Investigation of the Application of Various Water Additive Ratios on Unconfined Compressive Strength of Cement-Stabilized Amorphous Peat at Different Natural Moisture Contents

Natural peat is considered incapable of supporting built structure due to its poor engineering properties. Chemical stabilization is one of the peat soil improvement methods which has been studied by many researchers. +is study describes an investigation of water additive (W/A) ratio application on cement-stabilized peat strength. Peat soil at different moisture contents, which are 1210%, 803%, and 380%, were stabilized with cement byW/A ratio of 2.0, 2.5, 3.0, 3.5, and 4.0. Unconfined compressive strength (UCS) test was conducted after the specimens were being air-cured for 28 and 56 days.+e result shows that there is an increase of UCS value as the decrease ofW/A ratio (the increase of cement dosage) and the increase of curing time and peat moisture content. +e higher strength found in the specimen with higher moisture content, compared to the lower one at the sameW/A ratio, shows that the mix design of cement-stabilized peat usingW/A ratio should have differed under different peat natural moisture contents. From the result, it is also found that cement hydrolysis reaction occurred despite the presence of humic acid in the peat soil, which by many studies is assumed will hinder the cement-soil reaction.


Introduction
A mixture of fragmented organic material formed in wetlands under suitable climatic and topographic conditions is called peat.Peat is derived from vegetation that has been chemically changed and fossilized as described by Dhowian and Edil [1].Approximately, Malaysia has 2.6 million hectares of peatlands.Sarawak has the largest area of peat soils in Malaysia for about 69.08% of the total peatland area in the country [2].
In civil engineering, peat is classified as a problematic soil due to its weak characteristic related to its ability to support the civil structures.Peat consists of water and decomposed plant fragment with no measurable strength in its natural state.Peat has a high natural moisture content, high compressibility including significant secondary and tertiary compression, low shear strength, high-degree spatial variability, and potential further decomposition as a result of changing environmental conditions [3].Peat properties are site-dependent.Not only has a high natural moisture content, peat also has a wide range of moisture content depending on sites.e water content of peat can be more than 1500% [4].Huat et al. [5] reported that the natural water contents of peat sample from several locations in Malaysia were found to range from 150-700%.Moisture content in the range of 200-2200% is reported by Zainorabidin and Wijeyesekera [6] for east Malaysian peat.
Ground improvement method has to be done prior to construction on peat.Chemical stabilization such as cementpeat stabilization is considered the effective method for peat stabilization especially for deep peat which can reach up to 10 meters deep.ere are some factors that influence cemented-soil mixture [7,8], which are: type and properties of soil, quantity and type of cement, soil mixture content, mixing and compaction method, and condition and curing time.Many of cement-stabilized peat studies were conducted considering these factors.Table 1 shows the summary of peat stabilization studies by some researchers.
1.1.Cement as Chemical Stabilizer.When cement is added into the soil, there occur two chemical reactions.First is primary hydration where water reacts with cement, forming a binding gel called tobermorite/CSH.e second reaction is called secondary pozzolanic reaction.It happens by the reaction of calcium hydroxide [Ca(OH) 2 ], formed in primary hydration and water and pozzolan (silica and alumina) in the soil, which then forms more binding agents.
Axelsson et al. [15] recommended that the binding effect of stabilization should be based on hydraulic or pozzolanic reaction, for example, those from cement or lime.Compared to lime, cement is considered better for peat soils [7,15].With lime, pozzolanic reaction hardly occurs because of the presence of fewer clay particles and humic acid that inhibit the strengthenhancing mechanism.Meanwhile, cement still forms binding materials with water, despite the presence of humic acid [16].OPC is the common type of cement used as the stabilizer and considered the best stabilizer for peat [13].OPC is good for handling the high moisture content of peat [17].
Unlike clay, peat has a humic acid that can retard the strength development of cement-stabilized peat.However, Huttunen et al. [18] indicated that humus or humic acid is one of the factors affecting the stabilization effectiveness; thus, it is not merely determined by organic and humus content of the soil.Axelsson et al. [15] indicated that in soils with high organic contents, the quantity of binder needs to exceed a threshold to neutralize the humic acid to be stabilized.Soil will remain unstabilized without sufficient binder added.Ali et al. [10] also conducted a study to prove the addition of sufficient binder to neutralize humic acids.Quantity of 150-250 kg/m 3 cement was recommended by Axelsson et al. [15] for peat soil.Ali et al. [10] found the dosage of 250 kg/m 3 binder with 75% cement and 25% slag is the minimum dosage for stabilized peat to achieve significant strength gain.Meanwhile, according to Dehghanbanadaki et al. [19], the combination of 300 kg/m 3 of cement gives the highest strength for all the samples tested as for eight times greater than untreated peat.

