Competitive Adsorption of Cations onto the Silicon Surface: The Role of the Ammonium Ion in Ammonia‐Peroxide Solution

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© 1999 ECS - The Electrochemical Society
, , Citation Lee M. Loewenstein and Paul W. Mertens 1999 J. Electrochem. Soc. 146 3886 DOI 10.1149/1.1392567

1945-7111/146/10/3886

Abstract

Study of metal ion adsorption in aqueous solutions using a spin‐contamination method has shown that can effectively prevent adsorption onto the hydrophilic, oxidized silicon surface. In ammonia‐hydrogen peroxide‐water solution (APM) the relatively low adsorption on the wet oxidized silicon surface can be explained by its competition for adsorption sites with , which is the dominant cation in APM. prevents adsorption onto the oxidized silicon surface, by an ion‐exchange mechanism analogous to that of in acidic solutions. The equilibrium constant governing the adsorption of is comparable to, or larger than, that of , meaning that is at least as effective as in removing metals from the oxidized silicon surface and in keeping metal ions off the surface. © 1999 The Electrochemical Society. All rights reserved.

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10.1149/1.1392567