Fused Salt Polarography Using a Dropping Bismuth Cathode

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© 1960 ECS - The Electrochemical Society
, , Citation Raymond J. Heus and James J. Egan 1960 J. Electrochem. Soc. 107 824 DOI 10.1149/1.2427522

1945-7111/107/10/824

Abstract

An apparatus is described which is suitable to study fused chlorides by the polarographic technique. Dropping bismuth is used in a way analogous to dropping mercury. Polarographic waves are shown for , , and in a eutectic melt at 450°C. The method serves as an analytical tool at high temperatures, besides yielding physicochemical information such as diffusion coefficients by application of the Ilkovic equation.

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10.1149/1.2427522