Water Additive (W/A) Ratio as Stabilization Mix Design.
Compaction method greatly contributes to the effectiveness of stabilization.However, it is difficult to compact peat soil because of its high moisture content and organic particles which make a slurry-like and sticky texture.Many of chemicalstabilized peat studies [3,7,[12][13][14] utilized the compaction test to determine the maximum dry density and optimum moisture content with a certain percentage of a stabilizer by the wet or dry weight of soil mass to find mix design for stabilization. is method is actually difficult to apply in the field for peat soil due to the high initial moisture content.
Axelsson et al. [15] studied the shear strength of 28-daycured-specimens added with several quantities of binder and reported that water-binder ratio has an effect to the soilstabilized specimens.
erefore, this study used various water additive (W/A) ratios to calculate the cement dosage of the cement-peat mixture based on its field moisture content and to observe the interaction between cement added and the moisture content yielded to the strength increased.is method of mix design is assumed to be more simple and practical, where peat moisture content is highly taken into consideration as one of the prominent characters of peat.Highest strength of 28-day-cured UCS value was found at the water to binder ratio at 4 (within the data range of the study) by Timoney et al. [20], who stabilized highly organic soil with cement in dry soil mixing.Several UNIMAS researchers [21][22][23][24] also have conducted cement-peat stabilization using the W/A ratio.
e maximum strength achieved at the W/A ratio of 3.5 (within the data range of the study) was found by Ismail [21] and Jimbai [23].However, more studies and wider data range are still required in investigating the optimum W/A ratio for peat stabilization.

Air-Curing for Cement-Stabilized Peat.
Curing time has an important role for cement-stabilized peat to gain strength since cement needs time for reacting with water and pozzolan materials.Many researchers had proved the strength increase over curing time in peat stabilization [3,7,9,10,12,14,19,23].Several studies of peat stabilization often used water curing method to allow cement hydrolysis reaction [10][11][12][13].Kalantari and Huat [9] used air-curing technique in peat stabilization in exchange of water curing technique that has been used before by many researchers.Air-curing technique allows the peat to lose their moisture content and gradually become harder.Kalantari and Huat [9] evaluated the effect of curing age and water-cement ratio on unconfined compression strength.e study found that the hardening process can occur with initial water content of natural peat soil and does not need extra water for the curing process.

Engineering Properties and Unconfined Shear Strength of
Cement-Stabilized Peat.Several studies of peat stabilization show the increment of engineering characteristics of peat after stabilization.e pozzolanic activity in stabilized specimens leads to the increase in its density due to the reduction of the amount of interparticle voids [14].Liquid limit and plasticity of soils are reported to decrease after the addition of cement [3,7,14].From the linear shrinkage test, Ali et al. [10] found stabilized peat had better volume stability than that of untreated peat.Rahman et al. [14] also reported a decrease in permeability value after stabilization.
e pH value of cemented peat specimens is increasing with cement addition, and the materials change from acidic to alkaline [3,10].From the compaction test, maximum dry density increase and optimum moisture content decrease was observed [3,7,14,25].
Many researchers agreed with the finding that unconfined compressive strength of cement-stabilized peat is 2 Advances in Civil Engineering increased compared to the untreated peat.e unconfined compressive strength was found to increase with the increase of cement content and curing time [3, 7, 9, 10, 12-14, 19, 25].
It is also found that the UCS values increase with the decrease of water-cement ratio [9].Kalantari and Huat [9] also found that the strength gain continues through curing period of 6 months as well.Hebib and Farrell [8] found a considerable increase in strength that was gained for cement-stabilized Ballydermot peat in 1-year time period.e 90-day unconfined compressive strength achieved 70% of the 1-year strength.However, the UCS value of cementstabilized peat reported decreasing after optimum amount as the binder increase, which is related to the moisture content of natural peat [19].

