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Annual Review of Materials Research

Volume 45, 2015

Surface Engineering of Mo-Base Alloys for Elevated-Temperature Environmental Resistance

Abstract

The synthesis of robust coatings that provide protection against environmental attack at ultrahigh temperatures is a difficult challenge. To achieve this goal for Mo-base alloys, the fundamental concepts of reactive diffusion pathway analysis and kinetic biasing are used to design a multilayer Mo-Si-B-base coating with a phase sequencing that allows for structural and thermodynamic compatibility and an underlying diffusion barrier to maintain coating integrity. The coating design concepts have a general applicability. The coating structure evolution during high-temperature exposure facilitates a prolonged lifetime as well as self-healing capability. The borosilicide coatings that can be synthesized by a pack cementation process yield superior environmental resistance for Mo-base systems at temperatures up to at least 1,700°C and can be adapted to apply to other refractory metal and ceramic systems.

Keyword(s): coating design, environmental resistance, oxidation, refractory metals, ultrahigh temperature
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2015-07-01
2024-04-23
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Surface Engineering of Mo-Base Alloys for Elevated-Temperature Environmental Resistance
Annual Review of Materials Research 45, 519 (2015); https://doi.org/10.1146/annurev-matsci-070214-020959
/content/journals/10.1146/annurev-matsci-070214-020959
/content/journals/10.1146/annurev-matsci-070214-020959
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