performed in comparison with the conventional rigid pavement [102,113].Most of the studies have been performed at the individual sites.However, in a complex serving environment, various moisture levels might be captured in the porous pavement structure, resulting in various possible combinations of air, liquid, and solid.Moreover, with the ltration and the upward movement of sublayer and soil, the porous pavement structures are mostly in an unsaturated state, where multiphysical processes occurred such as freezing and spalling, drying and shrinkage, hydrodi usion and subsidence, and capillarity and cracking [115].Each one of these processes, involving more than two physical phases, can cause a complex mechanical distribution, which exerts a signi cant in uence on the pavement behavior [116].To address this problem, several coupledphase models have been established, with experimental validations.Results from numerical models and experimentations reveal the mechanism of porous pavement under partial saturated conditions [102,117].

Advances in Materials Science and Engineering
It can be concluded from the literatures of urban permeable pavements, including hydraulic characteristics and other functional performances, that using permeable pavement is promising and feasible to resolve the city flooding problem and eliminate the urban heat island effect.However, these researches are mostly based on the phenomenological analysis at the macroscopic level.e microscopic performances such as the inner water permeation, storage and evaporation, pollutant distribution, storage and migration are not clear, which hinders the understanding of degradation mechanisms.As a result, a systematic investigation of the permeable pavement system has to be carried out at multiple spatial scales.

Comparison of Green Technologies in Pavement
Applications.Green technology applications can contribute to sustainable and resilient pavements from many aspects.Applying energy harvesting techniques in pavements can continuously generate the self-contained and clean power to activate in situ monitoring sensors and illuminate traffic lights and signals.By contrast, permeable pavements can rapidly drain storm water runoff to alleviate the risk of urban flooding and enhance travel safety, especially for walkways and parking lots.Typically, permeable pavements have the interconnected voids of 15%∼35% by volume [118], with a significant hydraulic benefit of reducing 90% of the peak runoff volume [119][120][121].ese applications contribute to enhancing water sustainability management by reusing the urban runoff but also in improving the energy conservation by collecting wasted energy from pavements [84,[122][123][124].
e green technology applications in pavements lead to safe, sustainable, and resilient transportation infrastructures with a reduced cost of maintenance and emergence response, enhanced travel safety, and improved environmental benefit, allowing transportation infrastructures independent of external power grids in the case of the large-scale power outage in a disruptive event [46,123,125].Table 4 compares different energy harvesting technologies in pavement applications, in terms of the energy conversion method and efficiency, and advantage and disadvantage, as well as example applications and technology development maturity.Solar energy harvesting has the highest conversion efficiency to harvest the energy from solar radiations into electric energy.e major advantage of solar energy harvesting is that solar radiations are available worldwide.An obvious disadvantage is that sun radiations are maximized at the direct sunlight, and they are limited at nights or rainy days.Depending on the design scheme, piezoelectric energy harvesting converges mechanical energy into electric energy at a low-medium convergence efficiency.Previous research considered that piezoelectric energy harvesting may be one of the most encouraging technologies with the widest power density versus voltage envelope [126].Conversely, geothermal energy harvesting converges geothermal energy into electric energy or thermal energy at a medium convergence efficiency.e harvested renewable energy from these technologies can be applied to power electric devices associated with pavements, such as traffic lights and signal lights, or to monitor pavement health, such as temperature, deflection, and moisture content, or to deice pavement in cold weather.Many pilot studies have demonstrated the feasibility of energy harvesting from pavements.Both solar energy harvesting and geothermal energy harvesting techniques are relatively matured, whereas thermoelectric energy harvesting techniques are the least matured, with a low energy conversion level.