Sampling and Materials.
e disturbed peat sample was collected in Kampung Meranek, Sarawak, Malaysia, from 0.5-1 m depth below the surface.
e peat sample transported to the laboratory was kept in a sealed container.Before the tests were performed, the peat sample was screened through 6.63 mm (0.3″) sieve to remove larger objects.Leaving in the larger objects would introduce an inconsistency in the test result.
For the UCS test, peat soil with three different moisture contents were prepared, which are peat with moisture content of 1210% as the field moisture content (later referred as peat A), moisture content of 803% (later referred as peat B), and moisture content of 380% (later referred as peat C). e last two moisture contents are the result of air-dried peat.e stabilizer used was the ordinary Portland cement (OPC).

Physical Properties.
e physical properties tests carried out were Von Post classification (degree of decomposition), moisture content (BS 1377), organic content (ASTM 2974), fiber content (ASTM D 1997), specific gravity (BS 1377), liquid limit (BS 1377), linear shrinkage (BS 1377), and pH Advances in Civil Engineering test (BS 1377).ere are some adjustments for peat soil tests due to their distinct characters compared to other inorganic soils.For the specific gravity test, kerosene was used as the standard liquid instead of water due to the lightness of peat material.For the liquid limit test, the reversed method was used.Peat was tested from wet to dry condition using a dryer, instead of adding water to the dry peat.e reversed method was applied because peat will unlikely return into its natural state once dried.

Mould Preparation.
A PVC pipe was used as a split mould for UCS specimens.e sample size was 38 mm in diameter and 76 mm in length.Both ends of PVC were covered with Styrofoam and PVC cover.Plastic wrap was used around the PVC mould to prevent water leakage.e inside part was lubricated with grease to prevent the specimen adhering to the mould surface.

Stabilization and Air-Curing.
e W/A ratio was used as the mix design for stabilization to calculate cement dosage based on a specified W/A ratio and peat moisture content.
e W/A ratio of 2.0, 2.5, 3.0, 3.5, and 4.0 were used for peat A, B, and C. ree samples were prepared for each varied conditions to get more reliable data.Peat A with cement mixture is later referred as peat A specimen, peat B with cement mixture is later referred as peat B specimen, and peat C with cement mixture is later referred as peat C specimen.Cement dosage for both peats is shown in Table 2.
Peat and cement were weighed according to the mix design calculation and mixed well with a putty knife.erefore, the mixture was put inside the mould and pressed with a plastic spoon by three layers.Since the mixture was a kind of slurry, the standard compaction method cannot be used.After the mould had been covered, the air-curing procedure was done by keeping the specimens at a normal temperature and without any water intrusion.e aircuring procedure was carried for 28 and 56 days for peat A, B, and C specimens.To prevent water accumulation, the specimens were turned over every day for the first 3 days and then every 3-4 days.

Unconfined Compressive Strength (UCS) Test.
After the curing process, the unconfined compressive strength test was conducted for the peat specimens according to ASTM D 2166 guidelines.e specimens were loaded axially using UCS testing equipment with 2 kN load proving ring until the load values decreased, the sample failed, or the strain has reached 15%.

Physical Properties.
e test result of the physical properties of the peat is shown in Table 3.
e peat sample had a dark brown color.e consistency was very pasty and amorphous with faintly recognized plant remains.When squeezed, about two-thirds of peat escaped between the fingers.erefore, the degree of decomposition of Kampung Meranek peat by Von Post classification was classified as H7-H8 or sapric (amorphous) peat [26].e moisture content tested in the lab was 1210.497%, which was very high.e specific gravity was 1.408, which was a typical value of peat soil.e liquid limit value showed that the sample would enter liquid consistency by the moisture content of 458%.Linear shrinkage of 27.338% indicated that the peat had a high shrinkage when dried out.
Peat should be contained by organic content more than 75% [4].e organic content of the tested sample was found to be 95.793% which fell into the peat category mentioned by Huat [4].e fiber content of 32.333% showed that the peat is classified as sapric (amorphous) peat based on ASTM D 4427.
e pH value was 3.31, indicating that the peat is highly acidic [26].

