The Effects of  H 2 S  on Electrolyte Distribution and Cell Performance in the Molten Carbonate Fuel Cell

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© 2000 ECS - The Electrochemical Society
, , Citation Makoto Kawase et al 2000 J. Electrochem. Soc. 147 1240 DOI 10.1149/1.1393343

1945-7111/147/4/1240

Abstract

To evaluate the effects of on the performance of molten carbonate fuel cells, bench‐scale cell tests were performed and the meniscus heights of the electrolyte on Ni were measured with fuel gases containing various amounts of . In bench‐scale cell tests, in the fuel gas had a large effect on cell voltage in the early operating stages, but this effect showed a tendency to decrease with operating time. Basic wetting property measurements revealed that Ni becomes better wetted at higher concentrations. In calculations of the electrolyte distributions, the electrolyte fill of the anode with was found to be higher than that without . This study simulates the electrolyte distributions taking into account the effects of levels, the electrolyte loss and the change in pore size distributions of the electrodes, and discusses the relation between electrolyte distribution and cell performance. © 2000 The Electrochemical Society. All rights reserved.

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10.1149/1.1393343