Application Challenges and Recommendations.
For more practical applications, there are some challenging issues remaining, such as how to properly install the devices in construction, efficiently maintain the devices during the service life, and timely replace damaged components.Compared to the traditional pavement system, the presence of energy harvesting devices may have a negative influence on the structural integrity, leading to weak mechanical properties and crack developments, which may cause internal moisture damages in operations.On the contrary, there are concerns of their weak mechanical performances and clogging-prone nature of permeable pavements.Many studies have shown that there is a negative correlation between the porosity and compressive strength of permeable cement concrete [121,[127][128][129], which is commonly used in permeable pavement systems.For instance, the compressive strength of permeable concrete is usually less than 25 MPa [118].Such weak mechanical properties are likely to lead to crack failures in permeable pavements, which significantly reduce the service life.Moreover, previous studies have demonstrated that the clogging issue in permeable pavements significantly reduces the porosity, reducing the service life [121,129,130].erefore, we should optimize the design with the best efficiency, conduct the safe construction to eliminate initial damages, and determine an optimal time to perform regular maintenance in the following aspects.First, we need to pay special attention on optimal designs, proper location selections, and careful installations.In the case of energy harvester devices, the effect of energy harvesting throughout the service life is related to many factors, such as material type, device dimension, installation depth, physical and mechanical properties of pavement structure, weather condition, and geographical location, among others [11,37,40,64,75,131].By selecting appropriate materials and careful device designs, the stiffness of an energy harvester should be at a level similar to the overall pavement stiffness to avoid reflective cracks [46], and sharp edges should be eliminated to prevent cracks around the device and to minimize the differential deflection on the device-pavement interface [132].External tempered protectors are suggested to implement to improve the durability performance, by preventing future water infiltrations and chloride penetrations [132].Energy harvesting devices should be carefully installed by experienced workers to eliminate damages in the installation process.For piezoelectric energy harvesters, they are more suitable to be installed on the wheel path (1.5∼2 feet away from the lane edge) of asphalt pavements at a depth of 2 inch from the surface to allow for regular pavement maintenances (such as milling and overlaying) [46].For solar pavements, solar panels should be installed at a certain location range of the maximal solar exposure with the minimal reflection and glint effect to ensure the road safety.To the best knowledge of the authors, there is no publicly reported study on the replacement cost of energy harvesters in pavements yet.In the case of permeable pavement systems, hydraulic feature of permeable pavements depends on the grain size and mineralogy of sediments [133,134], and the clogging characteristics mainly depends on the filter media aggregate size [135].Coustumer et al. suggested to use the performance period when the effective hydraulic conductivity reduces to 50% of its design value due to clogging as the relevant specification [136].Recent researches have investigated different ways to eliminate the clogging effect through periodic cleaning [134,137,138] and to improve mix design for bearing heavier loads by using advanced porous materials [139,140].
Second, we should assess the life-cycle performance of green technologies in pavement applications in both socioeconomic and environmental aspects through both numerical simulations and laboratorial experiments, as well as field measurements.To improve the life-cycle performance of sustainable pavements, future research should be conducted to promote better designs and efficient applications.For example, the harvested energy could be used for Advances in Materials Science and Engineering powering sensors and data loggers for health monitoring [141].To understand the mechanical properties of energy harvesters and permeable pavements at multiple spatial scales, advanced testing and characterization methods could be used to evaluate the expected service life and identify the best timing for regular maintenance [142][143][144][145][146][147][148].From the economic point of view, we should also assess the life-cycle cost-benefit of green technology applications.e life-cycle cost includes not only the initial construction cost but also operation, maintenance, and repair costs, as well as replacement cost, and so on.Even though the initial installation cost of energy harvesting devices and permeable pavement systems is greater than conventional pavement structures, their life-cycle costs are likely to be smaller.e harnessed energy may significantly contribute to the energy saving and greenhouse gas emission reduction.In the pavement cooling applications, geothermal pavements can not only eliminate the risk of thermal cracking but also mitigate the UHI effect.In snow/ice melting applications, thermal electric and geothermal pavements can enhance the travel safety by eliminating surface snow and ice and reduce the environmental pollution due to a less usage of road salt.e collected runoff from permeable pavement systems can be reused to improve water sustainability in urban areas.
Last but not least, as scientific technology advances, more studies and applications of green technology in pavements are anticipated.At some point, we will need standardized guidelines and evaluation tools to facilitate engineers, researchers, and decision makers to design, construct, and assess the field performance of these pavements from different aspects.By establishing a database in a consistent format to continuously collect data about the materials, designs, methods, and costs for maintenance and replacement, researchers and engineers can utilize these data for allowing the objective assessment of lifecycle performance and cost-benefit analysis.In this way, sustainable pavements using different materials, of different designs, at different locations can be easily compared with each other.ese analyses can provide informative suggestions to decision makers for developing efficient plans of sustainable and resilient transportation infrastructures with the implementation of different green technologies.

Summary
In recent decades, there have been many studies focusing on the development of green technologies for sustainable pavements by generating renewable energy and eliminating adverse environmental impacts.
is paper starts with a comprehensive summary of energy harvesting technologies, including piezoelectric energy harvesting, solar energy harvesting, thermoelectric energy harvesting, and geothermal energy harvesting, as well as composite energy harvesting.After that, permeable pavement systems are critically reviewed.Major findings are as follows: (1) Energy harvesting technologies have been developed in laboratory and/or applied in prototype studies.Results from both laboratories and prototype studies have demonstrated the feasibility of energy generation from pavements and the adaptability of energy harvesting techniques to different pavement conditions.Among these energy harvesting technologies, solar energy harvesting has the greatest energy conversion efficiency in practice, with the most mature technologies and the widest application.Even though piezoelectric technologies become increasingly popular in research, the actual application is limited in laboratory and at a prototype stage due to a lower energy conversion efficiency and brittle properties of piezoelectric materials.In addition, geothermal energy harvesting technologies also have a similar energy conversion efficiency.ese energy harvesting technologies have not been well validated in practice yet; therefore, they are not ready for practical applications in field at the current stage.However, they provide us a promising future for building more sustainable pavements by harvesting renewable energy, once the challenging issues are properly addressed.
(2) Permeable pavement systems, on the contrary, are an important part of sustainable pavements.e implementation of permeable pavements helps us to eliminate surface runoffs in rainy days and to enhance water sustainability.Future research should be conducted to develop new designs or to use advanced materials for improving the mechanical strength and durability of permeability pavements with the least clogging effect.Moreover, an emerging trend for building sustainable pavements is to implement energy harvesting technologies in permeable pavements to improve both energy conservation efficiency and water sustainability.
(3) Future research should focus on solving the following urgent issues involved in the implementation of green technologies for sustainable pavements: construction technology, maintenance technology, and life-cycle performance.Solving these issues can strengthen theoretical understanding in technical, economical, and sustainable perspectives, and eventually, they would facilitate extensive applications of green technologies for building sustainable pavements in practice.

Figure 3
Figure 3 depicts a representative power density of three green technologies: piezoelectric, solar, and geothermal.

Figure 9 :
Figure 9: Typical permeable pavement sections (based on [99-101]): (a) fully permeable pavement, where water can infiltrate to subgrade; (b) half permeable pavement, with some water infiltrating to the subgrade, most is stored in the pavement structure; (c) permeable pavement with no water infiltrating to the subgrade but is stored in the pavement structures.

Table 1 :
Features of piezoelectric materials.
Note.NA: not available.

Table 2 :
Physical design and electric output of piezoelectric transducers.

Table 3 :
Advantages and disadvantages of thermoelectric materials.

Table 4 :
Comparison of green technologies to harvest energy from pavements.