Stress vs. Strain Relationship of Cement-Stabilized Peat
with Varied W/A Ratio.Figures 1-4 show the stress-strain graphs of the peat A, B, and C specimens with varied W/A ratio.
From the result of the UCS test, peak strength is found in peat A specimens.From the graphs, it can be inferred that UCS values increase as the decrease of W/A ratio, which also means the increase of cement dosage.For both curing times, W/A ratio 2.0 is showing a drastic increase of stress compared to other ratios, while close values of UCS strength are observed from W/A ratio of 2.5 to 4.0. is finding illustrates the quantity of binder needs to exceed a threshold to neutralize the humic acid to be stabilized as mentioned by Axelsson et al. [15].e close values of the stress of specimens with W/A ratio of 2.5-4.0 shows that there is no significant increase in strength, despite the addition of the cement.It means that the inadequate binder could not neutralize the humic acid, thus hinders the cement hydration process.
In contrary with the stress, W/A ratio 2.0 has the smallest strain value followed by other ratios consequently.is also shows the increase of the brittle characteristic as the decrease of the W/A ratio.
e pattern of the graphs from peat B specimens is relatively the same with peat A specimens.e peak strength is found, and strength from W/A ratio 2.0 is noticeably greater than other ratios.erefore, W/A ratio 2.0 could be assumed as the optimum W/A ratio of peat A and peat B. However, the strength from peat B seems to be lower than that from peat A for both curing times.
Aside from peat A and B, peat C shows a different response with W/A ratio variation.As shown in Figures 5 and  6, for both curing times, there is a drastic decrease in strength after W/A ratio of 2.5 to 2.0, despite the addition of cement dosage.Accordingly, from the graphs, W/A ratio 2.5 is assumed to be the optimum ratio for peat C. is finding is in agreement with Dehghanbanadaki et al. [19] who reported the decrease of UCS value of cement-stabilized peat after optimum amount as the binder increase that related to the moisture content of untreated peat.

4
Advances in Civil Engineering e strength obtained by peat C specimens is a lot greater than peat A and B specimens.e greater availability of soil particle in peat C specimens might a ect the greater strength compared to peat A and B specimens.Nevertheless, it is interesting that the strength of peat A specimens, which has fewer soil particles and higher moisture content compared to peat B specimens, is greater than that of peat B specimens.
erefore, the secondary pozzolanic reaction might occur in the stabilization of peat C specimens, while primary hydration took a more dominant role for peat A and B specimens since both have a high moisture content that exceeds the liquid limit and has fewer soil particles.

UCS Value vs. Curing Time.
Figure 7 shows the increase in UCS value towards curing time for each W/A ratio of peat A specimens.All of the specimens indicate the increase of UCS values through curing time, even though W/A ratio of 2.5 to 4.0 does not show a big increase of strength, unlike W/A ratio 2.0.Similar behavior was also found for peat B specimens, as shown in Figure 8. e increase factor from 28 days to 56 days is 9-40 folds for peat A, and about 4-20 folds for peat B (from varied W/A ratios).e graphs of W/A ratio 2.0 show that there is a signi cant increase in strength through longer curing time and show the workability of cement-soil reaction.ese also con rm that W/ratio 2.0 is the optimum ratio for peat A and B specimens.

Advances in Civil Engineering
For peat C specimens graph as shown in Figure 9, there is a decrease of UCS values with longer curing time for every W/A ratios except for W/A ratio 2.0.e data result shows a contrary belief by many studies that strength of cementstabilized peat would increase with longer curing time which might be a ected by uniformity or mixing method.

