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Electroless Deposition of Cobalt Using Hydrazine as a Reducing Agent

© 1997 ECS - The Electrochemical Society
, , Citation Stojan S. Djokić 1997 J. Electrochem. Soc. 144 2358 DOI 10.1149/1.1837818

1945-7111/144/7/2358

Abstract

Electroless deposition of cobalt using hydrazine as a reducing agent was investigated. The rate of deposition increased with an increase in pH, temperature, and concentration. Dependence of the rate of deposition on Co(II) concentration was found to pass through a maximum. Deposition of smooth and shiny Co deposits from the investigated solutions is possible within a relatively small range of pH (12.1 to 12.6). A further pH increase leads to an increase in the rate of deposition and formation of dendritic Co powder. Mechanistic aspects of Co deposition using hydrazine as a reducing agent have also been discussed.

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