The Heat‐Treatment of Anodic Oxide Films on Tantalum: III . The Conductivity Profile

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© 1964 ECS - The Electrochemical Society
, , Citation D. M. Smyth et al 1964 J. Electrochem. Soc. 111 1331 DOI 10.1149/1.2425997

1945-7111/111/12/1331

Abstract

Dielectric measurements have been used to study the distribution of the conductivity which is introduced into the anodic oxide film on tantalum by heat‐treatment in air. The temperature and frequency dependences of capacitance indicate that the conductivity distribution is exponential with position in the oxide. The combination of these dependences yields an activation energy of 0.6 ev for the conduction process. The temperature and frequency dependences of tan δ for films which have been partially reanodized after heat‐treatment also yield an activation energy of 0.6 ev.

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10.1149/1.2425997