UCS Value vs. W/A Ratio.
From Figure 10, the peat A specimens which have 1210% moisture content achieve higher strength compared to the peat B specimens which have 803% moisture content. is proves the workability of cement hydrolysis reaction in the stabilized peat, despite the presence of humic acid.In other words, higher moisture 6 Advances in Civil Engineering content inside the soil provides more water for the cement to react and produces the binding agent.Peat C specimens, otherwise, have a di erent condition from peat A and B specimens, to begin with.e moisture content of peat A and B which exceeds the moisture content of the liquid limit (Table 3) makes it categorized in the liquid state, while peat C does not.erefore, the di erent factors that peat C has, are believed to in uence the greater strength achieved compared to peat A and B specimens, which also include the possibility of secondary pozzolanic reaction since peat C has more soil particles than the other two peats.
As discussed above, W/A ratio 2.0 seems to be the optimum W/A ratio for peat A and B specimens.Meanwhile, W/A ratio 2.5 is the optimum W/A ratio for peat C specimens.e increase of cement addition after optimum ratio decreases the UCS value of peat C specimens.erefore, it can be presumed that the optimum additive by W/A ratio mix design on peat stabilization is di erent for di erent moisture contents.For example, from the data results, W/A ratio 2.0 of peat B specimen which has 803% moisture content can give quite the same strength with W/A ratio 2.5 of peat A specimen which has 1210% moisture content.

UCS Value Increase Factor vs. W/A Ratio.
Figure 11 shows the strength increase factor for each specimen with varied W/A ratio.Compared to the untreated peat strength, the specimens show a large improvement in strength.For peat A specimens, the highest increase factor is achieved by the 56-day cured specimens of W/A 2.0 which is 47 folds to the untreated peat strength.Peat B achieved 21 folds to the untreated peat strength by the 56-day-cured-specimens of W/A 2.0.And peat C achieved 62 folds to the untreated peat strength by the 28-day-cured-specimens of W/A 2.0.
Peat A and B, which had given the same variations of W/A ratios and have the same optimum W/A ratio based on this study, have di erent outcomes in the strength performances.For the same W/A ratio and close quantity of cement percentage, peat A specimens show higher UCS values for about 1.6-2 folds than peat B specimens for 28-daycuring.Meanwhile for 56-day-curing, peat A specimens show higher UCS values for about 1.4-1.5 folds than peat B specimens.

Conclusions
From the investigation of the various water additive ratio application on the uncon ned compressive strength of cement-stabilized amorphous peat at di erent natural moisture contents, several conclusions are made: (i) UCS values increase with the increase of cement dosage (decrease of water additive ratio).(ii) UCS values increase with the increase of curing time.Even though the increase is not really signi cant between 28 and 56 days, but compared to the original peat strength, it gives increase factor of 9-40 folds (from varied W/A ratios) for peat A, 4-20 folds for peat B, and about 6-30 folds for peat C. (iii) e insigni cant results in W/A ratio below 2.0 for peat A and B might be caused by inadequate cement to neutralize humic acid which retards the strength development of cemented peat.(iv) For the same W/A ratio and close quantity of cement percentage, peat A specimens show higher UCS value than peat B specimens.For 28-daycuring, peat A specimens show higher UCS values   for about 1.6-2 folds than peat B specimens.For 56-day-curing, peat A specimens show higher UCS values for about 1.4-1.5 folds than peat B specimens.(v) e application of W/A ratio on peat stabilization is different for different peat moisture contents, in terms of specified strength gain purpose.For example, W/A ratio 2.0 of peat B specimen which has 803% moisture content can give relatively the same strength with W/A ratio 2.5 of specimen peat A which has 1210% moisture content.(vi) W/A ratio 2.0 is the threshold for peat A and B to be stabilized, as W/A ratio 2.0 shows a drastic strength gain from W/A ratio 2.5, while W/A ratio of 2.5 to 4.0 does not show any drastic change from each other.Brittle behavior of W/A ratio 2.0 is evident from the stress-strain graphs compared to W/A ratio 2.5-4.0, which could be evaluated for the future study.(vii) W/A ratio 2.5 is the threshold for peat C to be stabilized.Addition of cement dosage after the optimum amount will decrease the UCS value (viii) Cement hydrolysis reaction is evident in the specimens, despite the presence of humic acid content of peat, proved by the higher strength values achieved by the higher moisture content of peat.

Figure 10 :
Figure 10: UCS value vs. W/A ratio for each specimen.

Figure 11 :
Figure 11: UCS value increase factor vs. W/A ratio for each specimen.

Table 1 :
Summary of tropical peat chemical stabilization study by some researchers.

Table 2 :
Cement dosage for peat A of various W/A ratios.
w, moisture content; W, wet soil mass; Ws, dry soil mass, Ww, water content; Wc, cement mass.