Reaction of Cobalt in  SO 2 Atmospheres at Elevated Temperatures

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© 1984 ECS - The Electrochemical Society
, , Citation Nathan S. Jacobson and Wayne L. Worrell 1984 J. Electrochem. Soc. 131 1182 DOI 10.1149/1.2115775

1945-7111/131/5/1182

Abstract

The reaction rate of cobalt in environments has been measured at 650°, 700°, 750°, and 800°C. Product scales consist primarily of an interconnected sulfide phase in an oxide matrix. At all temperatures, the rapid diffusion of cobalt outward through the interconnected sulfide appears to be important. At 650°C, the reaction rate slows dramatically after 5 min due to a change in the distribution of these sulfides. At 700° and 750°C, the reaction is primarily diffusion controlled; values of calculated from this work show favorable agreement with values of calculated from previous sulfidation work. At 800°C, a surface step becomes rate limiting.

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10.1149/1.2115775